Study of a TiO2/Ti4O7-coated plastic optic fiber photo-anode for advanced oxidation processes
Using the dip-coating technique, a photo-anode based on a plastic optical fiber (POF) was coated with a mixture of titanium oxide nanoparticles (TiO 2 :Ti 4 O 7 ). The semiconductor-coated material was prepared so that UV radiation fed into the fiber would escape along its path, photo-exciting the e...
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Veröffentlicht in: | Journal of solid state electrochemistry 2023-11, Vol.27 (11), p.2893-2904 |
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container_title | Journal of solid state electrochemistry |
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creator | Azúa-Humara, Ana Daniela Martínez-Sánchez, Carolina Robles, Irma García-Espinoza, Josué Daniel Salazar-López, María L. Esquivel, Karen Godínez, Luis A. |
description | Using the dip-coating technique, a photo-anode based on a plastic optical fiber (POF) was coated with a mixture of titanium oxide nanoparticles (TiO
2
:Ti
4
O
7
). The semiconductor-coated material was prepared so that UV radiation fed into the fiber would escape along its path, photo-exciting the electrically polarized semiconductor film and producing oxidant species capable of degrading pollutant chemicals in aqueous solution. The photoelectrode was developed to evaluate the potential degradation of organic pollutants in aqueous solutions, and for this purpose, methyl red was used to assess the photo-anode performance under photocatalysis, electrocatalysis, and photo-electrocatalysis processes. The results revealed that, as expected from the specific properties of TiO
2
and Ti
4
O
7
, the TiO
2
:Ti
4
O
7
-coated POF substrates showed a synergistic effect when UV light and electrical polarization are applied. The main purpose of using POFs instead of conventional SiO
2
fibers is that the former implies substantially lower cost and mechanical flexibility, which will result in the future novel photo-electrochemical arrangements for water treatment. |
doi_str_mv | 10.1007/s10008-023-05512-y |
format | Article |
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2
:Ti
4
O
7
). The semiconductor-coated material was prepared so that UV radiation fed into the fiber would escape along its path, photo-exciting the electrically polarized semiconductor film and producing oxidant species capable of degrading pollutant chemicals in aqueous solution. The photoelectrode was developed to evaluate the potential degradation of organic pollutants in aqueous solutions, and for this purpose, methyl red was used to assess the photo-anode performance under photocatalysis, electrocatalysis, and photo-electrocatalysis processes. The results revealed that, as expected from the specific properties of TiO
2
and Ti
4
O
7
, the TiO
2
:Ti
4
O
7
-coated POF substrates showed a synergistic effect when UV light and electrical polarization are applied. The main purpose of using POFs instead of conventional SiO
2
fibers is that the former implies substantially lower cost and mechanical flexibility, which will result in the future novel photo-electrochemical arrangements for water treatment.</description><identifier>ISSN: 1432-8488</identifier><identifier>EISSN: 1433-0768</identifier><identifier>DOI: 10.1007/s10008-023-05512-y</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Analytical Chemistry ; Anodizing ; Aqueous solutions ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Condensed Matter Physics ; Dip coatings ; Electrocatalysis ; Electrochemistry ; Electrode polarization ; Energy Storage ; Immersion coating ; Nanoparticles ; Optical fibers ; Original Paper ; Oxidation ; Oxidizing agents ; Photoanodes ; Physical Chemistry ; Pollutants ; Silicon dioxide ; Substrates ; Synergistic effect ; Titanium dioxide ; Titanium oxides ; Ultraviolet radiation ; Water treatment</subject><ispartof>Journal of solid state electrochemistry, 2023-11, Vol.27 (11), p.2893-2904</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-a1b16064fab86795e9ad367eb8fbc2b4b2a4c3e98ea93dbd9b4cda34fe175bfc3</citedby><cites>FETCH-LOGICAL-c319t-a1b16064fab86795e9ad367eb8fbc2b4b2a4c3e98ea93dbd9b4cda34fe175bfc3</cites><orcidid>0000-0002-4136-3858</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10008-023-05512-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10008-023-05512-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Azúa-Humara, Ana Daniela</creatorcontrib><creatorcontrib>Martínez-Sánchez, Carolina</creatorcontrib><creatorcontrib>Robles, Irma</creatorcontrib><creatorcontrib>García-Espinoza, Josué Daniel</creatorcontrib><creatorcontrib>Salazar-López, María L.