Characterisation of Conventional 87Sr/86Sr Isotope Ratios in Cement, Limestone and Slate Reference Materials Based on an Interlaboratory Comparison Study

An interlaboratory comparison (ILC) was organised to characterise 87Sr/86Sr isotope ratios in geological and industrial reference materials by applying the so‐called conventional method for determining 87Sr/86Sr isotope ratios. Four cements (VDZ 100a, VDZ 200a, VDZ 300a, IAG OPC‐1), one limestone (I...

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Veröffentlicht in:Geostandards and geoanalytical research 2023-12, Vol.47 (4), p.821-840
Hauptverfasser: Kazlagić, Anera, Rosner, Martin, Cipriani, Anna, Frick, Daniel A., Glodny, Johannes, Hoffmann, Elis J., Hora, John M., Irrgeher, Johanna, Lugli, Federico, Magna, Tomas, Meisel, Thomas C., Meixner, Anette, Possolo, Antonio, Pramann, Axel, Pribil, Michael J., Prohaska, Thomas, Retzmann, Anika, Rienitz, Olaf, Rutherford, Daniel, Paula‐Santos, Gustavo M., Tatzel, Michael, Widhalm, Sara, Willbold, Matthias, Zuliani, Tea, Vogl, Jochen
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container_issue 4
container_start_page 821
container_title Geostandards and geoanalytical research
container_volume 47
creator Kazlagić, Anera
Rosner, Martin
Cipriani, Anna
Frick, Daniel A.
Glodny, Johannes
Hoffmann, Elis J.
Hora, John M.
Irrgeher, Johanna
Lugli, Federico
Magna, Tomas
Meisel, Thomas C.
Meixner, Anette
Possolo, Antonio
Pramann, Axel
Pribil, Michael J.
Prohaska, Thomas
Retzmann, Anika
Rienitz, Olaf
Rutherford, Daniel
Paula‐Santos, Gustavo M.
Tatzel, Michael
Widhalm, Sara
Willbold, Matthias
Zuliani, Tea
Vogl, Jochen
description An interlaboratory comparison (ILC) was organised to characterise 87Sr/86Sr isotope ratios in geological and industrial reference materials by applying the so‐called conventional method for determining 87Sr/86Sr isotope ratios. Four cements (VDZ 100a, VDZ 200a, VDZ 300a, IAG OPC‐1), one limestone (IAG CGL ML‐3) and one slate (IAG OU‐6) reference materials were selected, covering a wide range of naturally occurring Sr isotopic signatures. Thirteen laboratories received aliquots of these six reference materials together with a detailed technical protocol. The consensus values for the six reference materials and their associated measurement uncertainties were obtained by applying a Gaussian, linear mixed effects model fitted to all the measurement results. By combining the consensus values and their uncertainties with an uncertainty contribution for potential heterogeneity, reference values ranging from 0.708134 mol mol‐1 to 0.729778 mol mol‐1 were obtained with relative expanded uncertainties of ≤ 0.007 %. This study represents an ILC on conventional 87Sr/86Sr isotope ratios, within which metrological principles were considered and the compatibility of measurement results obtained by MC‐ICP‐MS and by MC‐TIMS is demonstrated. The materials characterised in this study can be used as reference materials for validation and quality control purposes and to estimate measurement uncertainties in conventional 87Sr/86Sr isotope ratio measurement. Key Points Interlaboratory comparison of 87Sr/86Sr isotope ratios in geological and industrial reference materials. Metrological principles were considered and relative measurement uncertainties of < 0.007 % were achieved. Compatibility of MC-TIMS and MC-ICP-MS was demonstrated.
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subjects cement
conventional method
geological material
Heterogeneity
interlaboratory comparison
isotope ratios
Isotopes
Limestone
MC‐ICP‐MS
MC‐TIMS
measurement uncertainty
Quality control
Ratios
Reference materials
Sr isotope analysis
Stone
Strontium isotopes
title Characterisation of Conventional 87Sr/86Sr Isotope Ratios in Cement, Limestone and Slate Reference Materials Based on an Interlaboratory Comparison Study
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