Zero‐Dimensional Gua3SbCl6 Crystals as Intrinsically Reabsorption‐Free Scintillators for Radiation Detection
The search for efficient, re‐absorption‐free scintillators has recently focused the attention on antimony‐based halides, which exhibit largely Stokes shifted luminescence due to radiative recombination of excitons self‐trapped (STE) in strongly Jahn–Teller distorted Sb3+ color centers. Here, the syn...
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creator | Zaffalon, Matteo L. Wu, Ye Cova, Francesca Gironi, Luca Li, Xiaoming Pinchetti, Valerio Liu, Yang Imran, Muhammad Cemmi, Alessia Di Sarcina, Ilaria Manna, Liberato Zeng, Haibo Brovelli, Sergio |
description | The search for efficient, re‐absorption‐free scintillators has recently focused the attention on antimony‐based halides, which exhibit largely Stokes shifted luminescence due to radiative recombination of excitons self‐trapped (STE) in strongly Jahn–Teller distorted Sb3+ color centers. Here, the synthesis of a hybrid structure is reported with chemical formula (C13H14N3)3SbCl6 consisting of spatially isolated [SbCl6]3− octahedra separated by organic N,N'‐diphenylguanidinium (Gua) molecules. The optical properties of this material are mainly determined by the inorganic component and are characterized by a pronounced Stokes shift of ≈1.3 eV and a room‐temperature photoluminescence (PL) efficiency of up to 85%. Remarkably, highly efficient radioluminescence (RL) is observed with scintillation light yields of ≈2000 ph MeV−1 using both soft X‐rays and a 124 keV gamma source. Temperature‐dependent PL and RL measurements confirm the minor role of non‐radiative channels, which are completely suppressed below 100 K. Thermally stimulated luminescence measurements suggest that the traps in Gua3SbCl6 crystals have a significantly large energy depth distribution below the absorbing state.
Here, the optical and scintillation properties of Gua3SbCl6 hybrid crystals are reported, which exhibit largely Stokes‐shifted emission under both optical and ionising excitation (ФPL > 85%, LY ≈ 2 × 103 ph MeV−1) and good radiation hardness to high gamma‐ray doses (1 MGy). Complementary experiments with synchrotron light, X‐rays and 57Co γ‐rays, together with T‐dependent time‐resolved PL measurements, reveal the origin of their luminescence and identify the residual non‐radiative recombination channels quenched at cryogenic temperatures (T |
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Here, the optical and scintillation properties of Gua3SbCl6 hybrid crystals are reported, which exhibit largely Stokes‐shifted emission under both optical and ionising excitation (ФPL > 85%, LY ≈ 2 × 103 ph MeV−1) and good radiation hardness to high gamma‐ray doses (1 MGy). Complementary experiments with synchrotron light, X‐rays and 57Co γ‐rays, together with T‐dependent time‐resolved PL measurements, reveal the origin of their luminescence and identify the residual non‐radiative recombination channels quenched at cryogenic temperatures (T < 50 K).</description><identifier>ISSN: 1616-301X</identifier><identifier>EISSN: 1616-3028</identifier><identifier>DOI: 10.1002/adfm.202305564</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc</publisher><subject>Absorption ; Antimony ; Color centers ; Energy distribution ; Excitons ; Halides ; Hybrid structures ; Jahn-Teller effect ; Luminescence ; Materials science ; metal halides ; Optical properties ; Photoluminescence ; Radiative recombination ; radioluminescence ; Scintillation counters ; scintillators ; Temperature dependence ; thermally stimulated luminescence ; zero‐dimensional crystals</subject><ispartof>Advanced functional materials, 2023-11, Vol.33 (48), p.n/a</ispartof><rights>2023 The Authors. Advanced Functional Materials published by Wiley‐VCH GmbH</rights><rights>2023. This article is published under http://creativecommons.org/licenses/by-nc/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0002-1016-6413 ; 0000-0002-5993-855X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fadfm.202305564$$EPDF$$P50$$Gwiley$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fadfm.202305564$$EHTML$$P50$$Gwiley$$Hfree_for_read</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Zaffalon, Matteo L.</creatorcontrib><creatorcontrib>Wu, Ye</creatorcontrib><creatorcontrib>Cova, Francesca</creatorcontrib><creatorcontrib>Gironi, Luca</creatorcontrib><creatorcontrib>Li, Xiaoming</creatorcontrib><creatorcontrib>Pinchetti, Valerio</creatorcontrib><creatorcontrib>Liu, Yang</creatorcontrib><creatorcontrib>Imran, Muhammad</creatorcontrib><creatorcontrib>Cemmi, Alessia</creatorcontrib><creatorcontrib>Di Sarcina, Ilaria</creatorcontrib><creatorcontrib>Manna, Liberato</creatorcontrib><creatorcontrib>Zeng, Haibo</creatorcontrib><creatorcontrib>Brovelli, Sergio</creatorcontrib><title>Zero‐Dimensional Gua3SbCl6 Crystals as Intrinsically Reabsorption‐Free Scintillators for Radiation Detection</title><title>Advanced functional materials</title><description>The search for efficient, re‐absorption‐free scintillators has recently focused the attention on antimony‐based halides, which exhibit largely Stokes shifted luminescence due to radiative recombination of excitons self‐trapped (STE) in strongly Jahn–Teller distorted Sb3+ color centers. Here, the synthesis of a hybrid structure is reported with chemical formula (C13H14N3)3SbCl6 consisting of spatially isolated [SbCl6]3− octahedra separated by organic N,N'‐diphenylguanidinium (Gua) molecules. The optical properties of this material are mainly determined by the inorganic component and are characterized by a pronounced Stokes shift of ≈1.3 eV and a room‐temperature photoluminescence (PL) efficiency of up to 85%. Remarkably, highly efficient radioluminescence (RL) is observed with scintillation light yields of ≈2000 ph MeV−1 using both soft X‐rays and a 124 keV gamma source. Temperature‐dependent PL and RL measurements confirm the minor role of non‐radiative channels, which are completely suppressed below 100 K. Thermally stimulated luminescence measurements suggest that the traps in Gua3SbCl6 crystals have a significantly large energy depth distribution below the absorbing state.