</creatorcontrib><creatorcontrib>Esquivel, Karen</creatorcontrib><creatorcontrib>Godínez, Luis A.</creatorcontrib><title>Study of a TiO2/Ti4O7-coated plastic optic fiber photo-anode for advanced oxidation processes</title><title>Journal of solid state electrochemistry</title><addtitle>J Solid State Electrochem</addtitle><description>Using the dip-coating technique, a photo-anode based on a plastic optical fiber (POF) was coated with a mixture of titanium oxide nanoparticles (TiO
2
:Ti
4
O
7
). The semiconductor-coated material was prepared so that UV radiation fed into the fiber would escape along its path, photo-exciting the electrically polarized semiconductor film and producing oxidant species capable of degrading pollutant chemicals in aqueous solution. The photoelectrode was developed to evaluate the potential degradation of organic pollutants in aqueous solutions, and for this purpose, methyl red was used to assess the photo-anode performance under photocatalysis, electrocatalysis, and photo-electrocatalysis processes. The results revealed that, as expected from the specific properties of TiO
2
and Ti
4
O
7
, the TiO
2
:Ti
4
O
7
-coated POF substrates showed a synergistic effect when UV light and electrical polarization are applied. The main purpose of using POFs instead of conventional SiO
2
fibers is that the former implies substantially lower cost and mechanical flexibility, which will result in the future novel photo-electrochemical arrangements for water treatment.</description><subject>Analytical Chemistry</subject><subject>Anodizing</subject><subject>Aqueous solutions</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Dip coatings</subject><subject>Electrocatalysis</subject><subject>Electrochemistry</subject><subject>Electrode polarization</subject><subject>Energy Storage</subject><subject>Immersion coating</subject><subject>Nanoparticles</subject><subject>Optical fibers</subject><subject>Original Paper</subject><subject>Oxidation</subject><subject>Oxidizing agents</subject><subject>Photoanodes</subject><subject>Physical Chemistry</subject><subject>Pollutants</subject><subject>Silicon dioxide</subject><subject>Substrates</subject><subject>Synergistic effect</subject><subject>Titanium dioxide</subject><subject>Titanium oxides</subject><subject>Ultraviolet radiation</subject><subject>Water treatment</subject><issn>1432-8488</issn><issn>1433-0768</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9kElLAzEYhoMoWKt_wFPAc2y2mWSOUtxA6MF6lJBVp9TJmEzF-femHcGbl2-Bd4EHgEuCrwnGYpHLxBJhyhCuKkLReARmhLPyiloeH26KJJfyFJzlvMGYiJrgGXh9HnZuhDFADdftii7WLV8JZKMevIP9VuehtTD2-xla4xPs3-MQke6i8zDEBLX70p0t4vjdOj20sYN9itbn7PM5OAl6m_3F756Dl7vb9fIBPa3uH5c3T8gy0gxIE0NqXPOgjaxFU_lGO1YLb2QwlhpuqOaW-UZ63TBnXGO4dZrx4ImoTLBsDq6m3NL8ufN5UJu4S12pVFSKiley5BYVnVQ2xZyTD6pP7YdOoyJY7TGqCaMqGNUBoxqLiU2mXMTdm09_0f-4fgAPjHcB</recordid><startdate>20231101</startdate><enddate>20231101</enddate><creator>Azúa-Humara, Ana Daniela</creator><creator>Martínez-Sánchez, Carolina</creator><creator>Robles, Irma</creator><creator>García-Espinoza, Josué Daniel</creator><creator>Salazar-López, María L.</creator><creator>Esquivel, Karen</creator><creator>Godínez, Luis A.