The Role of Manganese Dioxide in Secondary Pollution of Freshwater Basins (According to Experimental Modeling Data)

— Experimental modeling was carried out for reductive dissolution of manganese(IV) oxyhydroxides of bottom sediments during the periods of hypoxia in freshwater basins. Along with iron(III) oxyhydroxides, those of Mn cause the secondary pollution of the water mass. It was shown that the hypoxia peri...

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Veröffentlicht in:Moscow University geology bulletin 2023-06, Vol.78 (3), p.437-441
Hauptverfasser: Savenko, A. V., Savenko, V. S.
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description — Experimental modeling was carried out for reductive dissolution of manganese(IV) oxyhydroxides of bottom sediments during the periods of hypoxia in freshwater basins. Along with iron(III) oxyhydroxides, those of Mn cause the secondary pollution of the water mass. It was shown that the hypoxia periods in the water mass might cause the accumulation of not only dissolved forms of manganese but also of trace elements adsorbed on manganese(IV) oxyhydroxides. The mass ratios to manganese of trace element impurities passing into a (Δ[ i ]/Δ[Mn] × 10 3 ) solution were estimated: Li, 0.41; Rb, 1.65; Cs, 0.010; Sr, 31.7; Ba, 50.3; Co, 0.093; Ni, 0.65; Сd, 0.046; Y, 0.070; La, 0.030; Ce, 0.086; Tl, 0.015; and U, 0.23.
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The mass ratios to manganese of trace element impurities passing into a (Δ[ i ]/Δ[Mn] × 10 3 ) solution were estimated: Li, 0.41; Rb, 1.65; Cs, 0.010; Sr, 31.7; Ba, 50.3; Co, 0.093; Ni, 0.65; Сd, 0.046; Y, 0.070; La, 0.030; Ce, 0.086; Tl, 0.015; and U, 0.23.</description><identifier>ISSN: 0145-8752</identifier><identifier>EISSN: 1934-8436</identifier><identifier>DOI: 10.3103/S0145875223030146</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Basins ; Bottom sediments ; Earth and Environmental Science ; Earth Sciences ; Freshwater ; Freshwater pollution ; Geology ; Hypoxia ; Inland water environment ; Manganese ; Manganese dioxide ; Mass ; Modelling ; Trace elements ; Water masses ; Water pollution</subject><ispartof>Moscow University geology bulletin, 2023-06, Vol.78 (3), p.437-441</ispartof><rights>Allerton Press, Inc. 2023. ISSN 0145-8752, Moscow University Geology Bulletin, 2023, Vol. 78, No. 3, pp. 437–441. © Allerton Press, Inc., 2023. 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subjects Basins
Bottom sediments
Earth and Environmental Science
Earth Sciences
Freshwater
Freshwater pollution
Geology
Hypoxia
Inland water environment
Manganese
Manganese dioxide
Mass
Modelling
Trace elements
Water masses
Water pollution
title The Role of Manganese Dioxide in Secondary Pollution of Freshwater Basins (According to Experimental Modeling Data)
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