Standard Enthalpies of Formation of Glycyl-L-tyrosine and Its Dissociation Products in Aqueous Solutions
The enthalpies of dissolution of crystalline glycyl-L-tyrosine in water and in aqueous potassium hydroxide at 298.15 К were determined by the direct calorimetric method. The measurements were performed on a calorimetric unit with automatic recording of the temperature–time curve. The standard enthal...
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Veröffentlicht in: | Russian Journal of Physical Chemistry A 2023-11, Vol.97 (11), p.2362-2366 |
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creator | Krutova, O. N. Bazanov, M. I. Chernikov, V. V. Krutov, P. D. |
description | The enthalpies of dissolution of crystalline glycyl-L-tyrosine in water and in aqueous potassium hydroxide at 298.15 К were determined by the direct calorimetric method. The measurements were performed on a calorimetric unit with automatic recording of the temperature–time curve. The standard enthalpies of combustion and formation of glycyl-L-tyrosine were calculated by the additive group method based on group systematics with classification of fragments of the type of Benson classification, with the effect of the initial environment for atoms included in calculation. The standard enthalpies of formation of dipeptide and the products of its dissociation in aqueous solution were calculated. |
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N. ; Bazanov, M. I. ; Chernikov, V. V. ; Krutov, P. D.</creator><creatorcontrib>Krutova, O. N. ; Bazanov, M. I. ; Chernikov, V. V. ; Krutov, P. D.</creatorcontrib><description>The enthalpies of dissolution of crystalline glycyl-L-tyrosine in water and in aqueous potassium hydroxide at 298.15 К were determined by the direct calorimetric method. The measurements were performed on a calorimetric unit with automatic recording of the temperature–time curve. The standard enthalpies of combustion and formation of glycyl-L-tyrosine were calculated by the additive group method based on group systematics with classification of fragments of the type of Benson classification, with the effect of the initial environment for atoms included in calculation. The standard enthalpies of formation of dipeptide and the products of its dissociation in aqueous solution were calculated.</description><identifier>ISSN: 0036-0244</identifier><identifier>EISSN: 1531-863X</identifier><identifier>DOI: 10.1134/S0036024423110171</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Aqueous solutions ; Chemical Thermodynamics and Thermochemistry ; Chemistry ; Chemistry and Materials Science ; Classification ; Enthalpy ; Heat measurement ; Mathematical analysis ; Physical Chemistry ; Potassium hydroxides ; Tyrosine</subject><ispartof>Russian Journal of Physical Chemistry A, 2023-11, Vol.97 (11), p.2362-2366</ispartof><rights>Pleiades Publishing, Ltd. 2023. ISSN 0036-0244, Russian Journal of Physical Chemistry A, 2023, Vol. 97, No. 11, pp. 2362–2366. © Pleiades Publishing, Ltd., 2023. 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D.</creatorcontrib><title>Standard Enthalpies of Formation of Glycyl-L-tyrosine and Its Dissociation Products in Aqueous Solutions</title><title>Russian Journal of Physical Chemistry A</title><addtitle>Russ. J. Phys. Chem</addtitle><description>The enthalpies of dissolution of crystalline glycyl-L-tyrosine in water and in aqueous potassium hydroxide at 298.15 К were determined by the direct calorimetric method. The measurements were performed on a calorimetric unit with automatic recording of the temperature–time curve. The standard enthalpies of combustion and formation of glycyl-L-tyrosine were calculated by the additive group method based on group systematics with classification of fragments of the type of Benson classification, with the effect of the initial environment for atoms included in calculation. The standard enthalpies of formation of dipeptide and the products of its dissociation in aqueous solution were calculated.</description><subject>Aqueous solutions</subject><subject>Chemical Thermodynamics and Thermochemistry</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Classification</subject><subject>Enthalpy</subject><subject>Heat measurement</subject><subject>Mathematical analysis</subject><subject>Physical Chemistry</subject><subject>Potassium hydroxides</subject><subject>Tyrosine</subject><issn>0036-0244</issn><issn>1531-863X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1UEtLw0AQXkTBWv0B3hY8R_eZ7B5LrbVQUKiCt7DZh01Js3U3OeTfuyGCB_E0zHyPmfkAuMXoHmPKHnYI0RwRxgjFGOECn4EZ5hRnIqcf52A2wtmIX4KrGA8IMcYwm4H9rlOtUcHAVdvtVXOqbYTewScfjqqrfTs262bQQ5Nts24IPtathUkDN12Ej3WMXtcT8zV40-s0rVu4-Oqt7yPc-aYfwXgNLpxqor35qXPw_rR6Wz5n25f1ZrnYZprkosscrxyXiDhTcW4kznmR57aquC1U4QhhggmjqDaUuFwSZqpCOso5EhopzCWdg7vJ9xR8uiF25cH3oU0rSyIE55IQSRILTyydHorBuvIU6qMKQ4lROQZa_gk0acikiYnbftrw6_y_6BuZxnfJ</recordid><startdate>20231101</startdate><enddate>20231101</enddate><creator>Krutova, O. 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The measurements were performed on a calorimetric unit with automatic recording of the temperature–time curve. The standard enthalpies of combustion and formation of glycyl-L-tyrosine were calculated by the additive group method based on group systematics with classification of fragments of the type of Benson classification, with the effect of the initial environment for atoms included in calculation. The standard enthalpies of formation of dipeptide and the products of its dissociation in aqueous solution were calculated.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0036024423110171</doi><tpages>5</tpages></addata></record> |
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subjects | Aqueous solutions Chemical Thermodynamics and Thermochemistry Chemistry Chemistry and Materials Science Classification Enthalpy Heat measurement Mathematical analysis Physical Chemistry Potassium hydroxides Tyrosine |
title | Standard Enthalpies of Formation of Glycyl-L-tyrosine and Its Dissociation Products in Aqueous Solutions |
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