Dehydroabietane-type bifunctional organocatalysts in asymmetric synthesis: recent progress
Dehydroabietane-type bifunctional organocatalysts derived from rosane-type diterpenes of dehydroabietic acid (DHAA) and dehydroabietylamine (DA) have been utilized in a wide variety of highly enantioselective reactions. Since one well-documented review exclusively reported on the development of terp...
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| Veröffentlicht in: | RSC advances 2023-10, Vol.13 (44), p.3147-3158 |
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| creator | Zhang, Zhen-Wei Liu, Shao-Wu Huang, Hong-Ping Xie, Yu-Hang Huang, Ruo-Chen Deng, Yan-Qiu Lin, Ning |
| description | Dehydroabietane-type bifunctional organocatalysts derived from rosane-type diterpenes of dehydroabietic acid (DHAA) and dehydroabietylamine (DA) have been utilized in a wide variety of highly enantioselective reactions. Since one well-documented review exclusively reported on the development of terpene-derived bifunctional thioureas in asymmetric organocatalysis in 2013, fragmentary progress on the dehydroabietane-type bifunctional thioureas and squaramides has been mentioned in other reviews. In this mini-review, we systematically analyze and reorganize the published literature on dehydroabietane-type bifunctional organocatalysts in the recent decade according to the type of catalysts. Our aim is for this review to provide helpful research information and serve as a foundation for further design and application of rosin-based organocatalysts.
Dehydroabietane-type bifunctional organocatalysts derived from rosane-type diterpenes of dehydroabietic acid (DHAA) and dehydroabietylamine (DA) have been utilized in a wide variety of highly enantioselective reactions. |
| doi_str_mv | 10.1039/d3ra06715g |
| format | Article |
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Dehydroabietane-type bifunctional organocatalysts derived from rosane-type diterpenes of dehydroabietic acid (DHAA) and dehydroabietylamine (DA) have been utilized in a wide variety of highly enantioselective reactions.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/d3ra06715g</identifier><identifier>PMID: 37881754</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Asymmetry ; Chemistry ; Enantiomers ; Rosin ; Thioureas</subject><ispartof>RSC advances, 2023-10, Vol.13 (44), p.3147-3158</ispartof><rights>This journal is © The Royal Society of Chemistry.</rights><rights>Copyright Royal Society of Chemistry 2023</rights><rights>This journal is © The Royal Society of Chemistry 2023 The Royal Society of Chemistry</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c429t-4af00f44b06479badbdd07971b97aa081e00038fb341b4af724c8977de9085a63</citedby><cites>FETCH-LOGICAL-c429t-4af00f44b06479badbdd07971b97aa081e00038fb341b4af724c8977de9085a63</cites><orcidid>0000-0003-1521-5728</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC10594059/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC10594059/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,864,885,27924,27925,53791,53793</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/37881754$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhang, Zhen-Wei</creatorcontrib><creatorcontrib>Liu, Shao-Wu</creatorcontrib><creatorcontrib>Huang, Hong-Ping</creatorcontrib><creatorcontrib>Xie, Yu-Hang</creatorcontrib><creatorcontrib>Huang, Ruo-Chen</creatorcontrib><creatorcontrib>Deng, Yan-Qiu</creatorcontrib><creatorcontrib>Lin, Ning</creatorcontrib><title>Dehydroabietane-type bifunctional organocatalysts in asymmetric synthesis: recent progress</title><title>RSC advances</title><addtitle>RSC Adv</addtitle><description>Dehydroabietane-type bifunctional organocatalysts derived from rosane-type diterpenes of dehydroabietic acid (DHAA) and dehydroabietylamine (DA) have been utilized in a wide variety of highly enantioselective reactions. Since one well-documented review exclusively reported on the development of terpene-derived bifunctional thioureas in asymmetric organocatalysis in 2013, fragmentary progress on the dehydroabietane-type bifunctional thioureas and squaramides has been mentioned in other reviews. In this mini-review, we systematically analyze and reorganize the published literature on dehydroabietane-type bifunctional organocatalysts in the recent decade according to the type of catalysts. Our aim is for this review to provide helpful research information and serve as a foundation for further design and application of rosin-based organocatalysts.
