Spidermen Strategy for Stable 24% Efficiency Perovskite Solar Cells
The interface energetics‐modification plays an important role in improving the power conversion efficiency (PCE) among the perovskite solar cells (PSCs). Considering the low carrier mobility caused by defects in PSCs, a double‐layer modification engineering strategy is adopted to introduce the “spid...
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| Veröffentlicht in: | Advanced functional materials 2023-10, Vol.33 (41) |
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| creator | Liu, Xuping Li, Qinghua Zheng, Juanjuan Xu, Jiewen Chen, Zixia Li, Zimin Liu, Jie Liang, Shengyong Wang, Deng Zhang, Zhenghe Jin, Xiao Wu, Jihuai Zhang, Xingcai |
| description | The interface energetics‐modification plays an important role in improving the power conversion efficiency (PCE) among the perovskite solar cells (PSCs). Considering the low carrier mobility caused by defects in PSCs, a double‐layer modification engineering strategy is adopted to introduce the “spiderman” NOBF
4
(nitrosonium tetrafluoroborate) between tin dioxide (SnO
2
and perovskite layers. NO
+
, as the interfacial bonding layer, can passivate the oxygen vacancy in SnO
2
, while BF
4
−
can optimize the defects in the bulk of perovskite. This conclusion is confirmed by theoretical calculation and transmission electron microscopy (TEM). The synergistic effect of NO
+
and BF
4
−
distinctly heightens the carrier extraction efficiency, and the PCE of PSCs is 24.04% with a fill factor (FF) of 82.98% and long‐term stability. This study underlines the effectiveness of multifunctional additives in improving interface contact and enhancing PCE of PSCs. |
| doi_str_mv | 10.1002/adfm.202308108 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2874672740</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2874672740</sourcerecordid><originalsourceid>FETCH-LOGICAL-c267t-c4b2aa414d2d0474b6eced90be96f484bad52e1c8654ab44ad2f3b4eec33db7e3</originalsourceid><addsrcrecordid>eNo9kE1LAzEYhIMoWKtXzwHxuGs-3ibboyy1CgWFKngL-XgjW3e7NdkK_fe2VHqaGRhm4CHklrOSMyYebIhdKZiQrOKsOiMjrrgqJBPV-cnzz0tylfOKMa61hBGpl5smYOpwTZdDsgN-7Wjs0z5Y1yIVcE9nMTa-wbXf0TdM_W_-bgaky761idbYtvmaXETbZrz51zH5eJq918_F4nX-Uj8uCi-UHgoPTlgLHIIIDDQ4hR7DlDmcqggVOBsmArmv1ASsA7BBROkA0UsZnEY5JnfH3U3qf7aYB7Pqt2m9vzSi0qC00MD2rfLY8qnPOWE0m9R0Nu0MZ-YAyhxAmRMo-Qcgh1uv</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2874672740</pqid></control><display><type>article</type><title>Spidermen Strategy for Stable 24% Efficiency Perovskite Solar Cells</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Liu, Xuping ; Li, Qinghua ; Zheng, Juanjuan ; Xu, Jiewen ; Chen, Zixia ; Li, Zimin ; Liu, Jie ; Liang, Shengyong ; Wang, Deng ; Zhang, Zhenghe ; Jin, Xiao ; Wu, Jihuai ; Zhang, Xingcai</creator><creatorcontrib>Liu, Xuping ; Li, Qinghua ; Zheng, Juanjuan ; Xu, Jiewen ; Chen, Zixia ; Li, Zimin ; Liu, Jie ; Liang, Shengyong ; Wang, Deng ; Zhang, Zhenghe ; Jin, Xiao ; Wu, Jihuai ; Zhang, Xingcai</creatorcontrib><description>The interface energetics‐modification plays an important role in improving the power conversion efficiency (PCE) among the perovskite solar cells (PSCs). Considering the low carrier mobility caused by defects in PSCs, a double‐layer modification engineering strategy is adopted to introduce the “spiderman” NOBF
4
(nitrosonium tetrafluoroborate) between tin dioxide (SnO
2
and perovskite layers. NO
+
, as the interfacial bonding layer, can passivate the oxygen vacancy in SnO
2
, while BF
4
−
can optimize the defects in the bulk of perovskite. This conclusion is confirmed by theoretical calculation and transmission electron microscopy (TEM). The synergistic effect of NO
+
and BF
4
−
