Correlation between heat of fusion and change of volume at melting by volume-dependent heat capacity

Heat capacity is a key subject in condensed matter physics due to its scientific and technological importance. Previous studies show that the change of heat d Q is dependent on both of the macroscopic physical variables in general solids: d T and dln V . In this paper, we analyze the thermal paramet...

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Veröffentlicht in:Journal of thermal analysis and calorimetry 2023-10, Vol.148 (20), p.11167-11172
Hauptverfasser: Tang, M. B., Liu, X. C., Zhang, M. H., Pan, X. H.
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container_issue 20
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creator Tang, M. B.
Liu, X. C.
Zhang, M. H.
Pan, X. H.
description Heat capacity is a key subject in condensed matter physics due to its scientific and technological importance. Previous studies show that the change of heat d Q is dependent on both of the macroscopic physical variables in general solids: d T and dln V . In this paper, we analyze the thermal parameters during the process of melting in a series of reference materials. The behavior of the heat of fusion and the volume change at melting in the reference materials can be explained by the new heat capacity model in solids. The change of volume at melting can be quantitatively gotten by the heat of fusion. The results are helpful to further understand the volume-dependent heat capacity in the model and the melting process in general materials.
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subjects Analytical Chemistry
Chemistry
Chemistry and Materials Science
Condensed matter physics
Heat of fusion
Inorganic Chemistry
Measurement Science and Instrumentation
Melting
Physical Chemistry
Polymer Sciences
Reference materials
Specific heat
Thermodynamic properties
title Correlation between heat of fusion and change of volume at melting by volume-dependent heat capacity
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