Adsorption of Arsenic and Lead From Phosphoric Acid Effluent Via 4A Zeolite: Statistical Experimental Design

The wet procedure is one of the prominent methods to produce phosphoric acid but unfortunately, remains the undesired components such as heavy metals in the final product. The aim of this work is to employ 4A zeolite adsorbent for the adsorption of lead and arsenic from the wet-process phosphoric ac...

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Veröffentlicht in:Water, air, and soil pollution air, and soil pollution, 2023-12, Vol.234 (12), p.764-764, Article 764
Hauptverfasser: Shahbazi, Javad, Fatehifar, Esmaeil, Daryani, Mohammad, Jodeiri, Naeimeh, Karimi, Asadollah
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container_start_page 764
container_title Water, air, and soil pollution
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creator Shahbazi, Javad
Fatehifar, Esmaeil
Daryani, Mohammad
Jodeiri, Naeimeh
Karimi, Asadollah
description The wet procedure is one of the prominent methods to produce phosphoric acid but unfortunately, remains the undesired components such as heavy metals in the final product. The aim of this work is to employ 4A zeolite adsorbent for the adsorption of lead and arsenic from the wet-process phosphoric acid. The Taguchi methodology was used to improve the processing quality and optimize design factors. Three operational factors of the concentrations of lead and arsenic, adsorbent dosage, and pH were chosen as variables of the experimental design. The batch adsorption method was applied to remove heavy metals. The results make it clear that the adsorption process of heavy metals is significantly affected by the pH of the solution, the heavy metals concentration, and lastly, by the adsorbent dosage. The adsorption mechanism has been surveyed using two adsorption isotherm models (the Langmuir and the Freundlich isotherm). The consequence demonstrated that the Langmuir model more excellently and effectively illustrates the experimental results compared to the Freundlich model. The equilibrium time for removal of arsenic and lead was found to be 140 min and 100 min, respectively. Using the experiment setting optimized by the Taguchi method, a 99% reduction in both pollutant concentrations was achieved by the adsorption process. By using analysis of variance and signal-to-noise ratio, the impact of the effect of each parameter on the response and the error rate based on a 95% confidence interval was obtained.
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subjects Adsorbents
Adsorption
air
analysis of variance
Arsenic
Atmospheric Protection/Air Quality Control/Air Pollution
Climate Change/Climate Change Impacts
confidence interval
Confidence intervals
Design
Design factors
Design of experiments
Design optimization
Dosage
Earth and Environmental Science
Environment
Environmental monitoring
Experimental design
Heavy metals
Hydrogeology
Isotherms
Lead
Metal concentrations
Metals
Phosphates
Phosphoric acid
Pollutant removal
pollutants
Production methods
Signal to noise ratio
soil
Soil Science & Conservation
sorption isotherms
Statistical analysis
Taguchi method
Taguchi methods
Variance analysis
water
Water Quality/Water Pollution
Zeolites
title Adsorption of Arsenic and Lead From Phosphoric Acid Effluent Via 4A Zeolite: Statistical Experimental Design
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