Synthesis, characterization and photoluminescence study of Nd3+/Ho3+ doped GdPO4 nanomaterials

The present study reports the preparation of nanomaterials by successful method of solvothermal synthesis of GdPO4:Nd3+/Ho3+which appear upconversion and downconversion nanomaterials in luminescence. These nanophosphors emit green and red color light whereas GdPO4: Nd3+/Ho3+downconversion peaks are...

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Veröffentlicht in:NeuroQuantology 2022-01, Vol.20 (9), p.2643
Hauptverfasser: Koneru, Girija Venkateswara, Bandi, Sirisha, Kolipaka Anjali Reddy, Dutta, Lakhyajit, Venkata Nagendra Kumar Putta
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container_start_page 2643
container_title NeuroQuantology
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creator Koneru, Girija Venkateswara
Bandi, Sirisha
Kolipaka Anjali Reddy
Dutta, Lakhyajit
Venkata Nagendra Kumar Putta
description The present study reports the preparation of nanomaterials by successful method of solvothermal synthesis of GdPO4:Nd3+/Ho3+which appear upconversion and downconversion nanomaterials in luminescence. These nanophosphors emit green and red color light whereas GdPO4: Nd3+/Ho3+downconversion peaks are observed at 460, 550, 672, and 791nm after excitation at 300nm and 532nm. We can observe a non-radiative resonance energy transfer take place along with the P-O CT (Charge Transfer) band of Holmium ions (Ho3+) there by improving emission of Ho3+ions we can also observed that upconversion (UC) nanophosphor GdPO4: Nd3+/Ho3+, this allows for large-scale luminescence creation and improvement. The upconversion emission spectra reveals a clear expectant peak at 550 & 791 nm, 672 and 791 nm of Ho3+ion on high 808 nm laser illumination is observed due to the presence of Nd3+.the method produce well crystalline nanoparticles with a range of a small number of nanometre’s to tens of nanometre’s as from the experimental study at 300nm & 532nm excitation, GdPO4: Nd3+/Ho3+ yielded. A high quantum yield value, indicating that these experimental studies have a wide range of applications for nanophosphor materials.
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subjects Charge transfer
Emission spectra
Energy transfer
Excitation
Gadolinium compounds
Holmium
Lanthanide phosphates
Luminescence
Nanomaterials
Nanophosphors
Photoluminescence
Synthesis
Upconversion
title Synthesis, characterization and photoluminescence study of Nd3+/Ho3+ doped GdPO4 nanomaterials
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