Study of a TiO2/Ti4O7-coated plastic optic fiber photo-anode for advanced oxidation processes

Using the dip-coating technique, a photo-anode based on a plastic optical fiber (POF) was coated with a mixture of titanium oxide nanoparticles (TiO 2 :Ti 4 O 7 ). The semiconductor-coated material was prepared so that UV radiation fed into the fiber would escape along its path, photo-exciting the e...

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Veröffentlicht in:Journal of solid state electrochemistry 2023-11, Vol.27 (11), p.2893-2904
Hauptverfasser: Azúa-Humara, Ana Daniela, Martínez-Sánchez, Carolina, Robles, Irma, García-Espinoza, Josué Daniel, Salazar-López, María L., Esquivel, Karen, Godínez, Luis A.
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container_end_page 2904
container_issue 11
container_start_page 2893
container_title Journal of solid state electrochemistry
container_volume 27
creator Azúa-Humara, Ana Daniela
Martínez-Sánchez, Carolina
Robles, Irma
García-Espinoza, Josué Daniel
Salazar-López, María L.
Esquivel, Karen
Godínez, Luis A.
description Using the dip-coating technique, a photo-anode based on a plastic optical fiber (POF) was coated with a mixture of titanium oxide nanoparticles (TiO 2 :Ti 4 O 7 ). The semiconductor-coated material was prepared so that UV radiation fed into the fiber would escape along its path, photo-exciting the electrically polarized semiconductor film and producing oxidant species capable of degrading pollutant chemicals in aqueous solution. The photoelectrode was developed to evaluate the potential degradation of organic pollutants in aqueous solutions, and for this purpose, methyl red was used to assess the photo-anode performance under photocatalysis, electrocatalysis, and photo-electrocatalysis processes. The results revealed that, as expected from the specific properties of TiO 2 and Ti 4 O 7 , the TiO 2 :Ti 4 O 7 -coated POF substrates showed a synergistic effect when UV light and electrical polarization are applied. The main purpose of using POFs instead of conventional SiO 2 fibers is that the former implies substantially lower cost and mechanical flexibility, which will result in the future novel photo-electrochemical arrangements for water treatment.
doi_str_mv 10.1007/s10008-023-05512-y
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subjects Analytical Chemistry
Anodizing
Aqueous solutions
Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Condensed Matter Physics
Dip coatings
Electrocatalysis
Electrochemistry
Electrode polarization
Energy Storage
Immersion coating
Nanoparticles
Optical fibers
Original Paper
Oxidation
Oxidizing agents
Photoanodes
Physical Chemistry
Pollutants
Silicon dioxide
Substrates
Synergistic effect
Titanium dioxide
Titanium oxides
Ultraviolet radiation
Water treatment
title Study of a TiO2/Ti4O7-coated plastic optic fiber photo-anode for advanced oxidation processes
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