Controlled packing of chiral assembly scaffolds to promote chiral J-aggregation of carbocyanine dyes
Controlled aggregation of dyes is crucial to achieve their desired optical and electronic properties. Here, we report the induction of chiral J-aggregation of carbocyanine dyes by using lysine-derived amphiphile assemblies as scaffolds in water. The molecular structure of the amphiphiles affected th...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2023-10, Vol.59 (8), p.11979-11982 |
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| creator | Ryu, Naoya Yamamoto, Yusei Okazaki, Yutaka Hano, Nanami Iwamoto, Yuki Shirosaki, Tomohiro Nagaoka, Shoji Oda, Reiko Ihara, Hirotaka Takafuji, Makoto |
| description | Controlled aggregation of dyes is crucial to achieve their desired optical and electronic properties. Here, we report the induction of chiral J-aggregation of carbocyanine dyes by using lysine-derived amphiphile assemblies as scaffolds in water. The molecular structure of the amphiphiles affected the packing of the assembly. The tight packing with some flexibility promoted the formation of J-aggregates of the dyes with strong chiroptical properties.
Lysine-derived amphiphile assemblies with moderate tightness of packing served as scaffolds for the chiral J-aggregation of cyanine dyes in water. The induced J-aggregates showed high absorption and emission dissymmetry factors in the order of 10
−2
. |
| doi_str_mv | 10.1039/d3cc03394e |
| format | Article |
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Lysine-derived amphiphile assemblies with moderate tightness of packing served as scaffolds for the chiral J-aggregation of cyanine dyes in water. The induced J-aggregates showed high absorption and emission dissymmetry factors in the order of 10
−2
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Lysine-derived amphiphile assemblies with moderate tightness of packing served as scaffolds for the chiral J-aggregation of cyanine dyes in water. The induced J-aggregates showed high absorption and emission dissymmetry factors in the order of 10
−2
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Here, we report the induction of chiral J-aggregation of carbocyanine dyes by using lysine-derived amphiphile assemblies as scaffolds in water. The molecular structure of the amphiphiles affected the packing of the assembly. The tight packing with some flexibility promoted the formation of J-aggregates of the dyes with strong chiroptical properties.
Lysine-derived amphiphile assemblies with moderate tightness of packing served as scaffolds for the chiral J-aggregation of cyanine dyes in water. The induced J-aggregates showed high absorption and emission dissymmetry factors in the order of 10
−2
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Assembly Chemical Sciences Dyes Lysine Molecular structure Optical properties Scaffolds |
| title | Controlled packing of chiral assembly scaffolds to promote chiral J-aggregation of carbocyanine dyes |
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