Towards high-performance nonlinear optical materials through embedding a D-A system into β-ketoenamine-linked COFs
Two covalent organic framework (COF) films supported by a glass substrate were obtained by solvothermal reaction of an electron donor with electron acceptor 1,3,5-triformylbenzene (TF) or 2,4,6-triformylphloroglucinol (TFP), respectively. The TFP-BD film exhibits a nonlinear absorption coefficient o...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2023-12, Vol.59 (99), p.14669-14672 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Li, Mingyan Chu, Jiahui Ding, Debo Li, Tingting Su, Endian Song, Yinglin Yang, Yun-Fang She, Yuanbin Jia, Jianhong |
| description | Two covalent organic framework (COF) films supported by a glass substrate were obtained by solvothermal reaction of an electron donor with electron acceptor 1,3,5-triformylbenzene (TF) or 2,4,6-triformylphloroglucinol (TFP), respectively. The
TFP-BD
film exhibits a nonlinear absorption coefficient of −3.01 × 10
5
cm GW
−1
. The
TFP-BD
film can aggregate electrons around the connected monomer through the D-A effect due to its highly polar and electronegative carbonyl oxygen atoms, thereby modulating the electronic structure of the COFs. This work provides a novel approach for the structural modulation of optical materials with strong nonlinearity.
Two covalent organic framework (COF) films supported by a glass substrate were obtained by solvothermal reaction of an electron donor with electron acceptor 1,3,5-triformylbenzene (TF) or 2,4,6-triformylphloroglucinol (TFP), respectively. |
| doi_str_mv | 10.1039/d3cc04845d |
| format | Article |
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TFP-BD
film exhibits a nonlinear absorption coefficient of −3.01 × 10
5
cm GW
−1
. The
TFP-BD
film can aggregate electrons around the connected monomer through the D-A effect due to its highly polar and electronegative carbonyl oxygen atoms, thereby modulating the electronic structure of the COFs. This work provides a novel approach for the structural modulation of optical materials with strong nonlinearity.
Two covalent organic framework (COF) films supported by a glass substrate were obtained by solvothermal reaction of an electron donor with electron acceptor 1,3,5-triformylbenzene (TF) or 2,4,6-triformylphloroglucinol (TFP), respectively.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/d3cc04845d</identifier><identifier>PMID: 37991933</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Absorptivity ; Carbonyls ; Electronegativity ; Electronic structure ; Electrons ; Glass substrates ; Nonlinear optics ; Nonlinearity ; Optical materials ; Oxygen atoms</subject><ispartof>Chemical communications (Cambridge, England), 2023-12, Vol.59 (99), p.14669-14672</ispartof><rights>Copyright Royal Society of Chemistry 2023</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c337t-8d3b37af36277e83bd386e5d3d5427b03a781ce81a6dbab1c65fe607065bd51a3</citedby><cites>FETCH-LOGICAL-c337t-8d3b37af36277e83bd386e5d3d5427b03a781ce81a6dbab1c65fe607065bd51a3</cites><orcidid>0000-0002-6287-1640 ; 0000-0002-5516-7372 ; 0000-0002-1352-7341 ; 0000-0002-1007-1852</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/37991933$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Li, Mingyan</creatorcontrib><creatorcontrib>Chu, Jiahui</creatorcontrib><creatorcontrib>Ding, Debo</creatorcontrib><creatorcontrib>Li, Tingting</creatorcontrib><creatorcontrib>Su, Endian</creatorcontrib><creatorcontrib>Song, Yinglin</creatorcontrib><creatorcontrib>Yang, Yun-Fang</creatorcontrib><creatorcontrib>She, Yuanbin</creatorcontrib><creatorcontrib>Jia, Jianhong</creatorcontrib><title>Towards high-performance nonlinear optical materials through embedding a D-A system into β-ketoenamine-linked COFs</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>Two covalent organic framework (COF) films supported by a glass substrate were obtained by solvothermal reaction of an electron donor with electron acceptor 1,3,5-triformylbenzene (TF) or 2,4,6-triformylphloroglucinol (TFP), respectively. The
TFP-BD
film exhibits a nonlinear absorption coefficient of −3.01 × 10
5
cm GW
−1
. The
TFP-BD
film can aggregate electrons around the connected monomer through the D-A effect due to its highly polar and electronegative carbonyl oxygen atoms, thereby modulating the electronic structure of the COFs. This work provides a novel approach for the structural modulation of optical materials with strong nonlinearity.
