Preparation and Properties of Transparent Scandium Oxide-Modified Nd:YAG Ceramics
— We have studied the effect of Sc 2 O 3 as a modifying additive on the formation of weakly agglomerated single-phase nanopowders of doped yttrium aluminum garnet with the laser composition Y 2.97 Nd 0.03 ScAl 4 O 12 (Nd:YSAG), the fundamental aspects of the preparation of transparent ceramics from...
Gespeichert in:
| Veröffentlicht in: | Inorganic materials 2023-05, Vol.59 (5), p.530-536 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 536 |
|---|---|
| container_issue | 5 |
| container_start_page | 530 |
| container_title | Inorganic materials |
| container_volume | 59 |
| creator | Kolomiets, T. Yu Tel’nova, G. B. Ashmarin, A. A. Solntsev, K. A. |
| description | —
We have studied the effect of Sc
2
O
3
as a modifying additive on the formation of weakly agglomerated single-phase nanopowders of doped yttrium aluminum garnet with the laser composition Y
2.97
Nd
0.03
ScAl
4
O
12
(Nd:YSAG), the fundamental aspects of the preparation of transparent ceramics from the modified powders, and the microstructure and properties of the ceramics. Carbonate precursor powders with a specific surface area of 285 m
2
/g, synthesized via quantitative chemical coprecipitation of metal cations from an aqueous solution of hydrochloric acid salts in the presence of high molecular weight surfactants have been characterized by high-temperature X-ray diffraction. The results demonstrate for the first time that, during the thermal decomposition of the carbonate precursor, the structure of Nd:YSAG is formed in the temperature range 850–1000°C in the form of a metastable nonstoichiometric cubic aluminate, (Y,Nd)Sc
x
Al
1–
x
O
3
, with a garnet-like structure. In the range 1100–1150°C, it reacts with the Al
2
O
3
resulting from the decomposition of the precursor to form Nd:YSAG. The synthesized weakly agglomerated spherical nanoparticles and submicron particles with a controlled stable size in the range 100 to 200 nm were vacuum-sintered to give transparent ceramics with an average grain size of 3 μm and high transmission (up to 78%) in the visible spectral region. |
| doi_str_mv | 10.1134/S0020168523050072 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2896315846</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2896315846</sourcerecordid><originalsourceid>FETCH-LOGICAL-c268t-f394cf6948499c4dfe1b31ad1eb658c378f2d7ae14ec20356efb84224732665f3</originalsourceid><addsrcrecordid>eNp1kE1LAzEURYMoWKs_wF3A9Wi-J-OuFK1CtZXWhashTV4kxU7GZAr13zulggtx9RbnnvvgInRJyTWlXNwsCGGEKi0ZJ5KQkh2hAVVEF5yW7BgN9rjY81N0lvOaECKkrgboZZ6gNcl0ITbYNA7PU2whdQEyjh4vk2lyz6Hp8ML2PGw3eLYLDoqn6IIP4PCzu30bTfAYktkEm8_RiTcfGS5-7hC93t8txw_FdDZ5HI-mhWVKd4XnlbBeVUKLqrLCeaArTo2jsFJSW15qz1xpgAqwjHCpwK-0YEyUnCklPR-iq0Nvm-LnFnJXr-M2Nf3LmulKcSq1UH2KHlI2xZwT-LpNYWPSV01JvV-u_rNc77CDk_ts8w7pt_l_6Rt4uW6M</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2896315846</pqid></control><display><type>article</type><title>Preparation and Properties of Transparent Scandium Oxide-Modified Nd:YAG Ceramics</title><source>Springer Nature - Complete Springer Journals</source><creator>Kolomiets, T. Yu ; Tel’nova, G. B. ; Ashmarin, A. A. ; Solntsev, K. A.</creator><creatorcontrib>Kolomiets, T. Yu ; Tel’nova, G. B. ; Ashmarin, A. A. ; Solntsev, K. A.</creatorcontrib><description>—
We have studied the effect of Sc
2
O
3
as a modifying additive on the formation of weakly agglomerated single-phase nanopowders of doped yttrium aluminum garnet with the laser composition Y
2.97
Nd
0.03
ScAl
4
O
12
(Nd:YSAG), the fundamental aspects of the preparation of transparent ceramics from the modified powders, and the microstructure and properties of the ceramics. Carbonate precursor powders with a specific surface area of 285 m
2
/g, synthesized via quantitative chemical coprecipitation of metal cations from an aqueous solution of hydrochloric acid salts in the presence of high molecular weight surfactants have been characterized by high-temperature X-ray diffraction. The results demonstrate for the first time that, during the thermal decomposition of the carbonate precursor, the structure of Nd:YSAG is formed in the temperature range 850–1000°C in the form of a metastable nonstoichiometric cubic aluminate, (Y,Nd)Sc
x
Al
1–
x
O
3
, with a garnet-like structure. In the range 1100–1150°C, it reacts with the Al
2
O
3
