Biogenic synthesis of date stones biochar-based zirconium oxide nanocomposite for the removal of hexavalent chromium from aqueous solution
Pollution of water has become the main problem around the world; chromium (Cr) has several industrial applications. However, Cr is considered very toxic pollutant, because of its carcinogenicity and high toxicity. The existing methods for the treatment of heavy metals are not economical, difficult t...
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| Veröffentlicht in: | Applied nanoscience 2023-09, Vol.13 (9), p.6053-6066 |
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| creator | Hussain, Tauqeer Akhter, Naheed Nadeem, Raziya Rashid, Umer Noreen, Saima Anjum, Shazia Ullah, Sajid Hussain, Hafiza Raazia Ashfaq, Aamna Perveen, Shazia A. Alharthi, Fahad Kazerooni, Elham Ahmed |
| description | Pollution of water has become the main problem around the world; chromium (Cr) has several industrial applications. However, Cr is considered very toxic pollutant, because of its carcinogenicity and high toxicity. The existing methods for the treatment of heavy metals are not economical, difficult to operate, and not eco-friendly. The biosorption process is easy to operate, cost effective as well as eco-friendly for the elimination of the toxic metal. In the present work, a zirconium oxide/date stones biochar bio-nanocomposite (ZrO
2
BNC) was utilized as low-cost biosorbent to remove the toxic Cr (VI). The modification of the activated bio-nanocomposite was confirmed using scanning electron microscopy (SEM), energy-dispersive X-ray (EDX), UV–Vis and Fourier-transform infrared (FTIR) spectroscopy. Optimized condition of various parameters for removal of chromium ion by zirconium oxide bio-nanocomposite (ZrO
2
BNC) was observed at the pH = 5, contact time 120 min, initial concentration 100 ppm, while 0.1 g sorbent dose. The results showed that the sorption process optimally correlated with Langmuir and 1st kinetic models with
R
2
value of 0.999. The percentage removal of Cr (VI) ions was checked by atomic absorbance spectrophotometer subsequently before and after the process of adsorption. These findings demonstrated that produced ZrO
2
BNC can be a cost effective, potential, and novel adsorbent for removel of contaminated chromium metal ions from the aqueous environment. |
| doi_str_mv | 10.1007/s13204-022-02599-z |
| format | Article |
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2
BNC) was utilized as low-cost biosorbent to remove the toxic Cr (VI). The modification of the activated bio-nanocomposite was confirmed using scanning electron microscopy (SEM), energy-dispersive X-ray (EDX), UV–Vis and Fourier-transform infrared (FTIR) spectroscopy. Optimized condition of various parameters for removal of chromium ion by zirconium oxide bio-nanocomposite (ZrO
2
BNC) was observed at the pH = 5, contact time 120 min, initial concentration 100 ppm, while 0.1 g sorbent dose. The results showed that the sorption process optimally correlated with Langmuir and 1st kinetic models with
R
2
value of 0.999. The percentage removal of Cr (VI) ions was checked by atomic absorbance spectrophotometer subsequently before and after the process of adsorption. These findings demonstrated that produced ZrO
2
BNC can be a cost effective, potential, and novel adsorbent for removel of contaminated chromium metal ions from the aqueous environment.</description><identifier>ISSN: 2190-5509</identifier><identifier>EISSN: 2190-5517</identifier><identifier>DOI: 10.1007/s13204-022-02599-z</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Aqueous environments ; Aqueous solutions ; Carcinogenicity ; Carcinogens ; Chemistry and Materials Science ; Fourier transforms ; Heavy metals ; Hexavalent chromium ; Industrial applications ; Materials Science ; Membrane Biology ; Nanochemistry ; Nanocomposites ; Nanotechnology ; Nanotechnology and Microengineering ; Original Article ; Sorbents ; Stone ; Toxicity ; Zirconium ; Zirconium oxides</subject><ispartof>Applied nanoscience, 2023-09, Vol.13 (9), p.6053-6066</ispartof><rights>King Abdulaziz City for Science and Technology 