Two covalent organic framework (COF) films supported by a glass substrate were obtained by solvothermal reaction of an electron donor with electron acceptor 1,3,5-triformylbenzene (TF) or 2,4,6-triformylphloroglucinol (TFP), respectively.</description><subject>Absorptivity</subject><subject>Carbonyls</subject><subject>Electronegativity</subject><subject>Electronic structure</subject><subject>Electrons</subject><subject>Glass substrates</subject><subject>Nonlinear optics</subject><subject>Nonlinearity</subject><subject>Optical materials</subject><subject>Oxygen atoms</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpdkV1rFTEQhoMo9kNvvFcC3hQhmuxsPvay7LEqFHpTwbslm8yes-1uckx2kf4tf4i_ydRTKzg3MzAPD8O8hLwS_L3g0Hzw4ByvTS39E3IsQNVM1ubb0_tZNkxDLY_ISc43vJSQ5jk5At00ogE4Jvk6_rDJZ7obtzu2xzTENNvgkIYYpjGgTTTul9HZic52wTTaKdNll-K63VGce_R-DFtq6Yad03yXF5zpGJZIf_1kt7hEDHYuGlZct-hpe3WRX5BnQ7Hgy4d-Sr5efLxuP7PLq09f2vNL5gD0woyHHrQdQFVao4Heg1EoPXhZV7rnYLURDo2wyve2F07JARXXXMneS2HhlJwdvPsUv6-Yl24es8NpsgHjmrvKNFVTKyWgoG__Q2_imkK5rqsazlUtjeKFenegXIo5Jxy6fRpnm-46wbv7KLoNtO2fKDYFfvOgXPsZ_SP69_cFeH0AUnaP239Zwm-md472</recordid><startdate>20231212</startdate><enddate>20231212</enddate><creator>Li, Mingyan</creator><creator>Chu, Jiahui</creator><creator>Ding, Debo</creator><creator>Li, Tingting</creator><creator>Su, Endian</creator><creator>Song, Yinglin</creator><creator>Yang, Yun-Fang</creator><creator>She, Yuanbin</creator><creator>Jia, Jianhong</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-6287-1640</orcidid><orcidid>https://orcid.org/0000-0002-5516-7372</orcidid><orcidid>https://orcid.org/0000-0002-1352-7341</orcidid><orcidid>https://orcid.org/0000-0002-1007-1852</orcidid></search><sort><creationdate>20231212</creationdate><title>Towards high-performance nonlinear optical materials through embedding a D-A system into β-ketoenamine-linked COFs</title><author>Li, Mingyan ; Chu, Jiahui ; Ding, Debo ; Li, Tingting ; Su, Endian ; Song, Yinglin ; Yang, Yun-Fang ; She, Yuanbin ; Jia, Jianhong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-8d3b37af36277e83bd386e5d3d5427b03a781ce81a6dbab1c65fe607065bd51a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Absorptivity</topic><topic>Carbonyls</topic><topic>Electronegativity</topic><topic>Electronic structure</topic><topic>Electrons</topic><topic>Glass substrates</topic><topic>Nonlinear optics</topic><topic>Nonlinearity</topic><topic>Optical materials</topic><topic>Oxygen atoms</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Mingyan</creatorcontrib><creatorcontrib>Chu, Jiahui</creatorcontrib><creatorcontrib>Ding, Debo</creatorcontrib><creatorcontrib>Li, Tingting</creatorcontrib><creatorcontrib>Su, Endian</creatorcontrib><creatorcontrib>Song, Yinglin</creatorcontrib><creatorcontrib>Yang, Yun-Fang</creatorcontrib><creatorcontrib>She, Yuanbin</creatorcontrib><creatorcontrib>Jia, Jianhong</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Mingyan</au><au>Chu, Jiahui</au><au>Ding, Debo</au><au>Li, Tingting</au><au>Su, Endian</au><au>Song, Yinglin</au><au>Yang, Yun-Fang</au><au>She, Yuanbin</au><au>Jia, Jianhong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Towards high-performance nonlinear optical materials through embedding a D-A system into β-ketoenamine-linked COFs</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2023-12-12</date><risdate>2023</risdate><volume>59</volume><issue>99</issue><spage>14669</spage><epage>14672</epage><pages>14669-14672</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>Two covalent organic framework (COF) films supported by a glass substrate were obtained by solvothermal reaction of an electron donor with electron acceptor 1,3,5-triformylbenzene (TF) or 2,4,6-triformylphloroglucinol (TFP), respectively. The
TFP-BD
film exhibits a nonlinear absorption coefficient of −3.01 × 10
5
cm GW
−1
. The
TFP-BD
film can aggregate electrons around the connected monomer through the D-A effect due to its highly polar and electronegative carbonyl oxygen atoms, thereby modulating the electronic structure of the COFs. This work provides a novel approach for the structural modulation of optical materials with strong nonlinearity.
Two covalent organic framework (COF) films supported by a glass substrate were obtained by solvothermal reaction of an electron donor with electron acceptor 1,3,5-triformylbenzene (TF) or 2,4,6-triformylphloroglucinol (TFP), respectively.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>37991933</pmid><doi>10.1039/d3cc04845d</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-6287-1640</orcidid><orcidid>https://orcid.org/0000-0002-5516-7372</orcidid><orcidid>https://orcid.org/0000-0002-1352-7341</orcidid><orcidid>https://orcid.org/0000-0002-1007-1852</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2023-12, Vol.59 (99), p.14669-14672 |
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| language | eng |
| recordid | cdi_proquest_journals_2900645860 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Absorptivity Carbonyls Electronegativity Electronic structure Electrons Glass substrates Nonlinear optics Nonlinearity Optical materials Oxygen atoms |
| title | Towards high-performance nonlinear optical materials through embedding a D-A system into β-ketoenamine-linked COFs |
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