resulting from the decomposition of the precursor to form Nd:YSAG. The synthesized weakly agglomerated spherical nanoparticles and submicron particles with a controlled stable size in the range 100 to 200 nm were vacuum-sintered to give transparent ceramics with an average grain size of 3 μm and high transmission (up to 78%) in the visible spectral region.</description><identifier>ISSN: 0020-1685</identifier><identifier>EISSN: 1608-3172</identifier><identifier>DOI: 10.1134/S0020168523050072</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Aluminum oxide ; Aqueous solutions ; Ceramics ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Decomposition reactions ; Grain size ; High temperature ; Hydrochloric acid ; Industrial Chemistry/Chemical Engineering ; Inorganic Chemistry ; Materials Science ; Nanoparticles ; Precursors ; Scandium oxides ; Sintering (powder metallurgy) ; Thermal decomposition ; YAG lasers ; Yttrium</subject><ispartof>Inorganic materials, 2023-05, Vol.59 (5), p.530-536</ispartof><rights>Pleiades Publishing, Ltd. 2023. ISSN 0020-1685, Inorganic Materials, 2023, Vol. 59, No. 5, pp. 530–536. © Pleiades Publishing, Ltd., 2023. Russian Text © The Author(s), 2023, published in Neorganicheskie Materialy, 2023, Vol. 59, No. 5, pp. 552–558.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-f394cf6948499c4dfe1b31ad1eb658c378f2d7ae14ec20356efb84224732665f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0020168523050072$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0020168523050072$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Kolomiets, T. Yu</creatorcontrib><creatorcontrib>Tel’nova, G. B.</creatorcontrib><creatorcontrib>Ashmarin, A. A.</creatorcontrib><creatorcontrib>Solntsev, K. A.</creatorcontrib><title>Preparation and Properties of Transparent Scandium Oxide-Modified Nd:YAG Ceramics</title><title>Inorganic materials</title><addtitle>Inorg Mater</addtitle><description>—
We have studied the effect of Sc
2
O
3
as a modifying additive on the formation of weakly agglomerated single-phase nanopowders of doped yttrium aluminum garnet with the laser composition Y
2.97
Nd
0.03
ScAl
4
O
12
(Nd:YSAG), the fundamental aspects of the preparation of transparent ceramics from the modified powders, and the microstructure and properties of the ceramics. Carbonate precursor powders with a specific surface area of 285 m
2
/g, synthesized via quantitative chemical coprecipitation of metal cations from an aqueous solution of hydrochloric acid salts in the presence of high molecular weight surfactants have been characterized by high-temperature X-ray diffraction. The results demonstrate for the first time that, during the thermal decomposition of the carbonate precursor, the structure of Nd:YSAG is formed in the temperature range 850–1000°C in the form of a metastable nonstoichiometric cubic aluminate, (Y,Nd)Sc
x
Al
1–
x
O
3
, with a garnet-like structure. In the range 1100–1150°C, it reacts with the Al
2
O
3
resulting from the decomposition of the precursor to form Nd:YSAG. The synthesized weakly agglomerated spherical nanoparticles and submicron particles with a controlled stable size in the range 100 to 200 nm were vacuum-sintered to give transparent ceramics with an average grain size of 3 μm and high transmission (up to 78%) in the visible spectral region.</description><subject>Aluminum oxide</subject><subject>Aqueous solutions</subject><subject>Ceramics</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Decomposition reactions</subject><subject>Grain size</subject><subject>High temperature</subject><subject>Hydrochloric acid</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Inorganic Chemistry</subject><subject>Materials Science</subject><subject>Nanoparticles</subject><subject>Precursors</subject><subject>Scandium oxides</subject><subject>Sintering (powder metallurgy)</subject><subject>Thermal decomposition</subject><subject>YAG lasers</subject><subject>Yttrium</subject><issn>0020-1685</issn><issn>1608-3172</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1kE1LAzEURYMoWKs_wF3A9Wi-J-OuFK1CtZXWhashTV4kxU7GZAr13zulggtx9RbnnvvgInRJyTWlXNwsCGGEKi0ZJ5KQkh2hAVVEF5yW7BgN9rjY81N0lvOaECKkrgboZZ6gNcl0ITbYNA7PU2whdQEyjh4vk2lyz6Hp8ML2PGw3eLYLDoqn6IIP4PCzu30bTfAYktkEm8_RiTcfGS5-7hC93t8txw_FdDZ5HI-mhWVKd4XnlbBeVUKLqrLCeaArTo2jsFJSW15qz1xpgAqwjHCpwK-0YEyUnCklPR-iq0Nvm-LnFnJXr-M2Nf3LmulKcSq1UH2KHlI2xZwT-LpNYWPSV01JvV-u_rNc77CDk_ts8w7pt_l_6Rt4uW6M</recordid><startdate>20230501</startdate><enddate>20230501</enddate><creator>Kolomiets, T. Yu</creator><creator>Tel’nova, G. B.</creator><creator>Ashmarin, A. A.</creator><creator>Solntsev, K. A.