Effect of Fluorine on Thermoluminescence in LiMgPO4
Fluorine-doped lithium magnesium phosphate has been studied for the first time. It has been shown that fluorine significantly enhances the intensity of thermally stimulated luminescence. To find the preferred positions of fluorine and structural distortions caused by aliovalent substitution, ab init...
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| Veröffentlicht in: | Russian journal of inorganic chemistry 2023-02, Vol.68 (2), p.216-220 |
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| container_title | Russian journal of inorganic chemistry |
| container_volume | 68 |
| creator | Kalinkin, M. O. Akulov, D. A. Gyrdasova, O. I. Abashev, R. M. Surdo, A. I. Medvedeva, N. I. Kellerman, D. G. |
| description | Fluorine-doped lithium magnesium phosphate has been studied for the first time. It has been shown that fluorine significantly enhances the intensity of thermally stimulated luminescence. To find the preferred positions of fluorine and structural distortions caused by aliovalent substitution, ab initio calculations have been performed, which demonstrate that fluorine is not included into the (PO
4
)
3–
anion; rather, it promotes the formation of clusters simultaneously containing lithium and fluorine ions. |
| doi_str_mv | 10.1134/S0036023622602276 |
| format | Article |
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4
)
3–
anion; rather, it promotes the formation of clusters simultaneously containing lithium and fluorine ions.</description><identifier>ISSN: 0036-0236</identifier><identifier>EISSN: 1531-8613</identifier><identifier>DOI: 10.1134/S0036023622602276</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemistry ; Chemistry and Materials Science ; Fluorine ; Inorganic Chemistry ; Inorganic Materials and Nanomaterials ; Lithium ; Magnesium phosphate ; Thermoluminescence</subject><ispartof>Russian journal of inorganic chemistry, 2023-02, Vol.68 (2), p.216-220</ispartof><rights>Pleiades Publishing, Ltd. 2023. ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2023, Vol. 68, No. 2, pp. 216–220. © Pleiades Publishing, Ltd., 2023. ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2023. © Pleiades Publishing, Ltd., 2023. Russian Text © The Author(s), 2023, published in Zhurnal Neorganicheskoi Khimii, 2023, Vol. 68, No. 2, pp. 265–270.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-176f4975a215af8b269102e2087a456efb7c7176d9319153f5d4faab959678693</citedby><cites>FETCH-LOGICAL-c316t-176f4975a215af8b269102e2087a456efb7c7176d9319153f5d4faab959678693</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0036023622602276$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0036023622602276$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Kalinkin, M. O.</creatorcontrib><creatorcontrib>Akulov, D. A.</creatorcontrib><creatorcontrib>Gyrdasova, O. I.</creatorcontrib><creatorcontrib>Abashev, R. M.</creatorcontrib><creatorcontrib>Surdo, A. I.</creatorcontrib><creatorcontrib>Medvedeva, N. I.</creatorcontrib><creatorcontrib>Kellerman, D. G.</creatorcontrib><title>Effect of Fluorine on Thermoluminescence in LiMgPO4</title><title>Russian journal of inorganic chemistry</title><addtitle>Russ. J. Inorg. Chem</addtitle><description>Fluorine-doped lithium magnesium phosphate has been studied for the first time. It has been shown that fluorine significantly enhances the intensity of thermally stimulated luminescence. To find the preferred positions of fluorine and structural distortions caused by aliovalent substitution, ab initio calculations have been performed, which demonstrate that fluorine is not included into the (PO
4
)
3–
anion; rather, it promotes the formation of clusters simultaneously containing lithium and fluorine ions.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Fluorine</subject><subject>Inorganic Chemistry</subject><subject>Inorganic Materials and Nanomaterials</subject><subject>Lithium</subject><subject>Magnesium phosphate</subject><subject>Thermoluminescence</subject><issn>0036-0236</issn><issn>1531-8613</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1kEFLxDAQhYMoWFd_gLeA52omSZPmKMuuK1RWcD2XtJusXdpmTdqD_96UCh7E0zC8770ZHkK3QO4BGH94I4QJQpmgNA4qxRlKIGOQ5gLYOUomOZ30S3QVwpEQzonME8RW1pp6wM7idTs63_QGux7vPozvXDt2cQ-16WuDmx4Xzcvhdcuv0YXVbTA3P3OB3ter3XKTFtun5-VjkdYMxJCCFJYrmWkKmbZ5RYUCQg0ludQ8E8ZWspYR2isGKv5qsz23WlcqU0LmQrEFuptzT959jiYM5dGNvo8nS6oIcCEh55GCmaq9C8EbW55802n_VQIpp27KP91ED509IbL9wfjf5P9N32y0Ykw</recordid><startdate>20230201</startdate><enddate>20230201</enddate><creator>Kalinkin, M. O.</creator><creator>Akulov, D. A.</creator><creator>Gyrdasova, O. I.</creator><creator>Abashev, R. M.</creator><creator>Surdo, A. I.</creator><creator>Medvedeva, N. I.</creator><creator>Kellerman, D. G.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20230201</creationdate><title>Effect of Fluorine on Thermoluminescence in LiMgPO4</title><author>Kalinkin, M. O. ; Akulov, D. A. ; Gyrdasova, O. I. ; Abashev, R. M. ; Surdo, A. I. ; Medvedeva, N. I. ; Kellerman, D. G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-176f4975a215af8b269102e2087a456efb7c7176d9319153f5d4faab959678693</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Fluorine</topic><topic>Inorganic Chemistry</topic><topic>Inorganic Materials and Nanomaterials</topic><topic>Lithium</topic><topic>Magnesium phosphate</topic><topic>Thermoluminescence</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kalinkin, M. O.</creatorcontrib><creatorcontrib>Akulov, D. A.</creatorcontrib><creatorcontrib>Gyrdasova, O. I.</creatorcontrib><creatorcontrib>Abashev, R. M.</creatorcontrib><creatorcontrib>Surdo, A. I.</creatorcontrib><creatorcontrib>Medvedeva, N. I.</creatorcontrib><creatorcontrib>Kellerman, D. G.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kalinkin, M. O.</au><au>Akulov, D. A.</au><au>Gyrdasova, O. I.</au><au>Abashev, R. M.</au><au>Surdo, A. I.</au><au>Medvedeva, N. I.</au><au>Kellerman, D. G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of Fluorine on Thermoluminescence in LiMgPO4</atitle><jtitle>Russian journal of inorganic chemistry</jtitle><stitle>Russ. J. Inorg. Chem</stitle><date>2023-02-01</date><risdate>2023</risdate><volume>68</volume><issue>2</issue><spage>216</spage><epage>220</epage><pages>216-220</pages><issn>0036-0236</issn><eissn>1531-8613</eissn><abstract>Fluorine-doped lithium magnesium phosphate has been studied for the first time. It has been shown that fluorine significantly enhances the intensity of thermally stimulated luminescence. To find the preferred positions of fluorine and structural distortions caused by aliovalent substitution, ab initio calculations have been performed, which demonstrate that fluorine is not included into the (PO
4
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3–
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| subjects | Chemistry Chemistry and Materials Science Fluorine Inorganic Chemistry Inorganic Materials and Nanomaterials Lithium Magnesium phosphate Thermoluminescence |
| title | Effect of Fluorine on Thermoluminescence in LiMgPO4 |
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