Formation of Formic Acid and Its Esters in Oxidation of Fatty Acid Methyl Esters
Pathways of formation of low-boiling products in the course of oxidation of fatty acid methyl esters with atmospheric oxygen in a bubbling column were studied. These products are continuously removed from the reactor under the action of high temperature at continuous air supply. Two kinds of feedsto...
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| Veröffentlicht in: | Russian journal of applied chemistry 2023, Vol.96 (1), p.91-98 |
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| container_title | Russian journal of applied chemistry |
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| creator | Savel’ev, E. A. Cherepanova, A. D. Sapunov, V. N. |
| description | Pathways of formation of low-boiling products in the course of oxidation of fatty acid methyl esters with atmospheric oxygen in a bubbling column were studied. These products are continuously removed from the reactor under the action of high temperature at continuous air supply. Two kinds of feedstock with different content of esters of mono- and diunsaturated fatty acids (methyl esters of fatty acids of olive and sunflower oils) were used in the study. Along with acids and aldehydes forming the major fraction of low-boiling products, compounds containing ester groups were detected. The
1
Н and
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С NMR analysis revealed the presence of formic acid esters in the samples. The formate formation mechanism involving the Baeyer–Villiger reaction of aldehydes with hydroperoxides in the reaction volume was suggested. |
| doi_str_mv | 10.1134/S1070427223010123 |
| format | Article |
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1
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С NMR analysis revealed the presence of formic acid esters in the samples. The formate formation mechanism involving the Baeyer–Villiger reaction of aldehydes with hydroperoxides in the reaction volume was suggested.</description><identifier>ISSN: 1070-4272</identifier><identifier>EISSN: 1608-3296</identifier><identifier>DOI: 10.1134/S1070427223010123</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Aldehydes ; Boiling ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Esters ; Fatty acids ; Formic acid ; High temperature ; Industrial Chemistry/Chemical Engineering ; NMR ; Nuclear magnetic resonance ; Organic Synthesis and Industrial Organic Chemistry ; Oxidation ; Sunflower oil</subject><ispartof>Russian journal of applied chemistry, 2023, Vol.96 (1), p.91-98</ispartof><rights>Pleiades Publishing, Ltd. 2023</rights><rights>Pleiades Publishing, Ltd. 2023.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-e7786a0ddbb1f0b15507ff83a1a41220490f33598735dd177a9a92cf0ab869773</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070427223010123$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070427223010123$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Savel’ev, E. A.</creatorcontrib><creatorcontrib>Cherepanova, A. D.</creatorcontrib><creatorcontrib>Sapunov, V. N.</creatorcontrib><title>Formation of Formic Acid and Its Esters in Oxidation of Fatty Acid Methyl Esters</title><title>Russian journal of applied chemistry</title><addtitle>Russ J Appl Chem</addtitle><description>Pathways of formation of low-boiling products in the course of oxidation of fatty acid methyl esters with atmospheric oxygen in a bubbling column were studied. These products are continuously removed from the reactor under the action of high temperature at continuous air supply. Two kinds of feedstock with different content of esters of mono- and diunsaturated fatty acids (methyl esters of fatty acids of olive and sunflower oils) were used in the study. Along with acids and aldehydes forming the major fraction of low-boiling products, compounds containing ester groups were detected. The
1
Н and
13
С NMR analysis revealed the presence of formic acid esters in the samples. The formate formation mechanism involving the Baeyer–Villiger reaction of aldehydes with hydroperoxides in the reaction volume was suggested.</description><subject>Aldehydes</subject><subject>Boiling</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Esters</subject><subject>Fatty acids</subject><subject>Formic acid</subject><subject>High temperature</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Organic Synthesis and Industrial Organic Chemistry</subject><subject>Oxidation</subject><subject>Sunflower oil</subject><issn>1070-4272</issn><issn>1608-3296</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1kE9LAzEQxYMoWKsfwFvA8-pMsps_x1KqFioV1POS3SS6pd2tSQr227tlCz2Ip5nh_d4beITcItwj8vzhDUFCziRjHBCQ8TMyQgEq40yL837v5eygX5KrGFcAoIVQI_L62IWNSU3X0s7Tw9HUdFI3lprW0nmKdBaTC5E2LV3-NPaEmpT2A_ni0td-fQSvyYU36-hujnNMPh5n79PnbLF8mk8ni6xmQqXMSamEAWurCj1UWBQgvVfcoMmRMcg1eM4LrSQvrEUpjTaa1R5MpYSWko_J3ZC7Dd33zsVUrrpdaPuXJVNSABZC6Z7CgapDF2NwvtyGZmPCvkQoD8WVf4rrPWzwxJ5tP104Jf9v-gWXVGzg</recordid><startdate>2023</startdate><enddate>2023</enddate><creator>Savel’ev, E. A.</creator><creator>Cherepanova, A. D.</creator><creator>Sapunov, V. N.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2023</creationdate><title>Formation of Formic Acid and Its Esters in Oxidation of Fatty Acid Methyl Esters</title><author>Savel’ev, E. A. ; Cherepanova, A. D. ; Sapunov, V. N.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-e7786a0ddbb1f0b15507ff83a1a41220490f33598735dd177a9a92cf0ab869773</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Aldehydes</topic><topic>Boiling</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Esters</topic><topic>Fatty acids</topic><topic>Formic acid</topic><topic>High temperature</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Organic Synthesis and Industrial Organic Chemistry</topic><topic>Oxidation</topic><topic>Sunflower oil</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Savel’ev, E. A.</creatorcontrib><creatorcontrib>Cherepanova, A. D.</creatorcontrib><creatorcontrib>Sapunov, V. N.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of applied chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Savel’ev, E. A.</au><au>Cherepanova, A. D.</au><au>Sapunov, V. N.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Formation of Formic Acid and Its Esters in Oxidation of Fatty Acid Methyl Esters</atitle><jtitle>Russian journal of applied chemistry</jtitle><stitle>Russ J Appl Chem</stitle><date>2023</date><risdate>2023</risdate><volume>96</volume><issue>1</issue><spage>91</spage><epage>98</epage><pages>91-98</pages><issn>1070-4272</issn><eissn>1608-3296</eissn><abstract>Pathways of formation of low-boiling products in the course of oxidation of fatty acid methyl esters with atmospheric oxygen in a bubbling column were studied. These products are continuously removed from the reactor under the action of high temperature at continuous air supply. Two kinds of feedstock with different content of esters of mono- and diunsaturated fatty acids (methyl esters of fatty acids of olive and sunflower oils) were used in the study. Along with acids and aldehydes forming the major fraction of low-boiling products, compounds containing ester groups were detected. The
1
Н and
13
С NMR analysis revealed the presence of formic acid esters in the samples. The formate formation mechanism involving the Baeyer–Villiger reaction of aldehydes with hydroperoxides in the reaction volume was suggested.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070427223010123</doi><tpages>8</tpages></addata></record> |
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| language | eng |
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| subjects | Aldehydes Boiling Chemistry Chemistry and Materials Science Chemistry/Food Science Esters Fatty acids Formic acid High temperature Industrial Chemistry/Chemical Engineering NMR Nuclear magnetic resonance Organic Synthesis and Industrial Organic Chemistry Oxidation Sunflower oil |
| title | Formation of Formic Acid and Its Esters in Oxidation of Fatty Acid Methyl Esters |
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