$Phosphine/thiolate-containing dinitrosyl cobalt complexes (DNCCs): synthesis, characterization, interconversion, X-ray diffraction identification and NO release$

Phosphine/thiolate-containing dinitrosyl cobalt complexes (DNCCs): synthesis, characterization, interconversion, X-ray diffraction identification and NO release

Cobalt carbonyl/nitrosyl complexes, (PPh 3 )(CO) 2 Co(NO) ( 1 ) and (PPh 3 ) 2 (CO)Co(NO) ( 2 ), were obtained by reacting (CO) 3 Co(NO) with one equiv. and two equiv. of PPh 3 , respectively. The process of isoelectronic replacement of CO with NO + resulted in the formation of a cationic complex {C...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2023-10, Vol.52 (38), p.13724-13731
Hauptverfasser:	Chang, Wen-Chieh, Du, Wan-Tin, Lin, Yi-Xuan, Jhang, Ruei-Lin, Hsieh, Chung-Hung
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbonyls Cobalt compounds Ferric chloride Infrared spectroscopy Iron Ligands Nitric oxide Phosphines Single crystals
Online-Zugang:	Volltext
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