Synthesis, thermal and barrier properties of biodegradable aliphatic polycarbonates with different chain lengths
Aliphatic polycarbonates (APCs) have become an essential packaging material because of their renewability, biodegradability, and biocompatibility. In this study, a series of high molecular weights APCs have been successfully synthesized using dimethyl carbonate (DMC) and different lengths of aliphat...
Gespeichert in:
| Veröffentlicht in: | Journal of thermal analysis and calorimetry 2023-10, Vol.148 (19), p.10163-10174 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 10174 |
|---|---|
| container_issue | 19 |
| container_start_page | 10163 |
| container_title | Journal of thermal analysis and calorimetry |
| container_volume | 148 |
| creator | Liu, Lipeng Lu, Ying Xia, Mingze Wang, Bo Cheng, Yi Wei, Zhiyong |
| description | Aliphatic polycarbonates (APCs) have become an essential packaging material because of their renewability, biodegradability, and biocompatibility. In this study, a series of high molecular weights APCs have been successfully synthesized using dimethyl carbonate (DMC) and different lengths of aliphatic diols with even carbon (n
-CH2
= 4–12) via melt polymerization. Thermal properties, isothermal crystallization behavior, crystal structure, and scale of microstructure of APCs indicated that the flexibility and crystallization of molecular chains gradually increased with the increasing number of methylene groups of repeating units. However, due to the rigidity of ester group was higher than methylene group, and crystallization could increase the rigidity of chain segments, yielding strength and Young’s modulus of APCs decreased first and then gradually increased with the increasing number of methylene groups in the repeating units. Furthermore, the scale of microstructure indicated that Brill transition increased the distance between intermolecular chains. Therefore, although the
trans-gauche
coexistence chain conformation simultaneously decreased the rigidity and crystallization of chain segments, barrier property of poly(octamethylene carbonate) with Brill transition was similar to long-chain APCs because of the lengthened diffusion path. The analytical mechanism of structure-performance relationship from the viewpoint of molecular interactions and chain structure will provide an entirely new thought for developing new barrier materials. |
| doi_str_mv | 10.1007/s10973-023-12352-5 |
| format | Article |
| fullrecord | <record><control><sourceid>gale_proqu</sourceid><recordid>TN_cdi_proquest_journals_2870724708</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A767318936</galeid><sourcerecordid>A767318936</sourcerecordid><originalsourceid>FETCH-LOGICAL-c343t-6b828ede8785fc7b79b4bec8a75f324426b61131bf1996971ce9e22dcad376cb3</originalsourceid><addsrcrecordid>eNp9kU1rFTEUhgdRsFb_gKuAK8Gp-ZjJx7IUq4WCYHUdkszJTMrcZExy0fvvjU6hdCNZnMPheZIc3q57S_AFwVh8LAQrwXpMWU8oG2k_PuvOyChlTxXlz1vPWs_JiF92r0q5xxgrhclZt92dYl2ghPIBtZoPZkUmTsianANktOW0Qa4BCkoe2ZAmmLOZjF0BmTVsi6nBoS2tJ2eyTdHURv4KdUFT8B4yxIrcYkJEK8S5LuV198KbtcCbh3re_bj-9P3qS3_79fPN1eVt79jAas-tpBImkEKO3gkrlB0sOGnE6BkdBsotJ4QR64lSXAniQAGlkzMTE9xZdt692-9tG_w8Qqn6Ph1zbE9qKgUWdBBYNupip2azgg7Rp5qNa2eCQ3Apgg9tfim4YEQqxpvw_onQmAq_62yOpeibu29PWbqzLqdSMni95XAw-aQJ1n9j03tsusWm_8WmxyaxXSoNjjPkx3__x_oDi6mb0w</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2870724708</pqid></control><display><type>article</type><title>Synthesis, thermal and barrier properties of biodegradable aliphatic polycarbonates with different chain lengths</title><source>SpringerLink Journals - AutoHoldings</source><creator>Liu, Lipeng ; Lu, Ying ; Xia, Mingze ; Wang, Bo ; Cheng, Yi ; Wei, Zhiyong</creator><creatorcontrib>Liu, Lipeng ; Lu, Ying ; Xia, Mingze ; Wang, Bo ; Cheng, Yi ; Wei, Zhiyong</creatorcontrib><description>Aliphatic polycarbonates (APCs) have become an essential packaging material because of their renewability, biodegradability, and biocompatibility. In this study, a series of high molecular weights APCs have been successfully synthesized using dimethyl carbonate (DMC) and different lengths of aliphatic diols with even carbon (n
-CH2
