Separation of Al3Zr Intermetallic Compound from Al–Zr Master Alloy Prepared by Molten Salt Electrolysis
This paper focuses on preparation of Al–Zr master alloy and Al 3 Zr intermetallic compound. A method is proposed to obtain Al 3 Zr intermetallic compound from Al–Zr master alloy by leaching. The alloy was prepared by electrolysis in 2.4NaF–AlF 3 –5 wt % CaF 2 –5 wt % ZrO 2 cryolite-based electrolyte...
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| Veröffentlicht in: | Russian Journal of Physical Chemistry A 2023-10, Vol.97 (10), p.2314-2320 |
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| container_issue | 10 |
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| container_title | Russian Journal of Physical Chemistry A |
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| creator | Chen, Liyu Wang, Zhaowen Yang, Youjian Tao, Wenju Shi, Zhongning Hu, Xianwei |
| description | This paper focuses on preparation of Al–Zr master alloy and Al
3
Zr intermetallic compound. A method is proposed to obtain Al
3
Zr intermetallic compound from Al–Zr master alloy by leaching. The alloy was prepared by electrolysis in 2.4NaF–AlF
3
–5 wt % CaF
2
–5 wt % ZrO
2
cryolite-based electrolyte with the molten Al as cathode and the high purity graphite as anode at 980°C. Zirconium was deposited in the form of solid Al
3
Zr at the bottom of the cathode alloy, and the main phase compositions of the obtained Al-base alloy product were Al phase and Al
3
Zr phase. Then, cube-shaped Al
3
Zr intermetallic compound particles with an average size of 37.8 μm were obtained from the Al–Zr master alloy product by combining alkaline and acidic leaching. |
| doi_str_mv | 10.1134/S0036024423100151 |
| format | Article |
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3
Zr intermetallic compound. A method is proposed to obtain Al
3
Zr intermetallic compound from Al–Zr master alloy by leaching. The alloy was prepared by electrolysis in 2.4NaF–AlF
3
–5 wt % CaF
2
–5 wt % ZrO
2
cryolite-based electrolyte with the molten Al as cathode and the high purity graphite as anode at 980°C. Zirconium was deposited in the form of solid Al
3
Zr at the bottom of the cathode alloy, and the main phase compositions of the obtained Al-base alloy product were Al phase and Al
3
Zr phase. Then, cube-shaped Al
3
Zr intermetallic compound particles with an average size of 37.8 μm were obtained from the Al–Zr master alloy product by combining alkaline and acidic leaching.</description><identifier>ISSN: 0036-0244</identifier><identifier>EISSN: 1531-863X</identifier><identifier>DOI: 10.1134/S0036024423100151</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Aluminum base alloys ; Aluminum fluorides ; Cathodes ; Chemistry ; Chemistry and Materials Science ; Cryolite ; Electrochemistry. Generation and Storage of Energy from Renewable Sources ; Electrolysis ; Intermetallic compounds ; Leaching ; Master alloys ; Molten salts ; Phase composition ; Physical Chemistry ; Zirconium dioxide</subject><ispartof>Russian Journal of Physical Chemistry A, 2023-10, Vol.97 (10), p.2314-2320</ispartof><rights>Pleiades Publishing, Ltd. 2023. ISSN 0036-0244, Russian Journal of Physical Chemistry A, 2023, Vol. 97, No. 10, pp. 2314–2320. © Pleiades Publishing, Ltd., 2023.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-63062529f2770477c7debae9e6243b5c32a9c62ea021e9e65e93ac9dc7a2cad13</citedby><cites>FETCH-LOGICAL-c316t-63062529f2770477c7debae9e6243b5c32a9c62ea021e9e65e93ac9dc7a2cad13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0036024423100151$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0036024423100151$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,782,786,27931,27932,41495,42564,51326</link.rule.ids></links><search><creatorcontrib>Chen, Liyu</creatorcontrib><creatorcontrib>Wang, Zhaowen</creatorcontrib><creatorcontrib>Yang, Youjian</creatorcontrib><creatorcontrib>Tao, Wenju</creatorcontrib><creatorcontrib>Shi, Zhongning</creatorcontrib><creatorcontrib>Hu, Xianwei</creatorcontrib><title>Separation of Al3Zr Intermetallic Compound from Al–Zr Master Alloy Prepared by Molten Salt Electrolysis</title><title>Russian Journal of Physical Chemistry A</title><addtitle>Russ. J. Phys. Chem</addtitle><description>This paper focuses on preparation of Al–Zr master alloy and Al
3
Zr intermetallic compound. A method is proposed to obtain Al
3
Zr intermetallic compound from Al–Zr master alloy by leaching. The alloy was prepared by electrolysis in 2.4NaF–AlF
3
–5 wt % CaF
2
–5 wt % ZrO
2
cryolite-based electrolyte with the molten Al as cathode and the high purity graphite as anode at 980°C. Zirconium was deposited in the form of solid Al
3
Zr at the bottom of the cathode alloy, and the main phase compositions of the obtained Al-base alloy product were Al phase and Al
3
Zr phase. Then, cube-shaped Al
3
