Tin sulfide supported on cellulose nanocrystals-derived carbon as a green and effective catalyst for CO2 electroreduction to formate
This work reports a whole green two-step approach for the synthesis of novel catalysts for efficient CO 2 conversion. A conductive carbon support was firstly obtained via pyrolysis of cellulose nanocrystals (CNCs), and the carbon surface was successively decorated with tin sulfide (SnS) through a mi...
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| Veröffentlicht in: | Journal of materials science 2023-10, Vol.58 (37), p.14673-14685 |
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| creator | Garino, Nadia Monti, Nicolò Bartoli, Mattia Pirri, Candido F. Zeng, Juqin |
| description | This work reports a whole green two-step approach for the synthesis of novel catalysts for efficient CO
2
conversion. A conductive carbon support was firstly obtained via pyrolysis of cellulose nanocrystals (CNCs), and the carbon surface was successively decorated with tin sulfide (SnS) through a microwave-assisted hydrothermal process. The morphology and carbon structure were characterized by field emission scanning electron microscopy and Raman spectroscopy, and the presence of SnS decoration was confirmed by X-ray photoelectron spectroscopy and X-ray diffraction analyses. The SnS supported on CNC-derived carbon shows enhanced catalytic activity for the CO
2
conversion to formate (HCOO
−
). Good selectivity of 86% and high partial current density of 55 mA cm
−2
are reached at − 1.0 V vs. reversible hydrogen electrode in KHCO
3
electrolyte. Additionally, the mass activity of the composite catalyst achieves a value as high as 262.9 mA mg
Sn
−1
for HCOO
−
formation, demonstrating good utilization efficiency of Sn metal. In this work, the low-cost CNC-derived carbon is evidenced to be easily decorated with metal species and thus shows high versatility and tailorability. Incorporating metal species with conductive high-surface carbon supports represents an effective strategy to realize active and stable electrocatalysts, allowing efficient utilization of metals especially the raw and precious ones.
Graphical abstract |
| doi_str_mv | 10.1007/s10853-023-08925-2 |
| format | Article |
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2
conversion. A conductive carbon support was firstly obtained via pyrolysis of cellulose nanocrystals (CNCs), and the carbon surface was successively decorated with tin sulfide (SnS) through a microwave-assisted hydrothermal process. The morphology and carbon structure were characterized by field emission scanning electron microscopy and Raman spectroscopy, and the presence of SnS decoration was confirmed by X-ray photoelectron spectroscopy and X-ray diffraction analyses. The SnS supported on CNC-derived carbon shows enhanced catalytic activity for the CO
2
conversion to formate (HCOO
−
). Good selectivity of 86% and high partial current density of 55 mA cm
−2
are reached at − 1.0 V vs. reversible hydrogen electrode in KHCO
3
electrolyte. Additionally, the mass activity of the composite catalyst achieves a value as high as 262.9 mA mg
Sn
−1
for HCOO
−
formation, demonstrating good utilization efficiency of Sn metal. In this work, the low-cost CNC-derived carbon is evidenced to be easily decorated with metal species and thus shows high versatility and tailorability. Incorporating metal species with conductive high-surface carbon supports represents an effective strategy to realize active and stable electrocatalysts, allowing efficient utilization of metals especially the raw and precious ones.
