The Tribological Properties of Low-Sulfur and Low-Phosphorus Halogen-Free Ionic Liquids as Lubricants for the Nickel-Based Alloy Inconel 690

In this study, we synthesized three low-sulfur and low-phosphorus ionic liquids (ILs). These were N88816P8, P88816P8, and P88816DOSS. The viscosity and thermal stability of the three ILs were analyzed. The tribological properties and lubrication mechanisms of the three ILs were investigated as lubri...

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Veröffentlicht in:Coatings (Basel) 2023-10, Vol.13 (10), p.1793
Hauptverfasser: Guo, Bian, Liu, Mengnan, Li, Yan, Zheng, Jianming, Li, Xubo, Peng, Chao, Jing, Zhangshuai, Li, Feizhou, Yu, Qiangliang
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container_issue 10
container_start_page 1793
container_title Coatings (Basel)
container_volume 13
creator Guo, Bian
Liu, Mengnan
Li, Yan
Zheng, Jianming
Li, Xubo
Peng, Chao
Jing, Zhangshuai
Li, Feizhou
Yu, Qiangliang
description In this study, we synthesized three low-sulfur and low-phosphorus ionic liquids (ILs). These were N88816P8, P88816P8, and P88816DOSS. The viscosity and thermal stability of the three ILs were analyzed. The tribological properties and lubrication mechanisms of the three ILs were investigated as lubricants for a carbide ball–Inconel 690 nickel-based alloy friction pair and compared at 50 °C and 150 °C. The wear spots of the carbide ball and nickel-based alloy disc samples were characterized using SEM and EDS. The experimental results revealed that P88816P8 had excellent tribological properties. The lubrication mechanism of P88816P8 as a lubricant for the carbide ball–Inconel 690 nickel-based alloy friction pair was investigated using XPS. The excellent friction reduction and anti-wear properties of P88816P8 could be attributed to the tribo-chemistry between P88816P8 and Inconel 690 as well as the formation of a tribo-film on the wear-spot surface. This high-performance IL, suitable for carbide ball–Inconel 690 contact, will be applied to a cutting process of Inconel 690.
doi_str_mv 10.3390/coatings13101793
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These were N88816P8, P88816P8, and P88816DOSS. The viscosity and thermal stability of the three ILs were analyzed. The tribological properties and lubrication mechanisms of the three ILs were investigated as lubricants for a carbide ball–Inconel 690 nickel-based alloy friction pair and compared at 50 °C and 150 °C. The wear spots of the carbide ball and nickel-based alloy disc samples were characterized using SEM and EDS. The experimental results revealed that P88816P8 had excellent tribological properties. The lubrication mechanism of P88816P8 as a lubricant for the carbide ball–Inconel 690 nickel-based alloy friction pair was investigated using XPS. The excellent friction reduction and anti-wear properties of P88816P8 could be attributed to the tribo-chemistry between P88816P8 and Inconel 690 as well as the formation of a tribo-film on the wear-spot surface. This high-performance IL, suitable for carbide ball–Inconel 690 contact, will be applied to a cutting process of Inconel 690.</description><identifier>ISSN: 2079-6412</identifier><identifier>EISSN: 2079-6412</identifier><identifier>DOI: 10.3390/coatings13101793</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Aluminum ; Carbides ; Corrosion and anti-corrosives ; Corrosion tests ; Friction ; Friction reduction ; Heat conductivity ; Heat resistant alloys ; International economic relations ; Ionic liquids ; Lubricants ; Lubricants &amp; lubrication ; Lubrication ; Mechanical properties ; Molecular structure ; Nickel alloys ; Nickel base alloys ; Nuclear energy ; Nuclear power plants ; Phosphorus ; Specialty metals industry ; Stability analysis ; Sulfur ; Sulfur compounds ; Superalloys ; Temperature ; Thermal stability ; Titanium alloys ; Tribology ; Viscosity ; Wear</subject><ispartof>Coatings (Basel), 2023-10, Vol.13 (10), p.1793</ispartof><rights>COPYRIGHT 2023 MDPI AG</rights><rights>2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). 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These were N88816P8, P88816P8, and P88816DOSS. The viscosity and thermal stability of the three ILs were analyzed. The tribological properties and lubrication mechanisms of the three ILs were investigated as lubricants for a carbide ball–Inconel 690 nickel-based alloy friction pair and compared at 50 °C and 150 °C. The wear spots of the carbide ball and nickel-based alloy disc samples were characterized using SEM and EDS. The experimental results revealed that P88816P8 had excellent tribological properties. The lubrication mechanism of P88816P8 as a lubricant for the carbide ball–Inconel 690 nickel-based alloy friction pair was investigated using XPS. The excellent friction reduction and anti-wear properties of P88816P8 could be attributed to the tribo-chemistry between P88816P8 and Inconel 690 as well as the formation of a tribo-film on the wear-spot surface. This high-performance IL, suitable for carbide ball–Inconel 690 contact, will be applied to a cutting process of Inconel 690.</abstract><cop>Basel</cop><pub>MDPI AG</pub><doi>10.3390/coatings13101793</doi><orcidid>https://orcid.org/0000-0002-7264-6586</orcidid><orcidid>https://orcid.org/0000-0003-0980-3486</orcidid><orcidid>https://orcid.org/0000-0001-5434-4763</orcidid><oa>free_for_read</oa></addata></record>
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source MDPI - Multidisciplinary Digital Publishing Institute; EZB-FREE-00999 freely available EZB journals; Alma/SFX Local Collection
subjects Aluminum
Carbides
Corrosion and anti-corrosives
Corrosion tests
Friction
Friction reduction
Heat conductivity
Heat resistant alloys
International economic relations
Ionic liquids
Lubricants
Lubricants & lubrication
Lubrication
Mechanical properties
Molecular structure
Nickel alloys
Nickel base alloys
Nuclear energy
Nuclear power plants
Phosphorus
Specialty metals industry
Stability analysis
Sulfur
Sulfur compounds
Superalloys
Temperature
Thermal stability
Titanium alloys
Tribology
Viscosity
Wear
title The Tribological Properties of Low-Sulfur and Low-Phosphorus Halogen-Free Ionic Liquids as Lubricants for the Nickel-Based Alloy Inconel 690
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