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-3dc877c186e90b79250a5d189a8b4ead03627d3af30f23783c30cef5bc280bbc3</citedby><cites>FETCH-LOGICAL-c319t-3dc877c186e90b79250a5d189a8b4ead03627d3af30f23783c30cef5bc280bbc3</cites><orcidid>0000-0001-6224-413X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s13204-022-02599-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s13204-022-02599-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Hussain, Tauqeer</creatorcontrib><creatorcontrib>Akhter, Naheed</creatorcontrib><creatorcontrib>Nadeem, Raziya</creatorcontrib><creatorcontrib>Rashid, Umer</creatorcontrib><creatorcontrib>Noreen, Saima</creatorcontrib><creatorcontrib>Anjum, Shazia</creatorcontrib><creatorcontrib>Ullah, Sajid</creatorcontrib><creatorcontrib>Hussain, Hafiza Raazia</creatorcontrib><creatorcontrib>Ashfaq, Aamna</creatorcontrib><creatorcontrib>Perveen, Shazia</creatorcontrib><creatorcontrib>A. Alharthi, Fahad</creatorcontrib><creatorcontrib>Kazerooni, Elham Ahmed</creatorcontrib><title>Biogenic synthesis of date stones biochar-based zirconium oxide nanocomposite for the removal of hexavalent chromium from aqueous solution</title><title>Applied nanoscience</title><addtitle>Appl Nanosci</addtitle><description>Pollution of water has become the main problem around the world; chromium (Cr) has several industrial applications. However, Cr is considered very toxic pollutant, because of its carcinogenicity and high toxicity. The existing methods for the treatment of heavy metals are not economical, difficult to operate, and not eco-friendly. The biosorption process is easy to operate, cost effective as well as eco-friendly for the elimination of the toxic metal. In the present work, a zirconium oxide/date stones biochar bio-nanocomposite (ZrO
2
BNC) was utilized as low-cost biosorbent to remove the toxic Cr (VI). The modification of the activated bio-nanocomposite was confirmed using scanning electron microscopy (SEM), energy-dispersive X-ray (EDX), UV–Vis and Fourier-transform infrared (FTIR) spectroscopy. Optimized condition of various parameters for removal of chromium ion by zirconium oxide bio-nanocomposite (ZrO
2
BNC) was observed at the pH = 5, contact time 120 min, initial concentration 100 ppm, while 0.1 g sorbent dose. The results showed that the sorption process optimally correlated with Langmuir and 1st kinetic models with
R
2
value of 0.999. The percentage removal of Cr (VI) ions was checked by atomic absorbance spectrophotometer subsequently before and after the process of adsorption. These findings demonstrated that produced ZrO
2
BNC can be a cost effective, potential, and novel adsorbent for removel of contaminated chromium metal ions from the aqueous environment.</description><subject>Aqueous environments</subject><subject>Aqueous solutions</subject><subject>Carcinogenicity</subject><subject>Carcinogens</subject><subject>Chemistry and Materials Science</subject><subject>Fourier transforms</subject><subject>Heavy metals</subject><subject>Hexavalent chromium</subject><subject>Industrial applications</subject><subject>Materials Science</subject><subject>Membrane Biology</subject><subject>Nanochemistry</subject><subject>Nanocomposites</subject><subject>Nanotechnology</subject><subject>Nanotechnology and Microengineering</subject><subject>Original Article</subject><subject>Sorbents</subject><subject>Stone</subject><subject>Toxicity</subject><subject>Zirconium</subject><subject>Zirconium oxides</subject><issn>2190-5509</issn><issn>2190-5517</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9kMtOwzAQRSMEElXpD7CyxDrgRxPHS6h4SZXYwNpyHKd11XiKJ0FtP4GvxqUIdow0mlncc2d0s-yS0WtGqbxBJjid5pTz1IVS-f4kG3GmaF4UTJ7-7lSdZxPEFU1VTGUpilH2eedh4YK3BHehXzr0SKAljekdwR6CQ1J7sEsT89qga8jeRwvBDx2BrW8cCSaAhW4D6BPSQiTJhUTXwYdZH6yWbmvS6kJP7DJCd0DbNIl5HxwMSBDWQ-8hXGRnrVmjm_zMcfb2cP86e8rnL4_Ps9t5bgVTfS4aW0lpWVU6RWupeEFN0bBKmaqeOtNQUXLZCNMK2nIhK2EFta4tassrWtdWjLOro-8mQnoBe72CIYZ0UvNKlooJQVlS8aPKRkCMrtWb6DsTd5pRfYhdH2PXKXb9HbveJ0gcIUzisHDxz_of6gt9KImH</recordid><startdate>20230901</startdate><enddate>20230901</enddate><creator>Hussain, Tauqeer</creator><creator>Akhter, Naheed</creator><creator>Nadeem, Raziya</creator><creator>Rashid, Umer</creator><creator>Noreen, Saima</creator><creator>Anjum, Shazia</creator><creator>Ullah, Sajid</creator><creator>Hussain, Hafiza Raazia</creator><creator>Ashfaq, Aamna</creator><creator>Perveen, Shazia</creator><creator>A. Alharthi, Fahad</creator><creator>Kazerooni, Elham Ahmed</creator><general>Springer International Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-6224-413X</orcidid></search><sort><creationdate>20230901</creationdate><title>Biogenic synthesis of date stones biochar-based zirconium oxide nanocomposite for the removal of hexavalent