Functionalizable and Recyclable Aliphatic Polycarbonates Derived from Biomass Feedstocks and CO2
T wo bio-based seven-membered cyclic carbonate monomers M1 and M2 were synthesized in three steps from myrcene, which could produce polycarbonates via ring-opening polymerization using metal or organic catalysts. The functionalizable olefin moieties in resulting polycarbonates have driven post-polym...
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| Veröffentlicht in: | Chemical research in Chinese universities 2023-10, Vol.39 (5), p.809-815 |
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| container_title | Chemical research in Chinese universities |
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| creator | Wu, Yanchen Fan, Huazhong Shan, Siyi Wang, Siqi Cai, Zhongzheng Zhu, Jian-Bo |
| description | T
wo bio-based seven-membered cyclic carbonate monomers
M1
and
M2
were synthesized in three steps from myrcene, which could produce polycarbonates
via
ring-opening polymerization using metal or organic catalysts. The functionalizable olefin moieties in resulting polycarbonates have driven post-polymerization modifications
via
radical cross-linking and hydrogenation, enabling the resulting polymers with tunable thermal properties. More importantly, the chemical recycling of P(
M
)s was achieved through “monomer → polymer ⇄ dimer”, which presented a platform for the synthesis of chemically recyclable biobased polycarbonates. |
| doi_str_mv | 10.1007/s40242-023-3165-3 |
| format | Article |
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wo bio-based seven-membered cyclic carbonate monomers
M1
and
M2
were synthesized in three steps from myrcene, which could produce polycarbonates
via
ring-opening polymerization using metal or organic catalysts. The functionalizable olefin moieties in resulting polycarbonates have driven post-polymerization modifications
via
radical cross-linking and hydrogenation, enabling the resulting polymers with tunable thermal properties. More importantly, the chemical recycling of P(
M
)s was achieved through “monomer → polymer ⇄ dimer”, which presented a platform for the synthesis of chemically recyclable biobased polycarbonates.</description><identifier>ISSN: 1005-9040</identifier><identifier>EISSN: 2210-3171</identifier><identifier>DOI: 10.1007/s40242-023-3165-3</identifier><language>eng</language><publisher>Changchun: Jilin University and The Editorial Department of Chemical Research in Chinese Universities</publisher><subject>Analytical Chemistry ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Crosslinking ; Inorganic Chemistry ; Monomers ; Organic Chemistry ; Physical Chemistry ; Polycarbonate resins ; Ring opening polymerization ; Thermodynamic properties</subject><ispartof>Chemical research in Chinese universities, 2023-10, Vol.39 (5), p.809-815</ispartof><rights>Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH 2023</rights><rights>Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH 2023.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-76e2ab07ed1bb58f7b637c0f2dcd73385749052f62912a3731b9c9eefeeb72123</citedby><cites>FETCH-LOGICAL-c316t-76e2ab07ed1bb58f7b637c0f2dcd73385749052f62912a3731b9c9eefeeb72123</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s40242-023-3165-3$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s40242-023-3165-3$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Wu, Yanchen</creatorcontrib><creatorcontrib>Fan, Huazhong</creatorcontrib><creatorcontrib>Shan, Siyi</creatorcontrib><creatorcontrib>Wang, Siqi</creatorcontrib><creatorcontrib>Cai, Zhongzheng</creatorcontrib><creatorcontrib>Zhu, Jian-Bo</creatorcontrib><title>Functionalizable and Recyclable Aliphatic Polycarbonates Derived from Biomass Feedstocks and CO2</title><title>Chemical research in Chinese universities</title><addtitle>Chem. Res. Chin. Univ</addtitle><description>T
wo bio-based seven-membered cyclic carbonate monomers
M1
and
M2
were synthesized in three steps from myrcene, which could produce polycarbonates
via
ring-opening polymerization using metal or organic catalysts. The functionalizable olefin moieties in resulting polycarbonates have driven post-polymerization modifications
via
radical cross-linking and hydrogenation, enabling the resulting polymers with tunable thermal properties. More importantly, the chemical recycling of P(
M
