Geometrically Compelled Silicon(II)/Silicon(IV) Donor–Acceptor Interaction Enables the Enamination of Nitriles

Discovering new bonding scenarios and subsequently exploring the reactivity contribute substantially to advance the main group element chemistry. Herein, we report on the isolation and characterization of an intriguing class of the hydrido‐benzosiloles 2–4. These compounds exhibit a side arm of the...

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Veröffentlicht in:	Angewandte Chemie 2023-12, Vol.135 (49), p.n/a
Hauptverfasser:	Kong, Deliang, Li, Jiancheng, Dai, Wen, Jiang, Liuying, Zhao, Yiling, Zhu, Hongping, Fu, Gang, Roesky, Herbert W.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Density functional theory Donor-Acceptor Interaction Enamination Geometric constraints Hydrosilylation Hypercoordinated Silane Nitriles Polyheterocycles Reaction mechanisms Silicon Silylene
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