Graphical abstract</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-023-08925-2</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Carbon ; Carbon dioxide ; Catalysts ; Catalytic activity ; Catalytic converters ; Cellulose ; Characterization and Evaluation of Materials ; Chemical Routes to Materials ; Chemical synthesis ; Chemistry and Materials Science ; Classical Mechanics ; Conversion ; Crystallography and Scattering Methods ; Decoration ; Electrocatalysts ; electrodes ; electrolytes ; electron microscopy ; Field emission microscopy ; formates ; hydrogen ; Materials Science ; microwave treatment ; Nanocrystals ; Photoelectrons ; Polymer Sciences ; Pyrolysis ; Raman spectroscopy ; Solid Mechanics ; Spectrum analysis ; sulfides ; Tin ; X ray photoelectron spectroscopy ; X-ray diffraction</subject><ispartof>Journal of materials science, 2023-10, Vol.58 (37), p.14673-14685</ispartof><rights>The Author(s) 2023</rights><rights>The Author(s) 2023. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c396t-24141501de93cb1f2398e704925406f70bcd8f703144bfeecba59f5677512a1d3</citedby><cites>FETCH-LOGICAL-c396t-24141501de93cb1f2398e704925406f70bcd8f703144bfeecba59f5677512a1d3</cites><orcidid>0000-0001-8885-020X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10853-023-08925-2$$EPDF$$P50$$Gspringer$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10853-023-08925-2$$EHTML$$P50$$Gspringer$$Hfree_for_read</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Garino, Nadia</creatorcontrib><creatorcontrib>Monti, Nicolò</creatorcontrib><creatorcontrib>Bartoli, Mattia</creatorcontrib><creatorcontrib>Pirri, Candido F.</creatorcontrib><creatorcontrib>Zeng, Juqin</creatorcontrib><title>Tin sulfide supported on cellulose nanocrystals-derived carbon as a green and effective catalyst for CO2 electroreduction to formate</title><title>Journal of materials science</title><addtitle>J Mater Sci</addtitle><description>This work reports a whole green two-step approach for the synthesis of novel catalysts for efficient CO
2
conversion. A conductive carbon support was firstly obtained via pyrolysis of cellulose nanocrystals (CNCs), and the carbon surface was successively decorated with tin sulfide (SnS) through a microwave-assisted hydrothermal process. The morphology and carbon structure were characterized by field emission scanning electron microscopy and Raman spectroscopy, and the presence of SnS decoration was confirmed by X-ray photoelectron spectroscopy and X-ray diffraction analyses. The SnS supported on CNC-derived carbon shows enhanced catalytic activity for the CO
2
conversion to formate (HCOO
−
). Good selectivity of 86% and high partial current density of 55 mA cm
−2
are reached at − 1.0 V vs. reversible hydrogen electrode in KHCO
3
electrolyte. Additionally, the mass activity of the composite catalyst achieves a value as high as 262.9 mA mg
Sn
−1
for HCOO
−
formation, demonstrating good utilization efficiency of Sn metal. In this work, the low-cost CNC-derived carbon is evidenced to be easily decorated with metal species and thus shows high versatility and tailorability. Incorporating metal species with conductive high-surface carbon supports represents an effective strategy to realize active and stable electrocatalysts, allowing efficient utilization of metals especially the raw and precious ones.
Graphical abstract</description><subject>Carbon</subject><subject>Carbon dioxide</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Catalytic converters</subject><subject>Cellulose</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical Routes to Materials</subject><subject>Chemical synthesis</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Conversion</subject><subject>Crystallography and Scattering Methods</subject><subject>Decoration</subject><subject>Electrocatalysts</subject><subject>electrodes</subject><subject>electrolytes</subject><subject>electron microscopy</subject><subject>Field emission microscopy</subject><subject>formates</subject><subject>hydrogen</subject><subject>Materials Science</subject><subject>microwave treatment</subject><subject>Nanocrystals</subject><subject>Photoelectrons</subject><subject>Polymer Sciences</subject><subject>Pyrolysis</subject><subject>Raman spectroscopy</subject><subject>Solid Mechanics</subject><subject>Spectrum analysis</subject><subject>sulfides</subject><subject>Tin</subject><subject>X ray photoelectron spectroscopy</subject><subject>X-ray diffraction</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><sourceid>BENPR</sourceid><recordid>eNp9kU1LxDAQhoMouK7-AU8BL16qk69te5TFLxC86Dmk6WTp0m3WpBW8-8OddQXBg5AwgXnel5m8jJ0LuBIA5XUWUBlVgKRb1dIU8oDNhClVoStQh2wGIGUh9UIcs5Oc1wBgSilm7POlG3ie-tC1SHW7jWnElseBe-z7qY8Z-eCG6NNHHl2fixZT906Ed6khymXu-Coh0nNoOYaAfiSA-oSThoeY-PJZcuypk2LCdiKCpGPc9TZuxFN2FMgbz37qnL3e3b4sH4qn5_vH5c1T4VW9GGl8oYUB0WKtfCOCVHWFJWjaV8MilND4tqKihNZNQPSNM3Uwi7I0QjrRqjm73PtuU3ybMI920-Xdnm7AOGWrhKFDP6kJvfiDruOUBprOyqqUujZGAFFyT_kUc04Y7DZ1G5c-rAC7C8bug7EUjP0OxkoSqb0oEzysMP1a_6P6Am_nkco</recordid><startdate>20231001</startdate><enddate>20231001</enddate><creator>Garino, Nadia</creator><creator>Monti, Nicolò</creator><creator>Bartoli, Mattia</creator><creator>Pirri, Candido F.