Rücktitelbild: Mixed‐Valence CuI/CuIII Metal–Organic Frameworks with Non‐innocent Ligand for Multielectron Transfer (Angew. Chem. 50/2023)
Two novel Cu(I)/Cu(III) mixed‐valence metal–organic frameworks (MOFs) are synthesized from Cu(II) and redox‐non‐innocent ligand 1,4‐dicyano‐2,3,5,6‐tetrahydroxybenzene, as reported by Watchareeya Kaveevivitchai, Teng‐Hao Chen et al. in their Research Article (e202312494). The coordination between th...
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| Veröffentlicht in: | Angewandte Chemie 2023-12, Vol.135 (50), p.n/a |
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| creator | Fu, Shang‐Yuan Chang, Cheng‐Han Ivanov, Alexander S. Popovs, Ilja Chen, Jeng‐Lung Liao, Yen‐Fa Liu, Hsin‐Kuan Chirra, Suman Chiang, Yun‐Wei Lee, Jui‐Chin Liu, Wei‐Ling Kaveevivitchai, Watchareeya Chen, Teng‐Hao |
| description | Two novel Cu(I)/Cu(III) mixed‐valence metal–organic frameworks (MOFs) are synthesized from Cu(II) and redox‐non‐innocent ligand 1,4‐dicyano‐2,3,5,6‐tetrahydroxybenzene, as reported by Watchareeya Kaveevivitchai, Teng‐Hao Chen et al. in their Research Article (e202312494). The coordination between the mixed‐valence metal and redox‐non‐innocent ligand promotes through‐bond charge transfer between Cu metal sites, leading to semiconducting behavior and multielectron transfer. |
| doi_str_mv | 10.1002/ange.202315461 |
| format | Article |
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Chem. 50/2023)</title><title>Angewandte Chemie</title><description>Two novel Cu(I)/Cu(III) mixed‐valence metal–organic frameworks (MOFs) are synthesized from Cu(II) and redox‐non‐innocent ligand 1,4‐dicyano‐2,3,5,6‐tetrahydroxybenzene, as reported by Watchareeya Kaveevivitchai, Teng‐Hao Chen et al. in their Research Article (e202312494). The coordination between the mixed‐valence metal and redox‐non‐innocent ligand promotes through‐bond charge transfer between Cu metal sites, leading to semiconducting behavior and multielectron transfer.</description><subject>Charge transfer</subject><subject>Chemistry</subject><subject>Copper</subject><subject>Cu(I)/Cu(III)</subject><subject>Ligands</subject><subject>Metal-organic frameworks</subject><subject>Metals</subject><subject>Mixed-Valence</subject><subject>Non-innocent Ligand</subject><subject>Redox Chemistry</subject><issn>0044-8249</issn><issn>1521-3757</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNo9kM9Kw0AQxhdRsP65el7wooek-ye7m3grpdZCW0HUa9huJrptuqmbhOrNR1B8HW--SZ_ElIqHYRj4Zub7fgidURJSQlhXuycIGWGcikjSPdShgtGAK6H2UYeQKApiFiWH6Kiq5oQQyVTSQZ93P99mUdsaipktsis8sa-Qbd4_HnUBzgDuN6NuW6MRnkCti837161_0s4afO31EtalX1R4betnPC1du2edKw24Go9tK8twXno8aYraQgGm9qXD9167KgePL3qt43WI-8-wDLEg3a35yxN0kOuigtO_fowergf3_ZtgfDsc9XvjYEVpTANGZabEzERMGqmVSKSOlcwzwwnPhaDCAMRaSU5Um5Xnici0YDnomSIZMzN-jM53d1e-fGmgqtN52XjXvkxZnMRcykiSVpXsVGtbwFu68nap_VtKSbplnm6Zp__M0950OPif-C9B0nqr</recordid><startdate>20231211</startdate><enddate>20231211</enddate><creator>Fu, Shang‐Yuan</creator><creator>Chang, Cheng‐Han</creator><creator>Ivanov, Alexander S.</creator><creator>Popovs, Ilja</creator><creator>Chen, Jeng‐Lung</creator><creator>Liao, Yen‐Fa</creator><creator>Liu, Hsin‐Kuan</creator><creator>Chirra, Suman</creator><creator>Chiang, Yun‐Wei</creator><creator>Lee, Jui‐Chin</creator><creator>Liu, Wei‐Ling</creator><creator>Kaveevivitchai, Watchareeya</creator><creator>Chen, Teng‐Hao</creator><general>Wiley Subscription Services, Inc</general><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0001-9775-5909</orcidid><orcidid>https://orcid.org/0000-0001-9879-2162</orcidid></search><sort><creationdate>20231211</creationdate><title>Rücktitelbild: Mixed‐Valence CuI/CuIII Metal–Organic Frameworks with Non‐innocent Ligand for Multielectron Transfer (Angew. 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Chem. 50/2023)</atitle><jtitle>Angewandte Chemie</jtitle><date>2023-12-11</date><risdate>2023</risdate><volume>135</volume><issue>50</issue><epage>n/a</epage><issn>0044-8249</issn><eissn>1521-3757</eissn><abstract>Two novel Cu(I)/Cu(III) mixed‐valence metal–organic frameworks (MOFs) are synthesized from Cu(II) and redox‐non‐innocent ligand 1,4‐dicyano‐2,3,5,6‐tetrahydroxybenzene, as reported by Watchareeya Kaveevivitchai, Teng‐Hao Chen et al. in their Research Article (e202312494). The coordination between the mixed‐valence metal and redox‐non‐innocent ligand promotes through‐bond charge transfer between Cu metal sites, leading to semiconducting behavior and multielectron transfer.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/ange.202315461</doi><tpages>1</tpages><orcidid>https://orcid.org/0000-0001-9775-5909</orcidid><orcidid>https://orcid.org/0000-0001-9879-2162</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Charge transfer Chemistry Copper Cu(I)/Cu(III) Ligands Metal-organic frameworks Metals Mixed-Valence Non-innocent Ligand Redox Chemistry |
| title | Rücktitelbild: Mixed‐Valence CuI/CuIII Metal–Organic Frameworks with Non‐innocent Ligand for Multielectron Transfer (Angew. Chem. 50/2023) |
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