Tuning humidity for highly selective detection of methanol and 2-butanone using MOF-derivatives NiO microrods
Industrialization has brought about significant challenges to human well-being, primarily due to the emission of toxic volatile organic compounds (VOCs). Therefore, there is considerable interest and need to detect these VOCs with high selectivity and reproducibility. In this context, developing VOC...
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| Veröffentlicht in: | Journal of materials science. Materials in electronics 2023-12, Vol.34 (34), p.2232, Article 2232 |
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| creator | Theodoro, Reinaldo S. Sá, Bruna S. Perrone, Olavo M. Perfecto, Tarcísio M. Volanti, Diogo P. |
| description | Industrialization has brought about significant challenges to human well-being, primarily due to the emission of toxic volatile organic compounds (VOCs). Therefore, there is considerable interest and need to detect these VOCs with high selectivity and reproducibility. In this context, developing VOC sensing devices for continuous environmental monitoring and ensuring well-being is crucial. One way to produce inexpensive sensors with reasonable detection limits and selectivity is by using semiconductor metal oxides. Furthermore, they can withstand relative humidity variations in the detection process, which is still a significant challenge. In this study, we present a sensor based on NiO microrods derived from the decomposition of nickel-metal-organic frameworks (Ni-MOF) using microwave-assisted solvothermal (MAS) and thermal decomposition methods. The NiO microrods exhibited highly selective in detecting methanol (Response = 143 ± 27%) under dry atmospheric conditions and 2-butanone (Response = 119 ± 16%) under wet atmospheric conditions (43% RH) at a working temperature of 150 °C. In addition, the NiO sensor presented a relatively fast response time for detecting methanol (78 s) and 2-butanone (36 s) under optimal working conditions. Therefore, selectively modulating the relative humidity during the sensor analysis process, the NiO microrods act as a dual-mode sensor for methanol and 2-butanone. |
| doi_str_mv | 10.1007/s10854-023-11665-3 |
| format | Article |
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In addition, the NiO sensor presented a relatively fast response time for detecting methanol (78 s) and 2-butanone (36 s) under optimal working conditions. Therefore, selectively modulating the relative humidity during the sensor analysis process, the NiO microrods act as a dual-mode sensor for methanol and 2-butanone.</description><identifier>ISSN: 0957-4522</identifier><identifier>EISSN: 1573-482X</identifier><identifier>DOI: 10.1007/s10854-023-11665-3</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Environmental monitoring ; Humidity ; Materials Science ; Metal oxides ; Metal-organic frameworks ; Methanol ; Nickel oxides ; Optical and Electronic Materials ; Relative humidity ; Selectivity ; Sensors ; Thermal decomposition ; VOCs ; Volatile organic compounds</subject><ispartof>Journal of materials science. 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Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-f2fe30db48f0b6199bbd654532c502e7efe9199355c567d577d1a69076078b293</citedby><cites>FETCH-LOGICAL-c319t-f2fe30db48f0b6199bbd654532c502e7efe9199355c567d577d1a69076078b293</cites><orcidid>0000-0001-9315-9392</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10854-023-11665-3$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10854-023-11665-3$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Theodoro, Reinaldo S.</creatorcontrib><creatorcontrib>Sá, Bruna S.</creatorcontrib><creatorcontrib>Perrone, Olavo M.</creatorcontrib><creatorcontrib>Perfecto, Tarcísio M.</creatorcontrib><creatorcontrib>Volanti, Diogo P.</creatorcontrib><title>Tuning humidity for highly selective detection of methanol and 2-butanone using MOF-derivatives NiO microrods</title><title>Journal of materials science. 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The NiO microrods exhibited highly selective in detecting methanol (Response = 143 ± 27%) under dry atmospheric conditions and 2-butanone (Response = 119 ± 16%) under wet atmospheric conditions (43% RH) at a working temperature of 150 °C. In addition, the NiO sensor presented a relatively fast response time for detecting methanol (78 s) and 2-butanone (36 s) under optimal working conditions. 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| subjects | Characterization and Evaluation of Materials Chemistry and Materials Science Environmental monitoring Humidity Materials Science Metal oxides Metal-organic frameworks Methanol Nickel oxides Optical and Electronic Materials Relative humidity Selectivity Sensors Thermal decomposition VOCs Volatile organic compounds |
| title | Tuning humidity for highly selective detection of methanol and 2-butanone using MOF-derivatives NiO microrods |
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