Kinetic Delay in Cooperative Supramolecular Polymerization by Redefining the Trade‐Off Relationship between H‐Bonds and Van der Waals/π–π Stacking Interactions

We here present how rebalancing the interplay between H‐bonds and dispersive forces (Van der Waals/π–π stacking) may induce or not the generation of kinetic metastable states. In particular, we show that extending the aromatic content and favouring the interchain VdW interactions causes a delay into...

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Veröffentlicht in:	Angewandte Chemie 2023-12, Vol.135 (49), p.n/a
Hauptverfasser:	Gallonde, William T., Poidevin, Corentin, Houard, Felix, Caytan, Elsa, Dorcet, Vincent, Fihey, Arnaud, Bernot, Kevin, Rigaut, Stéphane, Galangau, Olivier
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Cooperativity Hydrogen Bonding Metastable state Pathway Complexity Polymerization Self-Assembly Stacking Supramolecular Polymer Toluene
Online-Zugang:	Volltext
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