</creator><creator>Zeng, Juqin</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>C6C</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PTHSS</scope><scope>7S9</scope><scope>L.6</scope><orcidid>https://orcid.org/0000-0001-8885-020X</orcidid></search><sort><creationdate>20231001</creationdate><title>Tin sulfide supported on cellulose nanocrystals-derived carbon as a green and effective catalyst for CO2 electroreduction to formate</title><author>Garino, Nadia ; Monti, Nicolò ; Bartoli, Mattia ; Pirri, Candido F. ; Zeng, Juqin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c396t-24141501de93cb1f2398e704925406f70bcd8f703144bfeecba59f5677512a1d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Carbon</topic><topic>Carbon dioxide</topic><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>Catalytic converters</topic><topic>Cellulose</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical Routes to Materials</topic><topic>Chemical synthesis</topic><topic>Chemistry and Materials Science</topic><topic>Classical Mechanics</topic><topic>Conversion</topic><topic>Crystallography and Scattering Methods</topic><topic>Decoration</topic><topic>Electrocatalysts</topic><topic>electrodes</topic><topic>electrolytes</topic><topic>electron microscopy</topic><topic>Field emission microscopy</topic><topic>formates</topic><topic>hydrogen</topic><topic>Materials Science</topic><topic>microwave treatment</topic><topic>Nanocrystals</topic><topic>Photoelectrons</topic><topic>Polymer Sciences</topic><topic>Pyrolysis</topic><topic>Raman spectroscopy</topic><topic>Solid Mechanics</topic><topic>Spectrum analysis</topic><topic>sulfides</topic><topic>Tin</topic><topic>X ray photoelectron spectroscopy</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Garino, Nadia</creatorcontrib><creatorcontrib>Monti, Nicolò</creatorcontrib><creatorcontrib>Bartoli, Mattia</creatorcontrib><creatorcontrib>Pirri, Candido F.</creatorcontrib><creatorcontrib>Zeng, Juqin</creatorcontrib><collection>Springer Nature OA Free Journals</collection><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Engineering Collection</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>Journal of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Garino, Nadia</au><au>Monti, Nicolò</au><au>Bartoli, Mattia</au><au>Pirri, Candido F.</au><au>Zeng, Juqin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Tin sulfide supported on cellulose nanocrystals-derived carbon as a green and effective catalyst for CO2 electroreduction to formate</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2023-10-01</date><risdate>2023</risdate><volume>58</volume><issue>37</issue><spage>14673</spage><epage>14685</epage><pages>14673-14685</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>This work reports a whole green two-step approach for the synthesis of novel catalysts for efficient CO
2
conversion. A conductive carbon support was firstly obtained via pyrolysis of cellulose nanocrystals (CNCs), and the carbon surface was successively decorated with tin sulfide (SnS) through a microwave-assisted hydrothermal process. The morphology and carbon structure were characterized by field emission scanning electron microscopy and Raman spectroscopy, and the presence of SnS decoration was confirmed by X-ray photoelectron spectroscopy and X-ray diffraction analyses. The SnS supported on CNC-derived carbon shows enhanced catalytic activity for the CO
2
conversion to formate (HCOO
−
). Good selectivity of 86% and high partial current density of 55 mA cm
−2
are reached at − 1.0 V vs. reversible hydrogen electrode in KHCO
3
electrolyte. Additionally, the mass activity of the composite catalyst achieves a value as high as 262.9 mA mg
Sn
−1
for HCOO
−
formation, demonstrating good utilization efficiency of Sn metal. In this work, the low-cost CNC-derived carbon is evidenced to be easily decorated with metal species and thus shows high versatility and tailorability. Incorporating metal species with conductive high-surface carbon supports represents an effective strategy to realize active and stable electrocatalysts, allowing efficient utilization of metals especially the raw and precious ones.
Graphical abstract</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10853-023-08925-2</doi><tpages>13</tpages><orcidid>https://orcid.org/0000-0001-8885-020X</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Carbon Carbon dioxide Catalysts Catalytic activity Catalytic converters Cellulose Characterization and Evaluation of Materials Chemical Routes to Materials Chemical synthesis Chemistry and Materials Science Classical Mechanics Conversion Crystallography and Scattering Methods Decoration Electrocatalysts electrodes electrolytes electron microscopy Field emission microscopy formates hydrogen Materials Science microwave treatment Nanocrystals Photoelectrons Polymer Sciences Pyrolysis Raman spectroscopy Solid Mechanics Spectrum analysis sulfides Tin X ray photoelectron spectroscopy X-ray diffraction |
| title | Tin sulfide supported on cellulose nanocrystals-derived carbon as a green and effective catalyst for CO2 electroreduction to formate |
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