distinctly heightens the carrier extraction efficiency, and the PCE of PSCs is 24.04% with a fill factor (FF) of 82.98% and long‐term stability. This study underlines the effectiveness of multifunctional additives in improving interface contact and enhancing PCE of PSCs.</description><identifier>ISSN: 1616-301X</identifier><identifier>EISSN: 1616-3028</identifier><identifier>DOI: 10.1002/adfm.202308108</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc</publisher><subject>Additives ; Carrier mobility ; Defects ; Energy conversion efficiency ; Interface stability ; Materials science ; Perovskites ; Photovoltaic cells ; Solar cells ; Synergistic effect ; Tin dioxide</subject><ispartof>Advanced functional materials, 2023-10, Vol.33 (41)</ispartof><rights>2023 Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c267t-c4b2aa414d2d0474b6eced90be96f484bad52e1c8654ab44ad2f3b4eec33db7e3</citedby><cites>FETCH-LOGICAL-c267t-c4b2aa414d2d0474b6eced90be96f484bad52e1c8654ab44ad2f3b4eec33db7e3</cites><orcidid>0000-0001-7114-1095 ; 0000-0002-9820-1382 ; 0000-0002-5143-6678 ; 0000-0001-5032-1185</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Liu, Xuping</creatorcontrib><creatorcontrib>Li, Qinghua</creatorcontrib><creatorcontrib>Zheng, Juanjuan</creatorcontrib><creatorcontrib>Xu, Jiewen</creatorcontrib><creatorcontrib>Chen, Zixia</creatorcontrib><creatorcontrib>Li, Zimin</creatorcontrib><creatorcontrib>Liu, Jie</creatorcontrib><creatorcontrib>Liang, Shengyong</creatorcontrib><creatorcontrib>Wang, Deng</creatorcontrib><creatorcontrib>Zhang, Zhenghe</creatorcontrib><creatorcontrib>Jin, Xiao</creatorcontrib><creatorcontrib>Wu, Jihuai</creatorcontrib><creatorcontrib>Zhang, Xingcai</creatorcontrib><title>Spidermen Strategy for Stable 24% Efficiency Perovskite Solar Cells</title><title>Advanced functional materials</title><description>The interface energetics‐modification plays an important role in improving the power conversion efficiency (PCE) among the perovskite solar cells (PSCs). Considering the low carrier mobility caused by defects in PSCs, a double‐layer modification engineering strategy is adopted to introduce the “spiderman” NOBF
4
(nitrosonium tetrafluoroborate) between tin dioxide (SnO
2
and perovskite layers. NO
+
, as the interfacial bonding layer, can passivate the oxygen vacancy in SnO
2
, while BF
4
−
can optimize the defects in the bulk of perovskite. This conclusion is confirmed by theoretical calculation and transmission electron microscopy (TEM). The synergistic effect of NO
+
and BF
4
−
distinctly heightens the carrier extraction efficiency, and the PCE of PSCs is 24.04% with a fill factor (FF) of 82.98% and long‐term stability. This study underlines the effectiveness of multifunctional additives in improving interface contact and enhancing PCE of PSCs.</description><subject>Additives</subject><subject>Carrier mobility</subject><subject>Defects</subject><subject>Energy conversion efficiency</subject><subject>Interface stability</subject><subject>Materials science</subject><subject>Perovskites</subject><subject>Photovoltaic cells</subject><subject>Solar cells</subject><subject>Synergistic effect</subject><subject>Tin dioxide</subject><issn>1616-301X</issn><issn>1616-3028</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNo9kE1LAzEYhIMoWKtXzwHxuGs-3ibboyy1CgWFKngL-XgjW3e7NdkK_fe2VHqaGRhm4CHklrOSMyYebIhdKZiQrOKsOiMjrrgqJBPV-cnzz0tylfOKMa61hBGpl5smYOpwTZdDsgN-7Wjs0z5Y1yIVcE9nMTa-wbXf0TdM_W_-bgaky761idbYtvmaXETbZrz51zH5eJq918_F4nX-Uj8uCi-UHgoPTlgLHIIIDDQ4hR7DlDmcqggVOBsmArmv1ASsA7BBROkA0UsZnEY5JnfH3U3qf7aYB7Pqt2m9vzSi0qC00MD2rfLY8qnPOWE0m9R0Nu0MZ-YAyhxAmRMo-Qcgh1uv</recordid><startdate>20231001</startdate><enddate>20231001</enddate><creator>Liu, Xuping</creator><creator>Li, Qinghua</creator><creator>Zheng, Juanjuan</creator><creator>Xu, Jiewen</creator><creator>Chen, Zixia</creator><creator>Li, Zimin</creator><creator>Liu, Jie</creator><creator>Liang, Shengyong</creator><creator>Wang, Deng</creator><creator>Zhang, Zhenghe</creator><creator>Jin, Xiao</creator><creator>Wu, Jihuai</creator><creator>Zhang, Xingcai</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0001-7114-1095</orcidid><orcidid>https://orcid.org/0000-0002-9820-1382</orcidid><orcidid>https://orcid.org/0000-0002-5143-6678</orcidid><orcidid>https://orcid.org/0000-0001-5032-1185</orcidid></search><sort><creationdate>20231001</creationdate><title>Spidermen