Zr intermetallic compound particles with an average size of 37.8 μm were obtained from the Al–Zr master alloy product by combining alkaline and acidic leaching.</description><subject>Aluminum base alloys</subject><subject>Aluminum fluorides</subject><subject>Cathodes</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Cryolite</subject><subject>Electrochemistry. Generation and Storage of Energy from Renewable Sources</subject><subject>Electrolysis</subject><subject>Intermetallic compounds</subject><subject>Leaching</subject><subject>Master alloys</subject><subject>Molten salts</subject><subject>Phase composition</subject><subject>Physical Chemistry</subject><subject>Zirconium dioxide</subject><issn>0036-0244</issn><issn>1531-863X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1kM1Kw0AUhQdRsFYfwN2A6-j8JdMsS6laaFGIgrgJ08mNpEwycWa6yM538A19EidUcCGuLvee75wLB6FLSq4p5eKmIIRnhAnBOCWEpvQITWjKaTLL-MsxmoxyMuqn6Mz7HSFCCComqCmgV06FxnbY1nhu-KvDqy6AayEoYxqNF7bt7b6rcO1sG4mvj8_IbJSPUFyNHfCjG1OgwtsBb6wJ0OFCmYCXBnRw1gy-8efopFbGw8XPnKLn2-XT4j5ZP9ytFvN1ojnNQpJxkrGU5TWTkggptaxgqyCHjAm-TTVnKtcZA0UYHa8p5FzpvNJSMa0qyqfo6pDbO_u-Bx_Knd27Lr4s2UzyVLAYHyl6oLSz3juoy941rXJDSUk5Nlr-aTR62MHjI9u9gftN_t_0DWJVeIo</recordid><startdate>20231001</startdate><enddate>20231001</enddate><creator>Chen, Liyu</creator><creator>Wang, Zhaowen</creator><creator>Yang, Youjian</creator><creator>Tao, Wenju</creator><creator>Shi, Zhongning</creator><creator>Hu, Xianwei</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20231001</creationdate><title>Separation of Al3Zr Intermetallic Compound from Al–Zr Master Alloy Prepared by Molten Salt Electrolysis</title><author>Chen, Liyu ; Wang, Zhaowen ; Yang, Youjian ; Tao, Wenju ; Shi, Zhongning ; Hu, Xianwei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-63062529f2770477c7debae9e6243b5c32a9c62ea021e9e65e93ac9dc7a2cad13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Aluminum base alloys</topic><topic>Aluminum fluorides</topic><topic>Cathodes</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Cryolite</topic><topic>Electrochemistry. Generation and Storage of Energy from Renewable Sources</topic><topic>Electrolysis</topic><topic>Intermetallic compounds</topic><topic>Leaching</topic><topic>Master alloys</topic><topic>Molten salts</topic><topic>Phase composition</topic><topic>Physical Chemistry</topic><topic>Zirconium dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chen, Liyu</creatorcontrib><creatorcontrib>Wang, Zhaowen</creatorcontrib><creatorcontrib>Yang, Youjian</creatorcontrib><creatorcontrib>Tao, Wenju</creatorcontrib><creatorcontrib>Shi, Zhongning</creatorcontrib><creatorcontrib>Hu, Xianwei</creatorcontrib><collection>CrossRef</collection><jtitle>Russian Journal of Physical Chemistry A</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chen, Liyu</au><au>Wang, Zhaowen</au><au>Yang, Youjian</au><au>Tao, Wenju</au><au>Shi, Zhongning</au><au>Hu, Xianwei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Separation of Al3Zr Intermetallic Compound from Al–Zr Master Alloy Prepared by Molten Salt Electrolysis</atitle><jtitle>Russian Journal of Physical Chemistry A</jtitle><stitle>Russ. J. Phys. Chem</stitle><date>2023-10-01</date><risdate>2023</risdate><volume>97</volume><issue>10</issue><spage>2314</spage><epage>2320</epage><pages>2314-2320</pages><issn>0036-0244</issn><eissn>1531-863X</eissn><abstract>This paper focuses on preparation of Al–Zr master alloy and Al
3
Zr intermetallic compound. A method is proposed to obtain Al
3
Zr intermetallic compound from Al–Zr master alloy by leaching. The alloy was prepared by electrolysis in 2.4NaF–AlF
3
–5 wt % CaF
2
–5 wt % ZrO
2
cryolite-based electrolyte with the molten Al as cathode and the high purity graphite as anode at 980°C. Zirconium was deposited in the form of solid Al
3
Zr at the bottom of the cathode alloy, and the main phase compositions of the obtained Al-base alloy product were Al phase and Al
3
Zr phase. Then, cube-shaped Al
3
Zr intermetallic compound particles with an average size of 37.8 μm were obtained from the Al–Zr master alloy product by combining alkaline and acidic leaching.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0036024423100151</doi><tpages>7</tpages></addata></record> |
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| ispartof | Russian Journal of Physical Chemistry A, 2023-10, Vol.97 (10), p.2314-2320 |
| issn | 0036-0244 1531-863X |
| language | eng |
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| source | SpringerNature Journals |
| subjects | Aluminum base alloys Aluminum fluorides Cathodes Chemistry Chemistry and Materials Science Cryolite Electrochemistry. Generation and Storage of Energy from Renewable Sources Electrolysis Intermetallic compounds Leaching Master alloys Molten salts Phase composition Physical Chemistry Zirconium dioxide |
| title | Separation of Al3Zr Intermetallic Compound from Al–Zr Master Alloy Prepared by Molten Salt Electrolysis |
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