Here, the optical and scintillation properties of Gua3SbCl6 hybrid crystals are reported, which exhibit largely Stokes‐shifted emission under both optical and ionising excitation (ФPL > 85%, LY ≈ 2 × 103 ph MeV−1) and good radiation hardness to high gamma‐ray doses (1 MGy). Complementary experiments with synchrotron light, X‐rays and 57Co γ‐rays, together with T‐dependent time‐resolved PL measurements, reveal the origin of their luminescence and identify the residual non‐radiative recombination channels quenched at cryogenic temperatures (T < 50 K).</description><subject>Absorption</subject><subject>Antimony</subject><subject>Color centers</subject><subject>Energy distribution</subject><subject>Excitons</subject><subject>Halides</subject><subject>Hybrid structures</subject><subject>Jahn-Teller effect</subject><subject>Luminescence</subject><subject>Materials science</subject><subject>metal halides</subject><subject>Optical properties</subject><subject>Photoluminescence</subject><subject>Radiative recombination</subject><subject>radioluminescence</subject><subject>Scintillation counters</subject><subject>scintillators</subject><subject>Temperature dependence</subject><subject>thermally stimulated luminescence</subject><subject>zero‐dimensional crystals</subject><issn>1616-301X</issn><issn>1616-3028</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>24P</sourceid><sourceid>WIN</sourceid><recordid>eNo9kF9LwzAUxYMoOKevPgd8ruZP0zaPY3NzMBE2BfEl3KUJZGRtTTqkb34EP6OfxJbJnu658DuHew9Ct5TcU0LYA5R2f88I40SILD1DI5rRLOGEFecnTd8v0VWMO0JonvN0hJoPE-rf75-Z25squroCjxcH4Jvt1Gd4GrrYgo8YIl5WbXA9osH7Dq8NbGMdmra39PZ5MAZvtKta5z20dYjY1gGvoXQwIHhmWqMHdY0ubJ9obv7nGL3NH1-nT8nqZbGcTlZJw_rDkoJCZqwRmkgL1kppBdesYGkhBC9SKHJJ01JkQlNaag0gIQWZl5YZSnKa8TG6O-Y2of48mNiqXX0I_XtRsUIykYusSHtKHqkv502nmuD2EDpFiRoqVUOl6lSpmszmz6eN_wHbSXBX</recordid><startdate>20231123</startdate><enddate>20231123</enddate><creator>Zaffalon, Matteo L.</creator><creator>Wu, Ye</creator><creator>Cova, Francesca</creator><creator>Gironi, Luca</creator><creator>Li, Xiaoming</creator><creator>Pinchetti, Valerio</creator><creator>Liu, Yang</creator><creator>Imran, Muhammad</creator><creator>Cemmi, Alessia</creator><creator>Di Sarcina, Ilaria</creator><creator>Manna, Liberato</creator><creator>Zeng, Haibo</creator><creator>Brovelli, Sergio</creator><general>Wiley Subscription Services, Inc</general><scope>24P</scope><scope>WIN</scope><scope>7SP</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-1016-6413</orcidid><orcidid>https://orcid.org/0000-0002-5993-855X</orcidid></search><sort><creationdate>20231123</creationdate><title>Zero‐Dimensional Gua3SbCl6 Crystals as Intrinsically Reabsorption‐Free Scintillators for Radiation Detection</title><author>Zaffalon, Matteo L. ; Wu, Ye ; Cova, Francesca ; Gironi, Luca ; Li, Xiaoming ; Pinchetti, Valerio ; Liu, Yang ; Imran, Muhammad ; Cemmi, Alessia ; Di Sarcina, Ilaria ; Manna, Liberato ; Zeng, Haibo ; Brovelli, Sergio</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p2734-81a6efe5c09faff99f53c2824855384a87914d565c11dccaa9a4a97df2e107163</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Absorption</topic><topic>Antimony</topic><topic>Color centers</topic><topic>Energy distribution</topic><topic>Excitons</topic><topic>Halides</topic><topic>Hybrid structures</topic><topic>Jahn-Teller effect</topic><topic>Luminescence</topic><topic>Materials science</topic><topic>metal halides</topic><topic>Optical properties</topic><topic>Photoluminescence</topic><topic>Radiative recombination</topic><topic>radioluminescence</topic><topic>Scintillation counters</topic><topic>scintillators</topic><topic>Temperature dependence</topic><topic>thermally stimulated luminescence</topic><topic>zero‐dimensional crystals</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zaffalon, Matteo L.