</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-4136-3858</orcidid></search><sort><creationdate>20231101</creationdate><title>Study of a TiO2/Ti4O7-coated plastic optic fiber photo-anode for advanced oxidation processes</title><author>Azúa-Humara, Ana Daniela ; Martínez-Sánchez, Carolina ; Robles, Irma ; García-Espinoza, Josué Daniel ; Salazar-López, María L. ; Esquivel, Karen ; Godínez, Luis A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-a1b16064fab86795e9ad367eb8fbc2b4b2a4c3e98ea93dbd9b4cda34fe175bfc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Analytical Chemistry</topic><topic>Anodizing</topic><topic>Aqueous solutions</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Dip coatings</topic><topic>Electrocatalysis</topic><topic>Electrochemistry</topic><topic>Electrode polarization</topic><topic>Energy Storage</topic><topic>Immersion coating</topic><topic>Nanoparticles</topic><topic>Optical fibers</topic><topic>Original Paper</topic><topic>Oxidation</topic><topic>Oxidizing agents</topic><topic>Photoanodes</topic><topic>Physical Chemistry</topic><topic>Pollutants</topic><topic>Silicon dioxide</topic><topic>Substrates</topic><topic>Synergistic effect</topic><topic>Titanium dioxide</topic><topic>Titanium oxides</topic><topic>Ultraviolet radiation</topic><topic>Water treatment</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Azúa-Humara, Ana Daniela</creatorcontrib><creatorcontrib>Martínez-Sánchez, Carolina</creatorcontrib><creatorcontrib>Robles, Irma</creatorcontrib><creatorcontrib>García-Espinoza, Josué Daniel</creatorcontrib><creatorcontrib>Salazar-López, María L.</creatorcontrib><creatorcontrib>Esquivel, Karen</creatorcontrib><creatorcontrib>Godínez, Luis A.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of solid state electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Azúa-Humara, Ana Daniela</au><au>Martínez-Sánchez, Carolina</au><au>Robles, Irma</au><au>García-Espinoza, Josué Daniel</au><au>Salazar-López, María L.</au><au>Esquivel, Karen</au><au>Godínez, Luis A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Study of a TiO2/Ti4O7-coated plastic optic fiber photo-anode for advanced oxidation processes</atitle><jtitle>Journal of solid state electrochemistry</jtitle><stitle>J Solid State Electrochem</stitle><date>2023-11-01</date><risdate>2023</risdate><volume>27</volume><issue>11</issue><spage>2893</spage><epage>2904</epage><pages>2893-2904</pages><issn>1432-8488</issn><eissn>1433-0768</eissn><abstract>Using the dip-coating technique, a photo-anode based on a plastic optical fiber (POF) was coated with a mixture of titanium oxide nanoparticles (TiO
2
:Ti
4
O
7
). The semiconductor-coated material was prepared so that UV radiation fed into the fiber would escape along its path, photo-exciting the electrically polarized semiconductor film and producing oxidant species capable of degrading pollutant chemicals in aqueous solution. The photoelectrode was developed to evaluate the potential degradation of organic pollutants in aqueous solutions, and for this purpose, methyl red was used to assess the photo-anode performance under photocatalysis, electrocatalysis, and photo-electrocatalysis processes. The results revealed that, as expected from the specific properties of TiO
2
and Ti
4
O
7
, the TiO
2
:Ti
4
O
7
-coated POF substrates showed a synergistic effect when UV light and electrical polarization are applied. The main purpose of using POFs instead of conventional SiO
2
fibers is that the former implies substantially lower cost and mechanical flexibility, which will result in the future novel photo-electrochemical arrangements for water treatment.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s10008-023-05512-y</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0002-4136-3858</orcidid></addata></record> |
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subjects | Analytical Chemistry Anodizing Aqueous solutions Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Condensed Matter Physics Dip coatings Electrocatalysis Electrochemistry Electrode polarization Energy Storage Immersion coating Nanoparticles Optical fibers Original Paper Oxidation Oxidizing agents Photoanodes Physical Chemistry Pollutants Silicon dioxide Substrates Synergistic effect Titanium dioxide Titanium oxides Ultraviolet radiation Water treatment |
title | Study of a TiO2/Ti4O7-coated plastic optic fiber photo-anode for advanced oxidation processes |
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