Crystal Structures of Two Metal-Organic Frameworks Based on Zn(II) and 2,5-Diiodoterephthalate
Three-dimensional coordination polymers Cat 2 [{Zn 4 O} 2 (H 2 O) 2 (2,5-I-bdc) 7 ] ( 1 ) (2,5-I-bdc = 2,5-diiodoterephthalate, Cat is dimethylammonium) and [Zn 2 (2,5-I-bdc) 2 dabco] ( 2 ) (dabco is 1,4-diazobicyclo [2.2.2]octane) are prepared. The structures of 1 and 2 are determined by single cry...
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| Veröffentlicht in: | Journal of structural chemistry 2023-11, Vol.64 (11), p.2157-2166 |
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| container_end_page | 2166 |
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| container_issue | 11 |
| container_start_page | 2157 |
| container_title | Journal of structural chemistry |
| container_volume | 64 |
| creator | Zaguzin, A. S. Bondarenko, M. A. Sukhikh, T. S. Fedin, V. P. Adonin, S. A. |
| description | Three-dimensional coordination polymers Cat
2
[{Zn
4
O}
2
(H
2
O)
2
(2,5-I-bdc)
7
] (
1
) (2,5-I-bdc = 2,5-diiodoterephthalate, Cat is dimethylammonium) and [Zn
2
(2,5-I-bdc)
2
dabco] (
2
) (dabco is 1,4-diazobicyclo [2.2.2]octane) are prepared. The structures of
1
and
2
are determined by single crystal X-ray diffraction. It is shown that the structure of
2
has a halogen bond between guest DMF molecules and the MOF iodine atom. The I⋯O distances are 2.93-3.03 Å. |
| doi_str_mv | 10.1134/S0022476623110136 |
| format | Article |
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2
[{Zn
4
O}
2
(H
2
O)
2
(2,5-I-bdc)
7
] (
1
) (2,5-I-bdc = 2,5-diiodoterephthalate, Cat is dimethylammonium) and [Zn
2
(2,5-I-bdc)
2
dabco] (
2
) (dabco is 1,4-diazobicyclo [2.2.2]octane) are prepared. The structures of
1
and
2
are determined by single crystal X-ray diffraction. It is shown that the structure of
2
has a halogen bond between guest DMF molecules and the MOF iodine atom. The I⋯O distances are 2.93-3.03 Å.</description><identifier>ISSN: 0022-4766</identifier><identifier>EISSN: 1573-8779</identifier><identifier>DOI: 10.1134/S0022476623110136</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Atomic ; Atomic/Molecular Structure and Spectra ; Chemical bonds ; Chemistry ; Chemistry and Materials Science ; Coordination polymers ; Inorganic Chemistry ; Iodine ; Metal-organic frameworks ; Molecular ; Optical and Plasma Physics ; Physical Chemistry ; Single crystals ; Solid State Physics</subject><ispartof>Journal of structural chemistry, 2023-11, Vol.64 (11), p.2157-2166</ispartof><rights>Pleiades Publishing, Ltd. 2023</rights><rights>Pleiades Publishing, Ltd. 2023.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-440a08abe68c5a08bab00504d87d626ec0103758d1b31c636b1d35fcfa82dfa33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0022476623110136$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0022476623110136$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids></links><search><creatorcontrib>Zaguzin, A. S.</creatorcontrib><creatorcontrib>Bondarenko, M. A.</creatorcontrib><creatorcontrib>Sukhikh, T. S.</creatorcontrib><creatorcontrib>Fedin, V. P.</creatorcontrib><creatorcontrib>Adonin, S. A.</creatorcontrib><title>Crystal Structures of Two Metal-Organic Frameworks Based on Zn(II) and 2,5-Diiodoterephthalate</title><title>Journal of structural chemistry</title><addtitle>J Struct Chem</addtitle><description>Three-dimensional coordination polymers Cat
2
[{Zn
4
O}
2
(H
2
O)
2
(2,5-I-bdc)
7
] (
1
) (2,5-I-bdc = 2,5-diiodoterephthalate, Cat is dimethylammonium) and [Zn
2
(2,5-I-bdc)
2
dabco] (
2
) (dabco is 1,4-diazobicyclo [2.2.2]octane) are prepared. The structures of
1
and
2
are determined by single crystal X-ray diffraction. It is shown that the structure of
2
