Structural, vibrational, optical and second harmonic generation studies of urea doped single KDP crystals grown by Sankaranarayanan–Ramasamy technique

The method of cooling aqueous solution and the Sankaranarayanan–Ramasamy technique were used for the preparation of urea doped KDP single crystals with additive concentrations of 0.1, 0.5, and 1 mol%. The single crystals were grown unidirectionally from seeds that were inclined to type I phase-match...

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Veröffentlicht in:Optical and quantum electronics 2024, Vol.56 (1), Article 70
Hauptverfasser: Phan, Vinh Trung, Nguyen, Vung Thanh, Nguyen, Bao Le Quoc
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description The method of cooling aqueous solution and the Sankaranarayanan–Ramasamy technique were used for the preparation of urea doped KDP single crystals with additive concentrations of 0.1, 0.5, and 1 mol%. The single crystals were grown unidirectionally from seeds that were inclined to type I phase-matching angle, the requirement for maximal second harmonic generation (SHG) efficiency. The analysis employed to study the chemical composition, crystal structure, bonding vibrations, and optical properties of the crystal samples was energy-dispersive X-ray spectroscopy, X-ray diffraction patterns, Raman spectroscopy, ultraviolet-visible spectroscopy, and SHG measurement respectively. The differences in chemical composition, crystal structure, optical transmittance, and SHG efficiency of the parts on each urea doped KDP single crystal rod were explained by the variation in the growth sector boundary. This work aims to improve the second-order nonlinear optical coefficient of KDP crystals and suggests which part of the urea doped KDP crystal rod grown by the SR technique is most acceptable for frequency-doubling applications.
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subjects Aqueous solutions
Characterization and Evaluation of Materials
Chemical composition
Computer Communication Networks
Crystal growth
Crystal structure
Diffraction patterns
Electrical Engineering
KDP crystals
Lasers
Nonlinear optics
Optical Devices
Optical properties
Optics
Phase matching
Photonics
Physics
Physics and Astronomy
Raman spectroscopy
Second harmonic generation
Single crystals
Spectrum analysis
Ureas
title Structural, vibrational, optical and second harmonic generation studies of urea doped single KDP crystals grown by Sankaranarayanan–Ramasamy technique
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