Performic acid—dichloromethane system as chemoselective reagent in the synthesis of 29-nor-20-O-formyl derivatives of betulin
A comparative study of the chemical behavior of performic acid in chloroform and methylene chloride revealed that the HCOOH—H 2 O 2 —CH 2 Cl 2 system ensured effective and chemoselective synthesis of 29- nor -20- O -formyl derivatives of betulin.
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| Veröffentlicht in: | Russian chemical bulletin 2023-10, Vol.72 (10), p.2484-2491 |
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| container_end_page | 2491 |
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| container_issue | 10 |
| container_start_page | 2484 |
| container_title | Russian chemical bulletin |
| container_volume | 72 |
| creator | Yakovleva, M. P. Sayakhov, R. R. Nugumanov, T. R. Medvedeva, N. I. Ishmuratova, N. M. Ishmuratov, G. Yu |
| description | A comparative study of the chemical behavior of performic acid in chloroform and methylene chloride revealed that the HCOOH—H
2
O
2
—CH
2
Cl
2
system ensured effective and chemoselective synthesis of 29-
nor
-20-
O
-formyl derivatives of betulin. |
| doi_str_mv | 10.1007/s11172-023-4050-4 |
| format | Article |
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—CH
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Cl
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O
2
—CH
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Cl
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-formyl derivatives of betulin.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Chloroform</subject><subject>Comparative studies</subject><subject>Dichloromethane</subject><subject>Full Articles</subject><subject>Hydrogen peroxide</subject><subject>Inorganic Chemistry</subject><subject>Organic Chemistry</subject><subject>Reagents</subject><subject>Synthesis</subject><issn>1066-5285</issn><issn>1573-9171</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1kL1OwzAUhSMEEqXwAGyWmA228-NkRBV_UqUywGw59nXjKomLnVbqBA_BE_IkOASJienc4TvnSl-SXFJyTQnhN4FSyhkmLMUZyQnOjpIZzXmKK8rpcbxJUeCclflpchbChhDCyrKcJe_P4I3znVVIKqu_Pj61VU3rvOtgaGQPKBzCAB2SAakGOhegBTXYPSAPcg39gGyPhmbk-hjBBuQMYhXunceM4BUe5w8t0uDtXo7NH6KGYdfa_jw5MbINcPGb8-T1_u5l8YiXq4enxe0SK1aUA9ZgqAJamxRSWQNksqKSQlFqbZTMSZ1rrYEzLmnGQZMii1bKuihNmnLD8nSeXE27W-_edhAGsXE738eXIoqookLKSaToRCnvQvBgxNbbTvqDoESMnsXkWUTPYvQssthhUydEtl-D_1v-v_QNlTCD3A</recordid><startdate>20231001</startdate><enddate>20231001</enddate><creator>Yakovleva, M. P.</creator><creator>Sayakhov, R. R.</creator><creator>Nugumanov, T. R.</creator><creator>Medvedeva, N. I.</creator><creator>Ishmuratova, N. M.</creator><creator>Ishmuratov, G. Yu</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20231001</creationdate><title>Performic acid—dichloromethane system as chemoselective reagent in the synthesis of 29-nor-20-O-formyl derivatives of betulin</title><author>Yakovleva, M. P. ; Sayakhov, R. R. ; Nugumanov, T. R. ; Medvedeva, N. I. ; Ishmuratova, N. M. ; Ishmuratov, G. Yu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-def1ce1bf3e3abee4a91a1e68ddfca50b5ddde727a147ed0641008b68f337f253</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Chloroform</topic><topic>Comparative studies</topic><topic>Dichloromethane</topic><topic>Full Articles</topic><topic>Hydrogen peroxide</topic><topic>Inorganic Chemistry</topic><topic>Organic Chemistry</topic><topic>Reagents</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yakovleva, M. P.</creatorcontrib><creatorcontrib>Sayakhov, R. R.</creatorcontrib><creatorcontrib>Nugumanov, T. R.</creatorcontrib><creatorcontrib>Medvedeva, N. I.</creatorcontrib><creatorcontrib>Ishmuratova, N. M.</creatorcontrib><creatorcontrib>Ishmuratov, G. Yu</creatorcontrib><collection>CrossRef</collection><jtitle>Russian chemical bulletin</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yakovleva, M. P.</au><au>Sayakhov, R. R.</au><au>Nugumanov, T. R.</au><au>Medvedeva, N. I.</au><au>Ishmuratova, N. M.</au><au>Ishmuratov, G. Yu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Performic acid—dichloromethane system as chemoselective reagent in the synthesis of 29-nor-20-O-formyl derivatives of betulin</atitle><jtitle>Russian chemical bulletin</jtitle><stitle>Russ Chem Bull</stitle><date>2023-10-01</date><risdate>2023</risdate><volume>72</volume><issue>10</issue><spage>2484</spage><epage>2491</epage><pages>2484-2491</pages><issn>1066-5285</issn><eissn>1573-9171</eissn><abstract>A comparative study of the chemical behavior of performic acid in chloroform and methylene chloride revealed that the HCOOH—H
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O
2
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2
Cl
2
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| fulltext | fulltext |
| identifier | ISSN: 1066-5285 |
| ispartof | Russian chemical bulletin, 2023-10, Vol.72 (10), p.2484-2491 |
| issn | 1066-5285 1573-9171 |
| language | eng |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Chemistry Chemistry and Materials Science Chemistry/Food Science Chloroform Comparative studies Dichloromethane Full Articles Hydrogen peroxide Inorganic Chemistry Organic Chemistry Reagents Synthesis |
| title | Performic acid—dichloromethane system as chemoselective reagent in the synthesis of 29-nor-20-O-formyl derivatives of betulin |
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