has a halogen bond between guest DMF molecules and the MOF iodine atom. The I⋯O distances are 2.93-3.03 Å.</description><subject>Atomic</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Chemical bonds</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coordination polymers</subject><subject>Inorganic Chemistry</subject><subject>Iodine</subject><subject>Metal-organic frameworks</subject><subject>Molecular</subject><subject>Optical and Plasma Physics</subject><subject>Physical Chemistry</subject><subject>Single crystals</subject><subject>Solid State Physics</subject><issn>0022-4766</issn><issn>1573-8779</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1kM9LwzAUx4MoOKd_gLeAFwWrL0mbpkedTgfKDpsXD5Y0SbfOrZlJyth_b8YED-LpPd73x4MPQucEbghh6e0EgNI055wyQoAwfoB6JMtZIvK8OES9nZzs9GN04v0CAApR8B76GLitD3KJJ8F1KnTOeGxrPN1Y_GriPRm7mWwbhYdOrszGuk-P76U3GtsWv7eXo9EVlq3G9DpLHprGahuMM-t5mMulDOYUHdVy6c3Zz-yjt-HjdPCcvIyfRoO7l0RRLkKSpiBByMpwobK4VbICyCDVIteccqOAAMszoUnFiOKMV0SzrFa1FFTXkrE-utj3rp396owP5cJ2ro0vSyqKjJEIpogusncpZ713pi7XrllJty0JlDuM5R-MMUP3GR-97cy43-b_Q999LXK9</recordid><startdate>20231101</startdate><enddate>20231101</enddate><creator>Zaguzin, A. S.</creator><creator>Bondarenko, M. A.</creator><creator>Sukhikh, T. S.</creator><creator>Fedin, V. P.</creator><creator>Adonin, S. A.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20231101</creationdate><title>Crystal Structures of Two Metal-Organic Frameworks Based on Zn(II) and 2,5-Diiodoterephthalate</title><author>Zaguzin, A. S. ; Bondarenko, M. A. ; Sukhikh, T. S. ; Fedin, V. P. ; Adonin, S. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-440a08abe68c5a08bab00504d87d626ec0103758d1b31c636b1d35fcfa82dfa33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Atomic</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Chemical bonds</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coordination polymers</topic><topic>Inorganic Chemistry</topic><topic>Iodine</topic><topic>Metal-organic frameworks</topic><topic>Molecular</topic><topic>Optical and Plasma Physics</topic><topic>Physical Chemistry</topic><topic>Single crystals</topic><topic>Solid State Physics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zaguzin, A. S.</creatorcontrib><creatorcontrib>Bondarenko, M. A.</creatorcontrib><creatorcontrib>Sukhikh, T. S.</creatorcontrib><creatorcontrib>Fedin, V. P.</creatorcontrib><creatorcontrib>Adonin, S. A.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of structural chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zaguzin, A. S.</au><au>Bondarenko, M. A.</au><au>Sukhikh, T. S.</au><au>Fedin, V. P.</au><au>Adonin, S. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Crystal Structures of Two Metal-Organic Frameworks Based on Zn(II) and 2,5-Diiodoterephthalate</atitle><jtitle>Journal of structural chemistry</jtitle><stitle>J Struct Chem</stitle><date>2023-11-01</date><risdate>2023</risdate><volume>64</volume><issue>11</issue><spage>2157</spage><epage>2166</epage><pages>2157-2166</pages><issn>0022-4766</issn><eissn>1573-8779</eissn><abstract>Three-dimensional coordination polymers Cat
2
[{Zn
4
O}
2
(H
2
O)
2
(2,5-I-bdc)
7
] (
1
) (2,5-I-bdc = 2,5-diiodoterephthalate, Cat is dimethylammonium) and [Zn
2
(2,5-I-bdc)
2
dabco] (
2
) (dabco is 1,4-diazobicyclo [2.2.2]octane) are prepared. The structures of
1
and
2
are determined by single crystal X-ray diffraction. It is shown that the structure of
2
has a halogen bond between guest DMF molecules and the MOF iodine atom. The I⋯O distances are 2.93-3.03 Å.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0022476623110136</doi><tpages>10</tpages></addata></record> |
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| language | eng |
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| source | SpringerLink Journals |
| subjects | Atomic Atomic/Molecular Structure and Spectra Chemical bonds Chemistry Chemistry and Materials Science Coordination polymers Inorganic Chemistry Iodine Metal-organic frameworks Molecular Optical and Plasma Physics Physical Chemistry Single crystals Solid State Physics |
| title | Crystal Structures of Two Metal-Organic Frameworks Based on Zn(II) and 2,5-Diiodoterephthalate |
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