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20230501</creationdate><title>Preparation and Properties of Transparent Scandium Oxide-Modified Nd:YAG Ceramics</title><author>Kolomiets, T. Yu ; Tel’nova, G. B. ; Ashmarin, A. A. ; Solntsev, K. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-f394cf6948499c4dfe1b31ad1eb658c378f2d7ae14ec20356efb84224732665f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Aluminum oxide</topic><topic>Aqueous solutions</topic><topic>Ceramics</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Decomposition reactions</topic><topic>Grain size</topic><topic>High temperature</topic><topic>Hydrochloric acid</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Inorganic Chemistry</topic><topic>Materials Science</topic><topic>Nanoparticles</topic><topic>Precursors</topic><topic>Scandium oxides</topic><topic>Sintering (powder metallurgy)</topic><topic>Thermal decomposition</topic><topic>YAG lasers</topic><topic>Yttrium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kolomiets, T. Yu</creatorcontrib><creatorcontrib>Tel’nova, G. B.</creatorcontrib><creatorcontrib>Ashmarin, A. A.</creatorcontrib><creatorcontrib>Solntsev, K. A.</creatorcontrib><collection>CrossRef</collection><jtitle>Inorganic materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kolomiets, T. Yu</au><au>Tel’nova, G. B.</au><au>Ashmarin, A. A.</au><au>Solntsev, K. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation and Properties of Transparent Scandium Oxide-Modified Nd:YAG Ceramics</atitle><jtitle>Inorganic materials</jtitle><stitle>Inorg Mater</stitle><date>2023-05-01</date><risdate>2023</risdate><volume>59</volume><issue>5</issue><spage>530</spage><epage>536</epage><pages>530-536</pages><issn>0020-1685</issn><eissn>1608-3172</eissn><abstract>—
We have studied the effect of Sc
2
O
3
as a modifying additive on the formation of weakly agglomerated single-phase nanopowders of doped yttrium aluminum garnet with the laser composition Y
2.97
Nd
0.03
ScAl
4
O
12
(Nd:YSAG), the fundamental aspects of the preparation of transparent ceramics from the modified powders, and the microstructure and properties of the ceramics. Carbonate precursor powders with a specific surface area of 285 m
2
/g, synthesized via quantitative chemical coprecipitation of metal cations from an aqueous solution of hydrochloric acid salts in the presence of high molecular weight surfactants have been characterized by high-temperature X-ray diffraction. The results demonstrate for the first time that, during the thermal decomposition of the carbonate precursor, the structure of Nd:YSAG is formed in the temperature range 850–1000°C in the form of a metastable nonstoichiometric cubic aluminate, (Y,Nd)Sc
x
Al
1–
x
O
3
, with a garnet-like structure. In the range 1100–1150°C, it reacts with the Al
2
O
3
resulting from the decomposition of the precursor to form Nd:YSAG. The synthesized weakly agglomerated spherical nanoparticles and submicron particles with a controlled stable size in the range 100 to 200 nm were vacuum-sintered to give transparent ceramics with an average grain size of 3 μm and high transmission (up to 78%) in the visible spectral region.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0020168523050072</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0020-1685 |
| ispartof | Inorganic materials, 2023-05, Vol.59 (5), p.530-536 |
| issn | 0020-1685 1608-3172 |
| language | eng |
| recordid | cdi_proquest_journals_2896315846 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Aluminum oxide Aqueous solutions Ceramics Chemical synthesis Chemistry Chemistry and Materials Science Decomposition reactions Grain size High temperature Hydrochloric acid Industrial Chemistry/Chemical Engineering Inorganic Chemistry Materials Science Nanoparticles Precursors Scandium oxides Sintering (powder metallurgy) Thermal decomposition YAG lasers Yttrium |
| title | Preparation and Properties of Transparent Scandium Oxide-Modified Nd:YAG Ceramics |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-27T16%3A07%3A41IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Preparation%20and%20Properties%20of%20Transparent%20Scandium%20Oxide-Modified%20Nd:YAG%20Ceramics&rft.jtitle=Inorganic%20materials&rft.au=Kolomiets,%20T.%20Yu&rft.date=2023-05-01&rft.volume=59&rft.issue=5&rft.spage=530&rft.epage=536&rft.pages=530-536&rft.issn=0020-1685&rft.eissn=1608-3172&rft_id=info:doi/10.1134/S0020168523050072&rft_dat=%3Cproquest_cross%3E2896315846%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2896315846&rft_id=info:pmid/&rfr_iscdi=true |