Dehydroabietane-type bifunctional organocatalysts derived from rosane-type diterpenes of dehydroabietic acid (DHAA) and dehydroabietylamine (DA) have been utilized in a wide variety of highly enantioselective reactions.</description><subject>Asymmetry</subject><subject>Chemistry</subject><subject>Enantiomers</subject><subject>Rosin</subject><subject>Thioureas</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpdkc9LHDEYhkOpqFgv3lsGehFh2mSSSSa9iPgbhEKpFy_hSyazG5mZbJOMMP-9WVe3toGQwPfw8vC9CB0R_I1gKr-3NADmgtSLD2i_woyXFeby47v_HjqM8RHnw2tScbKL9qhoGiJqto8eLuxyboMH7WyC0ZZpXtlCu24aTXJ-hL7wYQGjN5Cgn2OKhRsLiPMw2BScKeI8pqWNLv4ogjV2TMUq-EWwMX5COx300R6-vgfo_ury9_lNeffz-vb87K40rJKpZNBh3DGmMWdCamh122IhBdFSAOCG2GxOm05TRnSGRcVMI4VorcRNDZweoNNN7mrSg23XDgF6tQpugDArD079OxndUi38kyK4lizfnHD8mhD8n8nGpAYXje37vBA_RVU1TUWrmnOc0a__oY9-CnlNLxTjLEeulU42lAk-xmC7rQ3Bal2buqC_zl5qu87wl_f-W_StpAx83gAhmu30b-_0GSynnoU</recordid><startdate>20231018</startdate><enddate>20231018</enddate><creator>Zhang, Zhen-Wei</creator><creator>Liu, Shao-Wu</creator><creator>Huang, Hong-Ping</creator><creator>Xie, Yu-Hang</creator><creator>Huang, Ruo-Chen</creator><creator>Deng, Yan-Qiu</creator><creator>Lin, Ning</creator><general>Royal Society of Chemistry</general><general>The Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0003-1521-5728</orcidid></search><sort><creationdate>20231018</creationdate><title>Dehydroabietane-type bifunctional organocatalysts in asymmetric synthesis: recent progress</title><author>Zhang, Zhen-Wei ; Liu, Shao-Wu ; Huang, Hong-Ping ; Xie, Yu-Hang ; Huang, Ruo-Chen ; Deng, Yan-Qiu ; Lin, Ning</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c429t-4af00f44b06479badbdd07971b97aa081e00038fb341b4af724c8977de9085a63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Asymmetry</topic><topic>Chemistry</topic><topic>Enantiomers</topic><topic>Rosin</topic><topic>Thioureas</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Zhen-Wei</creatorcontrib><creatorcontrib>Liu, Shao-Wu</creatorcontrib><creatorcontrib>Huang, Hong-Ping</creatorcontrib><creatorcontrib>Xie, Yu-Hang</creatorcontrib><creatorcontrib>Huang, Ruo-Chen</creatorcontrib><creatorcontrib>Deng, Yan-Qiu</creatorcontrib><creatorcontrib>Lin, Ning</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Zhen-Wei</au><au>Liu, Shao-Wu</au><au>Huang, Hong-Ping</au><au>Xie, Yu-Hang</au><au>Huang, Ruo-Chen</au><au>Deng, Yan-Qiu</au><au>Lin, Ning</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Dehydroabietane-type bifunctional organocatalysts in asymmetric synthesis: recent progress</atitle><jtitle>RSC advances</jtitle><addtitle>RSC Adv</addtitle><date>2023-10-18</date><risdate>2023</risdate><volume>13</volume><issue>44</issue><spage>3147</spage><epage>3158</epage><pages>3147-3158</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>Dehydroabietane-type bifunctional organocatalysts derived from rosane-type diterpenes of dehydroabietic acid (DHAA) and dehydroabietylamine (DA) have been utilized in a wide variety of highly enantioselective reactions. Since one well-documented review exclusively reported on the development of terpene-derived bifunctional thioureas in asymmetric organocatalysis in 2013, fragmentary progress on the dehydroabietane-type bifunctional thioureas and squaramides has been mentioned in other reviews. In this mini-review, we systematically analyze and reorganize the published literature on dehydroabietane-type bifunctional organocatalysts in the recent decade according to the type of catalysts. Our aim is for this review to provide helpful research information and serve as a foundation for further design and application of rosin-based organocatalysts.
Dehydroabietane-type bifunctional organocatalysts derived from rosane-type diterpenes of dehydroabietic acid (DHAA) and dehydroabietylamine (DA) have been utilized in a wide variety of highly enantioselective reactions.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>37881754</pmid><doi>10.1039/d3ra06715g</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0003-1521-5728</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Asymmetry Chemistry Enantiomers Rosin Thioureas |
| title | Dehydroabietane-type bifunctional organocatalysts in asymmetric synthesis: recent progress |
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