)s was achieved through “monomer → polymer ⇄ dimer”, which presented a platform for the synthesis of chemically recyclable biobased polycarbonates.</description><subject>Analytical Chemistry</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Crosslinking</subject><subject>Inorganic Chemistry</subject><subject>Monomers</subject><subject>Organic Chemistry</subject><subject>Physical Chemistry</subject><subject>Polycarbonate resins</subject><subject>Ring opening polymerization</subject><subject>Thermodynamic properties</subject><issn>1005-9040</issn><issn>2210-3171</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1kNFKwzAUhoMoOKcP4F3A62py0jbr5ZxWhcFE9Dom6al2ds1MOmE-vdkqeOXV4cD3_5zzEXLO2SVnTF6FlEEKCQORCJ5niTggIwDO4ib5IRlFKEsKlrJjchLCkjFR5Hk6Iq_lprN94zrdNt_atEh1V9EntFvb7tdp26zfdd9Y-ujardXeRLbHQG_QN19Y0dq7Fb1u3EqHQEvEKvTOfoR9z2wBp-So1m3As985Ji_l7fPsPpkv7h5m03li4719InMEbZjEihuTTWppciEtq6GylRRiksm0YBnUORQctJCCm8IWiDWikcBBjMnF0Lv27nODoVdLt_HxraBgIgHSjGciUnygrHcheKzV2jcr7beKM7UTqQaRKopUO5Fql4EhEyLbvaH_a_4_9AMd2HXL</recordid><startdate>20231001</startdate><enddate>20231001</enddate><creator>Wu, Yanchen</creator><creator>Fan, Huazhong</creator><creator>Shan, Siyi</creator><creator>Wang, Siqi</creator><creator>Cai, Zhongzheng</creator><creator>Zhu, Jian-Bo</creator><general>Jilin University and The Editorial Department of Chemical Research in Chinese Universities</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20231001</creationdate><title>Functionalizable and Recyclable Aliphatic Polycarbonates Derived from Biomass Feedstocks and CO2</title><author>Wu, Yanchen ; Fan, Huazhong ; Shan, Siyi ; Wang, Siqi ; Cai, Zhongzheng ; Zhu, Jian-Bo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-76e2ab07ed1bb58f7b637c0f2dcd73385749052f62912a3731b9c9eefeeb72123</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Analytical Chemistry</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Crosslinking</topic><topic>Inorganic Chemistry</topic><topic>Monomers</topic><topic>Organic Chemistry</topic><topic>Physical Chemistry</topic><topic>Polycarbonate resins</topic><topic>Ring opening polymerization</topic><topic>Thermodynamic properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wu, Yanchen</creatorcontrib><creatorcontrib>Fan, Huazhong</creatorcontrib><creatorcontrib>Shan, Siyi</creatorcontrib><creatorcontrib>Wang, Siqi</creatorcontrib><creatorcontrib>Cai, Zhongzheng</creatorcontrib><creatorcontrib>Zhu, Jian-Bo</creatorcontrib><collection>CrossRef</collection><jtitle>Chemical research in Chinese universities</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wu, Yanchen</au><au>Fan, Huazhong</au><au>Shan, Siyi</au><au>Wang, Siqi</au><au>Cai, Zhongzheng</au><au>Zhu, Jian-Bo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Functionalizable and Recyclable Aliphatic Polycarbonates Derived from Biomass Feedstocks and CO2</atitle><jtitle>Chemical research in Chinese universities</jtitle><stitle>Chem. Res. Chin. Univ</stitle><date>2023-10-01</date><risdate>2023</risdate><volume>39</volume><issue>5</issue><spage>809</spage><epage>815</epage><pages>809-815</pages><issn>1005-9040</issn><eissn>2210-3171</eissn><abstract>T
wo bio-based seven-membered cyclic carbonate monomers
M1
and
M2
were synthesized in three steps from myrcene, which could produce polycarbonates
via
ring-opening polymerization using metal or organic catalysts. The functionalizable olefin moieties in resulting polycarbonates have driven post-polymerization modifications
via
radical cross-linking and hydrogenation, enabling the resulting polymers with tunable thermal properties. More importantly, the chemical recycling of P(
M
)s was achieved through “monomer → polymer ⇄ dimer”, which presented a platform for the synthesis of chemically recyclable biobased polycarbonates.</abstract><cop>Changchun</cop><pub>Jilin University and The Editorial Department of Chemical Research in Chinese Universities</pub><doi>10.1007/s40242-023-3165-3</doi><tpages>7</tpages></addata></record> |
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| issn | 1005-9040 2210-3171 |
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| source | SpringerLink Journals |
| subjects | Analytical Chemistry Chemistry Chemistry and Materials Science Chemistry/Food Science Crosslinking Inorganic Chemistry Monomers Organic Chemistry Physical Chemistry Polycarbonate resins Ring opening polymerization Thermodynamic properties |
| title | Functionalizable and Recyclable Aliphatic Polycarbonates Derived from Biomass Feedstocks and CO2 |
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