Optimizing electrical-optical parameters in TiO2@CdS@CdxCu1-xSe photoanodes using UV–Vis spectra, J-V curves, and EIS experiments in quantum dot-sensitized solar cells

In this research, photoanodes on the basis of a CdS/CdSe multilayer film, where CdSe-doped with Cu were successfully fabricated and optimized at a 3% doping concentration. The highest performance of quantum dot solar cells is 4.24%. This result is also confirmed by studying the optical and electrica...

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Veröffentlicht in:Optical and quantum electronics 2023-12, Vol.55 (14), Article 1221
Hauptverfasser: Tuan, Thi Tran Anh, Hung, Phan Thanh, Chinh, Truong Thi Ngoc, Van Sau, Nguyen, Tu, Le Thi Ngoc, Nguyen, Van Cuong, Phuc, Dang Huu
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container_issue 14
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container_title Optical and quantum electronics
container_volume 55
creator Tuan, Thi Tran Anh
Hung, Phan Thanh
Chinh, Truong Thi Ngoc
Van Sau, Nguyen
Tu, Le Thi Ngoc
Nguyen, Van Cuong
Phuc, Dang Huu
description In this research, photoanodes on the basis of a CdS/CdSe multilayer film, where CdSe-doped with Cu were successfully fabricated and optimized at a 3% doping concentration. The highest performance of quantum dot solar cells is 4.24%. This result is also confirmed by studying the optical and electrical properties of quantum dot solar cells that change with the Cu doping concentration. The enhanced efficiency can be explained by electrical-optical parameters, which are determined from UV–Vis spectra, J–V curves, and EIS experiments. The optical parameters such as absorption density, the band gap, the top of the valence band, and the bottom of the conduction band are estimated based on the Tauc equation and the UV–Vis spectra experiments for optical properties. Moreover, the electrical parameters, such as the shunt resistance and R ct1 and R ct2 resistances, are also extracted from J-V curves and the electrochemical impedance spectra experiments for electrical properties. Finally, the obtained results are used to explain the enhanced performance efficiency of devices.
doi_str_mv 10.1007/s11082-023-05363-x
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subjects Cadmium selenides
Cadmium sulfide
Characterization and Evaluation of Materials
Computer Communication Networks
Conduction bands
Doping
Electrical Engineering
Electrical properties
Electrons
Experiments
Lasers
Multilayers
Optical Devices
Optical properties
Optics
Parameters
Performance enhancement
Photoanodes
Photonics
Photovoltaic cells
Physics
Physics and Astronomy
Quantum dots
Shunt resistance
Solar cells
Spectra
Titanium dioxide
Valence band
title Optimizing electrical-optical parameters in TiO2@CdS@CdxCu1-xSe photoanodes using UV–Vis spectra, J-V curves, and EIS experiments in quantum dot-sensitized solar cells
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