Synergistic effect of carbon nanotube on improving thermal stability, flame retardancy, and electrical conductivity of poly(butylene succinate)/piperazine pyrophosphate composites
Biodegradable poly(butylene succinate) (PBS) is considered as promising material to replace conventional nondegradable polymers in various engineering fields, but the applications are limited by its inherent flammability and low electrical conductivity. In this study, the synergistic effect of carbo...
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| Veröffentlicht in: | Colloid and polymer science 2023-12, Vol.301 (12), p.1529-1537 |
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| creator | Wang, Yiming Meng, Fanjing Zhu, Junling Ba, Zhaotian Jiang, Dayong Wen, Xin Tang, Tao |
| description | Biodegradable poly(butylene succinate) (PBS) is considered as promising material to replace conventional nondegradable polymers in various engineering fields, but the applications are limited by its inherent flammability and low electrical conductivity. In this study, the synergistic effect of carbon nanotube (CNTs) on improving thermal stability, flame retardancy, and electrical conductivity of poly(butylene succinate)/piperazine pyrophosphate (PBS/PAPP) composites was investigated. Thermogravimetric analysis (TGA) demonstrated that the addition of CNTs could improve the thermal stability of PBS/PAPP composites, where the maximum mass loss temperature (
T
max
) of PBS/18PAPP-2CNT increased by 9.1 °C in comparison with that of PBS/20PAPP. Meanwhile, PBS/18PAPP-2CNT exhibited the optimal flame retardancy with limited oxygen index (LOI) of 30.1%, V0 rating in UL-94 vertical burning test, and 79.6% reduction on the peak of heat release rate (PHRR) in cone calorimeter test. The synergistic effect of CNTs and PAPP was beneficial to construct high-quality char layer, resulting in the enhanced flame retardancy of PBS. Furthermore, the CNTs could improve the electrical conductivity of PBS/PAPP composites with low percolation threshold of 1.75 wt%, which was ascribed to the “volume excluded effect” of PAPP. Thus, the current work provided an efficient strategy to prepare multifunctional PBS composites to meet various engineering applications. |
| doi_str_mv | 10.1007/s00396-023-05166-2 |
| format | Article |
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T
max
) of PBS/18PAPP-2CNT increased by 9.1 °C in comparison with that of PBS/20PAPP. Meanwhile, PBS/18PAPP-2CNT exhibited the optimal flame retardancy with limited oxygen index (LOI) of 30.1%, V0 rating in UL-94 vertical burning test, and 79.6% reduction on the peak of heat release rate (PHRR) in cone calorimeter test. The synergistic effect of CNTs and PAPP was beneficial to construct high-quality char layer, resulting in the enhanced flame retardancy of PBS. Furthermore, the CNTs could improve the electrical conductivity of PBS/PAPP composites with low percolation threshold of 1.75 wt%, which was ascribed to the “volume excluded effect” of PAPP. Thus, the current work provided an efficient strategy to prepare multifunctional PBS composites to meet various engineering applications.</description><identifier>ISSN: 0303-402X</identifier><identifier>EISSN: 1435-1536</identifier><identifier>DOI: 10.1007/s00396-023-05166-2</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Carbon fibers ; Carbon nanotubes ; Cellulose ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Composite materials ; Cone calorimeters ; Electrical resistivity ; Electrons ; Engineering ; Flame retardants ; Flammability ; Food Science ; Heat release rate ; Nanotechnology and Microengineering ; Percolation ; Physical Chemistry ; Polymer Sciences ; Polymers ; Science ; Soft and Granular Matter ; Synergistic effect ; Thermal stability ; Thermogravimetric analysis</subject><ispartof>Colloid and polymer science, 2023-12, Vol.301 (12), p.1529-1537</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-b03cec7b091851009329240a358a488a8d9c4436938337884717f5e9e14b08b83</citedby><cites>FETCH-LOGICAL-c319t-b03cec7b091851009329240a358a488a8d9c4436938337884717f5e9e14b08b83</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00396-023-05166-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00396-023-05166-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Wang, Yiming</creatorcontrib><creatorcontrib>Meng, Fanjing</creatorcontrib><creatorcontrib>Zhu, Junling</creatorcontrib><creatorcontrib>Ba, Zhaotian</creatorcontrib><creatorcontrib>Jiang, Dayong</creatorcontrib><creatorcontrib>Wen, Xin</creatorcontrib><creatorcontrib>Tang, Tao</creatorcontrib><title>Synergistic effect of carbon nanotube on improving thermal stability, flame retardancy, and electrical conductivity of poly(butylene succinate)/piperazine pyrophosphate composites</title><title>Colloid and polymer science</title><addtitle>Colloid Polym Sci</addtitle><description>Biodegradable poly(butylene succinate) (PBS) is considered as promising material to replace conventional nondegradable polymers in various engineering fields, but the applications are limited by its inherent flammability and low electrical conductivity. In this study, the synergistic effect of carbon nanotube (CNTs) on improving thermal stability, flame retardancy, and electrical conductivity of poly(butylene succinate)/piperazine pyrophosphate (PBS/PAPP) composites was investigated. Thermogravimetric analysis (TGA) demonstrated that the addition of CNTs could improve the thermal stability of PBS/PAPP composites, where the maximum mass loss temperature (
T
max
) of PBS/18PAPP-2CNT increased by 9.1 °C in comparison with that of PBS/20PAPP. Meanwhile, PBS/18PAPP-2CNT exhibited the optimal flame retardancy with limited oxygen index (LOI) of 30.1%, V0 rating in UL-94 vertical burning test, and 79.6% reduction on the peak of heat release rate (PHRR) in cone calorimeter test. The synergistic effect of CNTs and PAPP was beneficial to construct high-quality char layer, resulting in the enhanced flame retardancy of PBS. Furthermore, the CNTs could improve the electrical conductivity of PBS/PAPP composites with low percolation threshold of 1.75 wt%, which was ascribed to the “volume excluded effect” of PAPP. Thus, the current work provided an efficient strategy to prepare multifunctional PBS composites to meet various engineering applications.</description><subject>Carbon fibers</subject><subject>Carbon nanotubes</subject><subject>Cellulose</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Composite materials</subject><subject>Cone calorimeters</subject><subject>Electrical resistivity</subject><subject>Electrons</subject><subject>Engineering</subject><subject>Flame retardants</subject><subject>Flammability</subject><subject>Food Science</subject><subject>Heat release rate</subject><subject>Nanotechnology and Microengineering</subject><subject>Percolation</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Science</subject><subject>Soft and Granular Matter</subject><subject>Synergistic effect</subject><subject>Thermal stability</subject><subject>Thermogravimetric analysis</subject><issn>0303-402X</issn><issn>1435-1536</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kc1q3TAQhU1pobdpX6ArQTct1M3ox7a0LKE_gUAXTaA7IeuO71WwJVWSA-5r5QWj9Ba6y0pi5jtnmDlN85bCJwownGcArvoWGG-ho33fsmfNjgretbTj_fNmBxx4K4D9etm8yvkWAITq-11z_3PzmA4uF2cJThPaQsJErElj8MQbH8o6Iql_t8QU7pw_kHLEtJiZ5GJGN7uyfSTTbBYkCYtJe-NtrRi_JzhXu-RsZW3w-9UWd1fxxwExzNv7cS3bjB5JXq113hT8cB5dxGT-uFqNWwrxGHI81k51WGLIrmB-3byYzJzxzb_3rLn5-uX64nt79ePb5cXnq9Zyqko7ArdohxEUlV29kuJMMQGGd9IIKY3cKysE7xWXnA9SioEOU4cKqRhBjpKfNe9OvnXx3yvmom_DmnwdqZlUjKuBK6gUO1E2hZwTTjomt5i0aQr6MRx9CkfXcPTfcDSrIn4S5Qr7A6b_1k-oHgBBbZZ_</recordid><startdate>20231201</startdate><enddate>20231201</enddate><creator>Wang, Yiming</creator><creator>Meng, Fanjing</creator><creator>Zhu, Junling</creator><creator>Ba, Zhaotian</creator><creator>Jiang, Dayong</creator><creator>Wen, Xin</creator><creator>Tang, Tao</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>20231201</creationdate><title>Synergistic effect of carbon nanotube on improving thermal stability, flame retardancy, and electrical conductivity of poly(butylene succinate)/piperazine pyrophosphate composites</title><author>Wang, Yiming ; Meng, Fanjing ; Zhu, Junling ; Ba, Zhaotian ; Jiang, Dayong ; Wen, Xin ; Tang, Tao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-b03cec7b091851009329240a358a488a8d9c4436938337884717f5e9e14b08b83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Carbon fibers</topic><topic>Carbon nanotubes</topic><topic>Cellulose</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Complex Fluids and Microfluidics</topic><topic>Composite materials</topic><topic>Cone calorimeters</topic><topic>Electrical resistivity</topic><topic>Electrons</topic><topic>Engineering</topic><topic>Flame retardants</topic><topic>Flammability</topic><topic>Food Science</topic><topic>Heat release rate</topic><topic>Nanotechnology and Microengineering</topic><topic>Percolation</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Science</topic><topic>Soft and Granular Matter</topic><topic>Synergistic effect</topic><topic>Thermal stability</topic><topic>Thermogravimetric analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Yiming</creatorcontrib><creatorcontrib>Meng, Fanjing</creatorcontrib><creatorcontrib>Zhu, Junling</creatorcontrib><creatorcontrib>Ba, Zhaotian</creatorcontrib><creatorcontrib>Jiang, Dayong</creatorcontrib><creatorcontrib>Wen, Xin</creatorcontrib><creatorcontrib>Tang, Tao</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Colloid and polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Yiming</au><au>Meng, Fanjing</au><au>Zhu, Junling</au><au>Ba, Zhaotian</au><au>Jiang, Dayong</au><au>Wen, Xin</au><au>Tang, Tao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synergistic effect of carbon nanotube on improving thermal stability, flame retardancy, and electrical conductivity of poly(butylene succinate)/piperazine pyrophosphate composites</atitle><jtitle>Colloid and polymer science</jtitle><stitle>Colloid Polym Sci</stitle><date>2023-12-01</date><risdate>2023</risdate><volume>301</volume><issue>12</issue><spage>1529</spage><epage>1537</epage><pages>1529-1537</pages><issn>0303-402X</issn><eissn>1435-1536</eissn><abstract>Biodegradable poly(butylene succinate) (PBS) is considered as promising material to replace conventional nondegradable polymers in various engineering fields, but the applications are limited by its inherent flammability and low electrical conductivity. In this study, the synergistic effect of carbon nanotube (CNTs) on improving thermal stability, flame retardancy, and electrical conductivity of poly(butylene succinate)/piperazine pyrophosphate (PBS/PAPP) composites was investigated. Thermogravimetric analysis (TGA) demonstrated that the addition of CNTs could improve the thermal stability of PBS/PAPP composites, where the maximum mass loss temperature (
T
max
) of PBS/18PAPP-2CNT increased by 9.1 °C in comparison with that of PBS/20PAPP. Meanwhile, PBS/18PAPP-2CNT exhibited the optimal flame retardancy with limited oxygen index (LOI) of 30.1%, V0 rating in UL-94 vertical burning test, and 79.6% reduction on the peak of heat release rate (PHRR) in cone calorimeter test. The synergistic effect of CNTs and PAPP was beneficial to construct high-quality char layer, resulting in the enhanced flame retardancy of PBS. Furthermore, the CNTs could improve the electrical conductivity of PBS/PAPP composites with low percolation threshold of 1.75 wt%, which was ascribed to the “volume excluded effect” of PAPP. Thus, the current work provided an efficient strategy to prepare multifunctional PBS composites to meet various engineering applications.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00396-023-05166-2</doi><tpages>9</tpages></addata></record> |
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| subjects | Carbon fibers Carbon nanotubes Cellulose Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Composite materials Cone calorimeters Electrical resistivity Electrons Engineering Flame retardants Flammability Food Science Heat release rate Nanotechnology and Microengineering Percolation Physical Chemistry Polymer Sciences Polymers Science Soft and Granular Matter Synergistic effect Thermal stability Thermogravimetric analysis |
| title | Synergistic effect of carbon nanotube on improving thermal stability, flame retardancy, and electrical conductivity of poly(butylene succinate)/piperazine pyrophosphate composites |
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