Determination of lateral strain in InGaAsSb alloys and its effect on structural and optical properties

In x Ga 1 - x As y Sb 1 - y epilayers with a fixed In content of x = 0.145 were grown on GaSb(100) substrates using liquid-phase epitaxy (LPE). The lattice mismatch between the quaternary epilayers and substrates was analyzed for different As contents ( y ) by X-ray ω -2 θ . Epilayers with As conten...

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Veröffentlicht in:Journal of materials science 2023-11, Vol.58 (41), p.16172-16183
Hauptverfasser: González-Morales, M. A., Villa-Martínez, G., Cruz-Bueno, J. J., Ramírez-López, M., Camacho-Reynoso, M., Rodríguez-Fragoso, P., Mendoza-Álvarez, J. G., Casallas-Moreno, Y. L., Herrera-Pérez, J. L.
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container_end_page 16183
container_issue 41
container_start_page 16172
container_title Journal of materials science
container_volume 58
creator González-Morales, M. A.
Villa-Martínez, G.
Cruz-Bueno, J. J.
Ramírez-López, M.
Camacho-Reynoso, M.
Rodríguez-Fragoso, P.
Mendoza-Álvarez, J. G.
Casallas-Moreno, Y. L.
Herrera-Pérez, J. L.
description In x Ga 1 - x As y Sb 1 - y epilayers with a fixed In content of x = 0.145 were grown on GaSb(100) substrates using liquid-phase epitaxy (LPE). The lattice mismatch between the quaternary epilayers and substrates was analyzed for different As contents ( y ) by X-ray ω -2 θ . Epilayers with As content between y = 0.120 and y = 0.124 exhibited a positive lattice mismatch, leading to compressive strain. These samples showed a high crystalline quality and flat surfaces, as confirmed by high-resolution X-ray diffraction (HR-XRD) and atomic force microscopy (AFM). Quaternary alloys with As content between y = 0.133 and y = 0.141 displayed a negative lattice mismatch, resulting in tensile strain. Structural defects in these samples were evidenced by HR-XRD and on AFM micrographs. Raman measurements also revealed that lateral strain has a direct impact on the intensities of the LO-like, phonon–plasmon and disorder-activated longitudinal acoustic modes. For all In x Ga 1 - x As y Sb 1 - y films, photoluminescence (PL) spectra showed a bound exciton (BE) transition, with additional features observed in samples under tensile strain, indicating the involvement of native defect centers and donor–acceptor pairs. This study provides new insights into the effect of lateral strain on the crystalline and surface quality, and optical properties of quaternary alloys, relevant for novel optoelectronic applications.
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A. ; Villa-Martínez, G. ; Cruz-Bueno, J. J. ; Ramírez-López, M. ; Camacho-Reynoso, M. ; Rodríguez-Fragoso, P. ; Mendoza-Álvarez, J. G. ; Casallas-Moreno, Y. L. ; Herrera-Pérez, J. L.</creator><creatorcontrib>González-Morales, M. A. ; Villa-Martínez, G. ; Cruz-Bueno, J. J. ; Ramírez-López, M. ; Camacho-Reynoso, M. ; Rodríguez-Fragoso, P. ; Mendoza-Álvarez, J. G. ; Casallas-Moreno, Y. L. ; Herrera-Pérez, J. L.</creatorcontrib><description>In x Ga 1 - x As y Sb 1 - y epilayers with a fixed In content of x = 0.145 were grown on GaSb(100) substrates using liquid-phase epitaxy (LPE). The lattice mismatch between the quaternary epilayers and substrates was analyzed for different As contents ( y ) by X-ray ω -2 θ . Epilayers with As content between y = 0.120 and y = 0.124 exhibited a positive lattice mismatch, leading to compressive strain. 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Epilayers with As content between y = 0.120 and y = 0.124 exhibited a positive lattice mismatch, leading to compressive strain. These samples showed a high crystalline quality and flat surfaces, as confirmed by high-resolution X-ray diffraction (HR-XRD) and atomic force microscopy (AFM). Quaternary alloys with As content between y = 0.133 and y = 0.141 displayed a negative lattice mismatch, resulting in tensile strain. Structural defects in these samples were evidenced by HR-XRD and on AFM micrographs. Raman measurements also revealed that lateral strain has a direct impact on the intensities of the LO-like, phonon–plasmon and disorder-activated longitudinal acoustic modes. For all In x Ga 1 - x As y Sb 1 - y films, photoluminescence (PL) spectra showed a bound exciton (BE) transition, with additional features observed in samples under tensile strain, indicating the involvement of native defect centers and donor–acceptor pairs. 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subjects Alloys
Atomic force microscopy
Characterization and Evaluation of Materials
Chemistry and Materials Science
Classical Mechanics
Compressive properties
Crystal defects
Crystallography and Scattering Methods
Diffraction
Electronic Materials
Epitaxial growth
Epitaxy
Excitons
Flat surfaces
Force and energy
Lattice vibration
Liquid phase epitaxy
Liquid phases
Materials Science
Optical properties
Optoelectronics
Photoluminescence
Photomicrographs
Polymer Sciences
Quaternary alloys
Solid Mechanics
Specialty metals industry
Substrates
Surface properties
Tensile strain
X-ray diffraction
X-rays
title Determination of lateral strain in InGaAsSb alloys and its effect on structural and optical properties
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