Strategy for Stable 24% Efficiency Perovskite Solar Cells</title><author>Liu, Xuping ; Li, Qinghua ; Zheng, Juanjuan ; Xu, Jiewen ; Chen, Zixia ; Li, Zimin ; Liu, Jie ; Liang, Shengyong ; Wang, Deng ; Zhang, Zhenghe ; Jin, Xiao ; Wu, Jihuai ; Zhang, Xingcai</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c267t-c4b2aa414d2d0474b6eced90be96f484bad52e1c8654ab44ad2f3b4eec33db7e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Additives</topic><topic>Carrier mobility</topic><topic>Defects</topic><topic>Energy conversion efficiency</topic><topic>Interface stability</topic><topic>Materials science</topic><topic>Perovskites</topic><topic>Photovoltaic cells</topic><topic>Solar cells</topic><topic>Synergistic effect</topic><topic>Tin dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Xuping</creatorcontrib><creatorcontrib>Li, Qinghua</creatorcontrib><creatorcontrib>Zheng, Juanjuan</creatorcontrib><creatorcontrib>Xu, Jiewen</creatorcontrib><creatorcontrib>Chen, Zixia</creatorcontrib><creatorcontrib>Li, Zimin</creatorcontrib><creatorcontrib>Liu, Jie</creatorcontrib><creatorcontrib>Liang, Shengyong</creatorcontrib><creatorcontrib>Wang, Deng</creatorcontrib><creatorcontrib>Zhang, Zhenghe</creatorcontrib><creatorcontrib>Jin, Xiao</creatorcontrib><creatorcontrib>Wu, Jihuai</creatorcontrib><creatorcontrib>Zhang, Xingcai</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Advanced functional materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Xuping</au><au>Li, Qinghua</au><au>Zheng, Juanjuan</au><au>Xu, Jiewen</au><au>Chen, Zixia</au><au>Li, Zimin</au><au>Liu, Jie</au><au>Liang, Shengyong</au><au>Wang, Deng</au><au>Zhang, Zhenghe</au><au>Jin, Xiao</au><au>Wu, Jihuai</au><au>Zhang, Xingcai</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Spidermen Strategy for Stable 24% Efficiency Perovskite Solar Cells</atitle><jtitle>Advanced functional materials</jtitle><date>2023-10-01</date><risdate>2023</risdate><volume>33</volume><issue>41</issue><issn>1616-301X</issn><eissn>1616-3028</eissn><abstract>The interface energetics‐modification plays an important role in improving the power conversion efficiency (PCE) among the perovskite solar cells (PSCs). Considering the low carrier mobility caused by defects in PSCs, a double‐layer modification engineering strategy is adopted to introduce the “spiderman” NOBF
4
(nitrosonium tetrafluoroborate) between tin dioxide (SnO
2
and perovskite layers. NO
+
, as the interfacial bonding layer, can passivate the oxygen vacancy in SnO
2
, while BF
4
−
can optimize the defects in the bulk of perovskite. This conclusion is confirmed by theoretical calculation and transmission electron microscopy (TEM). The synergistic effect of NO
+
and BF
4
−
distinctly heightens the carrier extraction efficiency, and the PCE of PSCs is 24.04% with a fill factor (FF) of 82.98% and long‐term stability. This study underlines the effectiveness of multifunctional additives in improving interface contact and enhancing PCE of PSCs.</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/adfm.202308108</doi><orcidid>https://orcid.org/0000-0001-7114-1095</orcidid><orcidid>https://orcid.org/0000-0002-9820-1382</orcidid><orcidid>https://orcid.org/0000-0002-5143-6678</orcidid><orcidid>https://orcid.org/0000-0001-5032-1185</orcidid></addata></record> |
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| subjects | Additives Carrier mobility Defects Energy conversion efficiency Interface stability Materials science Perovskites Photovoltaic cells Solar cells Synergistic effect Tin dioxide |
| title | Spidermen Strategy for Stable 24% Efficiency Perovskite Solar Cells |
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