Understanding the Synergy between Fe and Mo Sites in the Nitrate Reduction Reaction on a Bio‐Inspired Bimetallic MXene Electrocatalyst

Mo‐ and Fe‐containing enzymes catalyze the reduction of nitrate and nitrite ions in nature. Inspired by this activity, we study here the nitrate reduction reaction (NO3RR) catalyzed by an Fe‐substituted two‐dimensional molybdenum carbide of the MXene family, viz., Mo2CTx : Fe (Tx are oxo, hydroxy an...

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Veröffentlicht in:	Angewandte Chemie 2023-12, Vol.135 (51), p.n/a
Hauptverfasser:	Abbott, Daniel F., Xu, Yuan‐Zi, Kuznetsov, Denis A., Kumar, Priyank, Müller, Christoph R., Fedorov, Alexey, Mougel, Victor
Format:	Artikel
Sprache:	eng
Schlagworte:	Absorption spectroscopy Ammonia Bimetals Chemical reduction Chemistry Density functional theory Electrocatalysis Electrocatalysts Enzymes In Situ X-Ray Absorption Spectroscopy Iron Molybdenum Molybdenum carbide MXene MXenes Nitrate reductase Nitrate Reduction Nitrates Oxygen transfer Reductases
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