= 4–12) via melt polymerization. Thermal properties, isothermal crystallization behavior, crystal structure, and scale of microstructure of APCs indicated that the flexibility and crystallization of molecular chains gradually increased with the increasing number of methylene groups of repeating units. However, due to the rigidity of ester group was higher than methylene group, and crystallization could increase the rigidity of chain segments, yielding strength and Young’s modulus of APCs decreased first and then gradually increased with the increasing number of methylene groups in the repeating units. Furthermore, the scale of microstructure indicated that Brill transition increased the distance between intermolecular chains. Therefore, although the
trans-gauche
coexistence chain conformation simultaneously decreased the rigidity and crystallization of chain segments, barrier property of poly(octamethylene carbonate) with Brill transition was similar to long-chain APCs because of the lengthened diffusion path. The analytical mechanism of structure-performance relationship from the viewpoint of molecular interactions and chain structure will provide an entirely new thought for developing new barrier materials.</description><identifier>ISSN: 1388-6150</identifier><identifier>EISSN: 1588-2926</identifier><identifier>DOI: 10.1007/s10973-023-12352-5</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Aliphatic compounds ; Analysis ; Analytical Chemistry ; Biocompatibility ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Crystal structure ; Crystallization ; Crystals ; Diols ; Inorganic Chemistry ; Measurement Science and Instrumentation ; Methylene ; Microstructure ; Modulus of elasticity ; Molecular chains ; Molecular conformation ; Molecular interactions ; Molecular structure ; Physical Chemistry ; Polycarbonate resins ; Polycarbonates ; Polymer Sciences ; Polymerization ; Rigidity ; Segments ; Structure ; Thermal properties ; Thermodynamic properties</subject><ispartof>Journal of thermal analysis and calorimetry, 2023-10, Vol.148 (19), p.10163-10174</ispartof><rights>Akadémiai Kiadó, Budapest, Hungary 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>COPYRIGHT 2023 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c343t-6b828ede8785fc7b79b4bec8a75f324426b61131bf1996971ce9e22dcad376cb3</cites><orcidid>0000-0002-5477-9502</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10973-023-12352-5$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10973-023-12352-5$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Liu, Lipeng</creatorcontrib><creatorcontrib>Lu, Ying</creatorcontrib><creatorcontrib>Xia, Mingze</creatorcontrib><creatorcontrib>Wang, Bo</creatorcontrib><creatorcontrib>Cheng, Yi</creatorcontrib><creatorcontrib>Wei, Zhiyong</creatorcontrib><title>Synthesis, thermal and barrier properties of biodegradable aliphatic polycarbonates with different chain lengths</title><title>Journal of thermal analysis and calorimetry</title><addtitle>J Therm Anal Calorim</addtitle><description>Aliphatic polycarbonates (APCs) have become an essential packaging material because of their renewability, biodegradability, and biocompatibility. In this study, a series of high molecular weights APCs have been successfully synthesized using dimethyl carbonate (DMC) and different lengths of aliphatic diols with even carbon (n
-CH2
= 4–12) via melt polymerization. Thermal properties, isothermal crystallization behavior, crystal structure, and scale of microstructure of APCs indicated that the flexibility and crystallization of molecular chains gradually increased with the increasing number of methylene groups of repeating units. However, due to the rigidity of ester group was higher than methylene group, and crystallization could increase the rigidity of chain segments, yielding strength and Young’s modulus of APCs decreased first and then gradually increased with the increasing number of methylene groups in the repeating units. Furthermore, the scale of microstructure indicated that Brill transition increased the distance between intermolecular chains. Therefore, although the
trans-gauche
