A novel shear-stiffening supramolecular material derived from diboron structure
Shear-stiffening polyborosiloxane (PBS), well-known as “silly putty”, “bouncing putty” or “solid-liquid”, has been widely used in protective armors, sport equipment, toys and so on, due to its fascinating anti-impact property. Since it was created during World War II, there has been rare upgrade of...
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| Veröffentlicht in: | Science China materials 2023-11, Vol.66 (11), p.4489-4498 |
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| creator | Wu, Qi Peng, Yan Xiong, Hui Hou, Yujia Cai, Minjie Wang, Yi Zhao, Lijuan Wu, Jinrong |
| description | Shear-stiffening polyborosiloxane (PBS), well-known as “silly putty”, “bouncing putty” or “solid-liquid”, has been widely used in protective armors, sport equipment, toys and so on, due to its fascinating anti-impact property. Since it was created during World War II, there has been rare upgrade of the material. Herein, we synthesize a novel shear-stiffening material, polydiborosiloxane (PDBS), through the design of diboron/oxygen coordination bond. It is revealed that the diboron/oxygen coordination bond possesses more coordination states and higher bond energy than the coordination bond between monoboron and oxygen atoms, leading to a shear-stiffening behavior with more solid-like property. Therefore, PDBS exhibits superior anti-impact property and safeguarding performance to PBS. This shear-stiffening material will open up a new horizon for next-generation intelligent armors, dampers and sensors. |
| doi_str_mv | 10.1007/s40843-023-2581-x |
| format | Article |
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Since it was created during World War II, there has been rare upgrade of the material. Herein, we synthesize a novel shear-stiffening material, polydiborosiloxane (PDBS), through the design of diboron/oxygen coordination bond. It is revealed that the diboron/oxygen coordination bond possesses more coordination states and higher bond energy than the coordination bond between monoboron and oxygen atoms, leading to a shear-stiffening behavior with more solid-like property. Therefore, PDBS exhibits superior anti-impact property and safeguarding performance to PBS. This shear-stiffening material will open up a new horizon for next-generation intelligent armors, dampers and sensors.</description><identifier>ISSN: 2095-8226</identifier><identifier>EISSN: 2199-4501</identifier><identifier>DOI: 10.1007/s40843-023-2581-x</identifier><language>eng</language><publisher>Beijing: Science China Press</publisher><subject>Bond energy ; Chemistry and Materials Science ; Chemistry/Food Science ; Coordination ; Dampers ; Materials Science ; Oxygen atoms ; Shear ; Sporting goods ; Stiffening ; Toys</subject><ispartof>Science China materials, 2023-11, Vol.66 (11), p.4489-4498</ispartof><rights>Science China Press 2023</rights><rights>Science China Press 2023.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c359t-18a56a97c34cb42a1c24b2dd3499e6cb5237c38966ef8d2f9561e374997b5b2a3</citedby><cites>FETCH-LOGICAL-c359t-18a56a97c34cb42a1c24b2dd3499e6cb5237c38966ef8d2f9561e374997b5b2a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s40843-023-2581-x$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s40843-023-2581-x$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Wu, Qi</creatorcontrib><creatorcontrib>Peng, Yan</creatorcontrib><creatorcontrib>Xiong, Hui</creatorcontrib><creatorcontrib>Hou, Yujia</creatorcontrib><creatorcontrib>Cai, Minjie</creatorcontrib><creatorcontrib>Wang, Yi</creatorcontrib><creatorcontrib>Zhao, Lijuan</creatorcontrib><creatorcontrib>Wu, Jinrong</creatorcontrib><title>A novel shear-stiffening supramolecular material derived from diboron structure</title><title>Science China materials</title><addtitle>Sci. China Mater</addtitle><description>Shear-stiffening polyborosiloxane (PBS), well-known as “silly putty”, “bouncing putty” or “solid-liquid”, has been widely used in protective armors, sport equipment, toys and so on, due to its fascinating anti-impact property. Since it was created during World War II, there has been rare upgrade of the material. Herein, we synthesize a novel shear-stiffening material, polydiborosiloxane (PDBS), through the design of diboron/oxygen coordination bond. It is revealed that the diboron/oxygen coordination bond possesses more coordination states and higher bond energy than the coordination bond between monoboron and oxygen atoms, leading to a shear-stiffening behavior with more solid-like property. Therefore, PDBS exhibits superior anti-impact property and safeguarding performance to PBS. This shear-stiffening material will open up a new horizon for next-generation intelligent armors, dampers and sensors.