</creatorcontrib><creatorcontrib>Wu, Ye</creatorcontrib><creatorcontrib>Cova, Francesca</creatorcontrib><creatorcontrib>Gironi, Luca</creatorcontrib><creatorcontrib>Li, Xiaoming</creatorcontrib><creatorcontrib>Pinchetti, Valerio</creatorcontrib><creatorcontrib>Liu, Yang</creatorcontrib><creatorcontrib>Imran, Muhammad</creatorcontrib><creatorcontrib>Cemmi, Alessia</creatorcontrib><creatorcontrib>Di Sarcina, Ilaria</creatorcontrib><creatorcontrib>Manna, Liberato</creatorcontrib><creatorcontrib>Zeng, Haibo</creatorcontrib><creatorcontrib>Brovelli, Sergio</creatorcontrib><collection>Wiley Online Library (Open Access Collection)</collection><collection>Wiley Online Library (Open Access Collection)</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Advanced functional materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zaffalon, Matteo L.</au><au>Wu, Ye</au><au>Cova, Francesca</au><au>Gironi, Luca</au><au>Li, Xiaoming</au><au>Pinchetti, Valerio</au><au>Liu, Yang</au><au>Imran, Muhammad</au><au>Cemmi, Alessia</au><au>Di Sarcina, Ilaria</au><au>Manna, Liberato</au><au>Zeng, Haibo</au><au>Brovelli, Sergio</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Zero‐Dimensional Gua3SbCl6 Crystals as Intrinsically Reabsorption‐Free Scintillators for Radiation Detection</atitle><jtitle>Advanced functional materials</jtitle><date>2023-11-23</date><risdate>2023</risdate><volume>33</volume><issue>48</issue><epage>n/a</epage><issn>1616-301X</issn><eissn>1616-3028</eissn><abstract>The search for efficient, re‐absorption‐free scintillators has recently focused the attention on antimony‐based halides, which exhibit largely Stokes shifted luminescence due to radiative recombination of excitons self‐trapped (STE) in strongly Jahn–Teller distorted Sb3+ color centers. Here, the synthesis of a hybrid structure is reported with chemical formula (C13H14N3)3SbCl6 consisting of spatially isolated [SbCl6]3− octahedra separated by organic N,N'‐diphenylguanidinium (Gua) molecules. The optical properties of this material are mainly determined by the inorganic component and are characterized by a pronounced Stokes shift of ≈1.3 eV and a room‐temperature photoluminescence (PL) efficiency of up to 85%. Remarkably, highly efficient radioluminescence (RL) is observed with scintillation light yields of ≈2000 ph MeV−1 using both soft X‐rays and a 124 keV gamma source. Temperature‐dependent PL and RL measurements confirm the minor role of non‐radiative channels, which are completely suppressed below 100 K. Thermally stimulated luminescence measurements suggest that the traps in Gua3SbCl6 crystals have a significantly large energy depth distribution below the absorbing state.
Here, the optical and scintillation properties of Gua3SbCl6 hybrid crystals are reported, which exhibit largely Stokes‐shifted emission under both optical and ionising excitation (ФPL > 85%, LY ≈ 2 × 103 ph MeV−1) and good radiation hardness to high gamma‐ray doses (1 MGy). Complementary experiments with synchrotron light, X‐rays and 57Co γ‐rays, together with T‐dependent time‐resolved PL measurements, reveal the origin of their luminescence and identify the residual non‐radiative recombination channels quenched at cryogenic temperatures (T < 50 K).</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/adfm.202305564</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-1016-6413</orcidid><orcidid>https://orcid.org/0000-0002-5993-855X</orcidid><oa>free_for_read</oa></addata></record> |
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subjects | Absorption Antimony Color centers Energy distribution Excitons Halides Hybrid structures Jahn-Teller effect Luminescence Materials science metal halides Optical properties Photoluminescence Radiative recombination radioluminescence Scintillation counters scintillators Temperature dependence thermally stimulated luminescence zero‐dimensional crystals |
title | Zero‐Dimensional Gua3SbCl6 Crystals as Intrinsically Reabsorption‐Free Scintillators for Radiation Detection |
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