chromium from aqueous solution</title><author>Hussain, Tauqeer ; Akhter, Naheed ; Nadeem, Raziya ; Rashid, Umer ; Noreen, Saima ; Anjum, Shazia ; Ullah, Sajid ; Hussain, Hafiza Raazia ; Ashfaq, Aamna ; Perveen, Shazia ; A. Alharthi, Fahad ; Kazerooni, Elham Ahmed</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-3dc877c186e90b79250a5d189a8b4ead03627d3af30f23783c30cef5bc280bbc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Aqueous environments</topic><topic>Aqueous solutions</topic><topic>Carcinogenicity</topic><topic>Carcinogens</topic><topic>Chemistry and Materials Science</topic><topic>Fourier transforms</topic><topic>Heavy metals</topic><topic>Hexavalent chromium</topic><topic>Industrial applications</topic><topic>Materials Science</topic><topic>Membrane Biology</topic><topic>Nanochemistry</topic><topic>Nanocomposites</topic><topic>Nanotechnology</topic><topic>Nanotechnology and Microengineering</topic><topic>Original Article</topic><topic>Sorbents</topic><topic>Stone</topic><topic>Toxicity</topic><topic>Zirconium</topic><topic>Zirconium oxides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hussain, Tauqeer</creatorcontrib><creatorcontrib>Akhter, Naheed</creatorcontrib><creatorcontrib>Nadeem, Raziya</creatorcontrib><creatorcontrib>Rashid, Umer</creatorcontrib><creatorcontrib>Noreen, Saima</creatorcontrib><creatorcontrib>Anjum, Shazia</creatorcontrib><creatorcontrib>Ullah, Sajid</creatorcontrib><creatorcontrib>Hussain, Hafiza Raazia</creatorcontrib><creatorcontrib>Ashfaq, Aamna</creatorcontrib><creatorcontrib>Perveen, Shazia</creatorcontrib><creatorcontrib>A. 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Alharthi, Fahad</au><au>Kazerooni, Elham Ahmed</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Biogenic synthesis of date stones biochar-based zirconium oxide nanocomposite for the removal of hexavalent chromium from aqueous solution</atitle><jtitle>Applied nanoscience</jtitle><stitle>Appl Nanosci</stitle><date>2023-09-01</date><risdate>2023</risdate><volume>13</volume><issue>9</issue><spage>6053</spage><epage>6066</epage><pages>6053-6066</pages><issn>2190-5509</issn><eissn>2190-5517</eissn><abstract>Pollution of water has become the main problem around the world; chromium (Cr) has several industrial applications. However, Cr is considered very toxic pollutant, because of its carcinogenicity and high toxicity. The existing methods for the treatment of heavy metals are not economical, difficult to operate, and not eco-friendly. The biosorption process is easy to operate, cost effective as well as eco-friendly for the elimination of the toxic metal. In the present work, a zirconium oxide/date stones biochar bio-nanocomposite (ZrO
2
BNC) was utilized as low-cost biosorbent to remove the toxic Cr (VI). The modification of the activated bio-nanocomposite was confirmed using scanning electron microscopy (SEM), energy-dispersive X-ray (EDX), UV–Vis and Fourier-transform infrared (FTIR) spectroscopy. Optimized condition of various parameters for removal of chromium ion by zirconium oxide bio-nanocomposite (ZrO
2
BNC) was observed at the pH = 5, contact time 120 min, initial concentration 100 ppm, while 0.1 g sorbent dose. The results showed that the sorption process optimally correlated with Langmuir and 1st kinetic models with
R
2
value of 0.999. The percentage removal of Cr (VI) ions was checked by atomic absorbance spectrophotometer subsequently before and after the process of adsorption. These findings demonstrated that produced ZrO
2
BNC can be a cost effective, potential, and novel adsorbent for removel of contaminated chromium metal ions from the aqueous environment.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s13204-022-02599-z</doi><tpages>14</tpages><orcidid>https://orcid.org/0000-0001-6224-413X</orcidid></addata></record> |
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| subjects | Aqueous environments Aqueous solutions Carcinogenicity Carcinogens Chemistry and Materials Science Fourier transforms Heavy metals Hexavalent chromium Industrial applications Materials Science Membrane Biology Nanochemistry Nanocomposites Nanotechnology Nanotechnology and Microengineering Original Article Sorbents Stone Toxicity Zirconium Zirconium oxides |
| title | Biogenic synthesis of date stones biochar-based zirconium oxide nanocomposite for the removal of hexavalent chromium from aqueous solution |
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