</description><subject>Bond energy</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Coordination</subject><subject>Dampers</subject><subject>Materials Science</subject><subject>Oxygen atoms</subject><subject>Shear</subject><subject>Sporting goods</subject><subject>Stiffening</subject><subject>Toys</subject><issn>2095-8226</issn><issn>2199-4501</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1kE1LwzAYx4MoOHQfwFvAczSvbXIcwzcY7KLnkKbp7Gib-aQd89ubUcGTp_8D_5cHfgjdMfrAKC0fk6RaCkK5IFxpRk4XaMGZMUQqyi7zTY0imvPiGi1T2lNKWaEYM3qBtis8xGPocPoMDkga26YJQzvscJoO4PrYBT91DnDvxgCt63Cd5Rhq3EDscd1WEeKA0wiTHycIt-iqcV0Ky1-9QR_PT-_rV7LZvrytVxvihTIjYdqpwpnSC-kryR3zXFa8roU0JhS-UlxkT5uiCI2ueWNUwYIos1tWquJO3KD7efcA8WsKabT7OMGQX1quc09wyUROsTnlIaYEobEHaHsH35ZRe0ZnZ3Q2o7NndPaUO3zupJwddgH-lv8v_QCLvHII</recordid><startdate>20231101</startdate><enddate>20231101</enddate><creator>Wu, Qi</creator><creator>Peng, Yan</creator><creator>Xiong, Hui</creator><creator>Hou, Yujia</creator><creator>Cai, Minjie</creator><creator>Wang, Yi</creator><creator>Zhao, Lijuan</creator><creator>Wu, Jinrong</creator><general>Science China Press</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20231101</creationdate><title>A novel shear-stiffening supramolecular material derived from diboron structure</title><author>Wu, Qi ; Peng, Yan ; Xiong, Hui ; Hou, Yujia ; Cai, Minjie ; Wang, Yi ; Zhao, Lijuan ; Wu, Jinrong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c359t-18a56a97c34cb42a1c24b2dd3499e6cb5237c38966ef8d2f9561e374997b5b2a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Bond energy</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Coordination</topic><topic>Dampers</topic><topic>Materials Science</topic><topic>Oxygen atoms</topic><topic>Shear</topic><topic>Sporting goods</topic><topic>Stiffening</topic><topic>Toys</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wu, Qi</creatorcontrib><creatorcontrib>Peng, Yan</creatorcontrib><creatorcontrib>Xiong, Hui</creatorcontrib><creatorcontrib>Hou, Yujia</creatorcontrib><creatorcontrib>Cai, Minjie</creatorcontrib><creatorcontrib>Wang, Yi</creatorcontrib><creatorcontrib>Zhao, Lijuan</creatorcontrib><creatorcontrib>Wu, Jinrong</creatorcontrib><collection>CrossRef</collection><jtitle>Science China materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wu, Qi</au><au>Peng, Yan</au><au>Xiong, Hui</au><au>Hou, Yujia</au><au>Cai, Minjie</au><au>Wang, Yi</au><au>Zhao, Lijuan</au><au>Wu, Jinrong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A novel shear-stiffening supramolecular material derived from diboron structure</atitle><jtitle>Science China materials</jtitle><stitle>Sci. China Mater</stitle><date>2023-11-01</date><risdate>2023</risdate><volume>66</volume><issue>11</issue><spage>4489</spage><epage>4498</epage><pages>4489-4498</pages><issn>2095-8226</issn><eissn>2199-4501</eissn><abstract>Shear-stiffening polyborosiloxane (PBS), well-known as “silly putty”, “bouncing putty” or “solid-liquid”, has been widely used in protective armors, sport equipment, toys and so on, due to its fascinating anti-impact property. Since it was created during World War II, there has been rare upgrade of the material. Herein, we synthesize a novel shear-stiffening material, polydiborosiloxane (PDBS), through the design of diboron/oxygen coordination bond. It is revealed that the diboron/oxygen coordination bond possesses more coordination states and higher bond energy than the coordination bond between monoboron and oxygen atoms, leading to a shear-stiffening behavior with more solid-like property. Therefore, PDBS exhibits superior anti-impact property and safeguarding performance to PBS. This shear-stiffening material will open up a new horizon for next-generation intelligent armors, dampers and sensors.</abstract><cop>Beijing</cop><pub>Science China Press</pub><doi>10.1007/s40843-023-2581-x</doi><tpages>10</tpages><oa>free_for_read</oa></addata></record> |
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| source | Alma/SFX Local Collection; SpringerLink Journals - AutoHoldings |
| subjects | Bond energy Chemistry and Materials Science Chemistry/Food Science Coordination Dampers Materials Science Oxygen atoms Shear Sporting goods Stiffening Toys |
| title | A novel shear-stiffening supramolecular material derived from diboron structure |
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