The role of dimensionality and direction of hydrogen-bonded networks in the mechanical flexibility of organic crystals
The role of directionality and dimensionality of hydrogen-bonded networks in the flexibility of organic crystals has been discussed in this highlight. Only those flexible organic crystals whose hydrogen-bonded networks are 1D, 2D, or 3D in their crystal structures have been considered and only conve...
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| Veröffentlicht in: | CrystEngComm 2023-10, Vol.25 (42), p.587-5881 |
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| creator | Saha, Binoy K Das, Sunirban Veluthaparambath, Ragima V. P |
| description | The role of directionality and dimensionality of hydrogen-bonded networks in the flexibility of organic crystals has been discussed in this highlight. Only those flexible organic crystals whose hydrogen-bonded networks are 1D, 2D, or 3D in their crystal structures have been considered and only conventional strong hydrogen bonds such as O-H O, O-H N, N-H O, N-H N,
etc.
are considered. 37 cases of plastic/elastic bending and one case of shearing crystals have been analyzed. How the crystal grows with respect to the unit cell dimension and the hydrogen-bonded networks has also been taken into account in this analysis. As hydrogen-bonded synthons are the main and most reliable element in crystal engineering while designing molecules to obtain crystals with desired properties, we anticipate that this knowledge, discussed here, would be helpful in designing flexible crystals with desired properties.
The role of directionality and dimensionality of hydrogen-bonded synthons in the flexibility of organic crystals has been discussed. |
| doi_str_mv | 10.1039/d3ce00681f |
| format | Article |
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etc.
are considered. 37 cases of plastic/elastic bending and one case of shearing crystals have been analyzed. How the crystal grows with respect to the unit cell dimension and the hydrogen-bonded networks has also been taken into account in this analysis. As hydrogen-bonded synthons are the main and most reliable element in crystal engineering while designing molecules to obtain crystals with desired properties, we anticipate that this knowledge, discussed here, would be helpful in designing flexible crystals with desired properties.
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etc.
are considered. 37 cases of plastic/elastic bending and one case of shearing crystals have been analyzed. How the crystal grows with respect to the unit cell dimension and the hydrogen-bonded networks has also been taken into account in this analysis. As hydrogen-bonded synthons are the main and most reliable element in crystal engineering while designing molecules to obtain crystals with desired properties, we anticipate that this knowledge, discussed here, would be helpful in designing flexible crystals with desired properties.
The role of directionality and dimensionality of hydrogen-bonded synthons in the flexibility of organic crystals has been discussed.</description><subject>Bonding strength</subject><subject>Crystal growth</subject><subject>Elastic bending</subject><subject>Flexibility</subject><subject>Hydrogen bonding</subject><subject>Hydrogen bonds</subject><subject>Networks</subject><subject>Organic crystals</subject><subject>Shearing</subject><subject>Unit cell</subject><issn>1466-8033</issn><issn>1466-8033</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpNkEFLAzEQhYMoWKsX70LAm7Ca7GzT3aPUVoWCl3pessmkTd0mNdmq_femrainN7z55sE8Qi45u-UMqjsNChkTJTdHpMcLIbKSARz_m0_JWYxLxnjBOeuRj9kCafAtUm-otit00XonW9ttqXQ6WQFVl6zdfrHVwc_RZY13GjV12H368BapdbRLOStUC-mski01LX7Zxu5z0qUP892CqrCNnWzjOTkxSfDiR_vkdTKejZ6y6cvj8-h-mqm8YF0GXFZQaWGqBlCiyI0uVW7MsGw4NKDTqxwKoYalqUrkeWMKkEKjGApTIAygT64Puevg3zcYu3rpNyH9F-u8LEEIGLAqUTcHSgUfY0BTr4NdybCtOat3vdYPMBrve50k-OoAh6h-ub_e4RvFLHap</recordid><startdate>20231030</startdate><enddate>20231030</enddate><creator>Saha, Binoy K</creator><creator>Das, Sunirban</creator><creator>Veluthaparambath, Ragima V. P</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><orcidid>https://orcid.org/0009-0007-7725-0832</orcidid><orcidid>https://orcid.org/0000-0002-4384-8023</orcidid><orcidid>https://orcid.org/0000-0002-1696-2939</orcidid></search><sort><creationdate>20231030</creationdate><title>The role of dimensionality and direction of hydrogen-bonded networks in the mechanical flexibility of organic crystals</title><author>Saha, Binoy K ; Das, Sunirban ; Veluthaparambath, Ragima V. P</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c240t-31a939d6f9b3eae62fd8c2ff78b13b3d0061346c78f98e12bf43a6de676f4e353</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Bonding strength</topic><topic>Crystal growth</topic><topic>Elastic bending</topic><topic>Flexibility</topic><topic>Hydrogen bonding</topic><topic>Hydrogen bonds</topic><topic>Networks</topic><topic>Organic crystals</topic><topic>Shearing</topic><topic>Unit cell</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Saha, Binoy K</creatorcontrib><creatorcontrib>Das, Sunirban</creatorcontrib><creatorcontrib>Veluthaparambath, Ragima V. P</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>CrystEngComm</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Saha, Binoy K</au><au>Das, Sunirban</au><au>Veluthaparambath, Ragima V. P</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The role of dimensionality and direction of hydrogen-bonded networks in the mechanical flexibility of organic crystals</atitle><jtitle>CrystEngComm</jtitle><date>2023-10-30</date><risdate>2023</risdate><volume>25</volume><issue>42</issue><spage>587</spage><epage>5881</epage><pages>587-5881</pages><issn>1466-8033</issn><eissn>1466-8033</eissn><abstract>The role of directionality and dimensionality of hydrogen-bonded networks in the flexibility of organic crystals has been discussed in this highlight. Only those flexible organic crystals whose hydrogen-bonded networks are 1D, 2D, or 3D in their crystal structures have been considered and only conventional strong hydrogen bonds such as O-H O, O-H N, N-H O, N-H N,
etc.
are considered. 37 cases of plastic/elastic bending and one case of shearing crystals have been analyzed. How the crystal grows with respect to the unit cell dimension and the hydrogen-bonded networks has also been taken into account in this analysis. As hydrogen-bonded synthons are the main and most reliable element in crystal engineering while designing molecules to obtain crystals with desired properties, we anticipate that this knowledge, discussed here, would be helpful in designing flexible crystals with desired properties.
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| identifier | ISSN: 1466-8033 |
| ispartof | CrystEngComm, 2023-10, Vol.25 (42), p.587-5881 |
| issn | 1466-8033 1466-8033 |
| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Bonding strength Crystal growth Elastic bending Flexibility Hydrogen bonding Hydrogen bonds Networks Organic crystals Shearing Unit cell |
| title | The role of dimensionality and direction of hydrogen-bonded networks in the mechanical flexibility of organic crystals |
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