coexistence chain conformation simultaneously decreased the rigidity and crystallization of chain segments, barrier property of poly(octamethylene carbonate) with Brill transition was similar to long-chain APCs because of the lengthened diffusion path. The analytical mechanism of structure-performance relationship from the viewpoint of molecular interactions and chain structure will provide an entirely new thought for developing new barrier materials.</description><subject>Aliphatic compounds</subject><subject>Analysis</subject><subject>Analytical Chemistry</subject><subject>Biocompatibility</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crystal structure</subject><subject>Crystallization</subject><subject>Crystals</subject><subject>Diols</subject><subject>Inorganic Chemistry</subject><subject>Measurement Science and Instrumentation</subject><subject>Methylene</subject><subject>Microstructure</subject><subject>Modulus of elasticity</subject><subject>Molecular chains</subject><subject>Molecular conformation</subject><subject>Molecular interactions</subject><subject>Molecular structure</subject><subject>Physical Chemistry</subject><subject>Polycarbonate resins</subject><subject>Polycarbonates</subject><subject>Polymer Sciences</subject><subject>Polymerization</subject><subject>Rigidity</subject><subject>Segments</subject><subject>Structure</subject><subject>Thermal properties</subject><subject>Thermodynamic properties</subject><issn>1388-6150</issn><issn>1588-2926</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9kU1rFTEUhgdRsFb_gKuAK8Gp-ZjJx7IUq4WCYHUdkszJTMrcZExy0fvvjU6hdCNZnMPheZIc3q57S_AFwVh8LAQrwXpMWU8oG2k_PuvOyChlTxXlz1vPWs_JiF92r0q5xxgrhclZt92dYl2ghPIBtZoPZkUmTsianANktOW0Qa4BCkoe2ZAmmLOZjF0BmTVsi6nBoS2tJ2eyTdHURv4KdUFT8B4yxIrcYkJEK8S5LuV198KbtcCbh3re_bj-9P3qS3_79fPN1eVt79jAas-tpBImkEKO3gkrlB0sOGnE6BkdBsotJ4QR64lSXAniQAGlkzMTE9xZdt692-9tG_w8Qqn6Ph1zbE9qKgUWdBBYNupip2azgg7Rp5qNa2eCQ3Apgg9tfim4YEQqxpvw_onQmAq_62yOpeibu29PWbqzLqdSMni95XAw-aQJ1n9j03tsusWm_8WmxyaxXSoNjjPkx3__x_oDi6mb0w</recordid><startdate>20231001</startdate><enddate>20231001</enddate><creator>Liu, Lipeng</creator><creator>Lu, Ying</creator><creator>Xia, Mingze</creator><creator>Wang, Bo</creator><creator>Cheng, Yi</creator><creator>Wei, Zhiyong</creator><general>Springer International Publishing</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><orcidid>https://orcid.org/0000-0002-5477-9502</orcidid></search><sort><creationdate>20231001</creationdate><title>Synthesis, thermal and barrier properties of biodegradable aliphatic polycarbonates with different chain lengths</title><author>Liu, Lipeng ; Lu, Ying ; Xia, Mingze ; Wang, Bo ; Cheng, Yi ; Wei, Zhiyong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c343t-6b828ede8785fc7b79b4bec8a75f324426b61131bf1996971ce9e22dcad376cb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Aliphatic compounds</topic><topic>Analysis</topic><topic>Analytical Chemistry</topic><topic>Biocompatibility</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crystal structure</topic><topic>Crystallization</topic><topic>Crystals</topic><topic>Diols</topic><topic>Inorganic Chemistry</topic><topic>Measurement Science and Instrumentation</topic><topic>Methylene</topic><topic>Microstructure</topic><topic>Modulus of elasticity</topic><topic>Molecular chains</topic><topic>Molecular conformation</topic><topic>Molecular interactions</topic><topic>Molecular structure</topic><topic>Physical Chemistry</topic><topic>Polycarbonate resins</topic><topic>Polycarbonates</topic><topic>Polymer Sciences</topic><topic>Polymerization</topic><topic>Rigidity</topic><topic>Segments</topic><topic>Structure</topic><topic>Thermal properties</topic><topic>Thermodynamic properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Lipeng</creatorcontrib><creatorcontrib>Lu, Ying</creatorcontrib><creatorcontrib>Xia, Mingze</creatorcontrib><creatorcontrib>Wang, Bo</creatorcontrib><creatorcontrib>Cheng, Yi</creatorcontrib><creatorcontrib>Wei, Zhiyong</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><jtitle>Journal of thermal analysis and calorimetry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Lipeng</au><au>Lu, Ying</au><au>Xia, Mingze</au><au>Wang, Bo</au><au>Cheng, Yi</au><au>Wei, Zhiyong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, thermal and barrier properties of biodegradable aliphatic polycarbonates with different chain lengths</atitle><jtitle>Journal of thermal analysis and calorimetry</jtitle><stitle>J Therm Anal Calorim</stitle><date>2023-10-01</date><risdate>2023</risdate><volume>148</volume><issue>19</issue><spage>10163</spage><epage>10174</epage><pages>10163-10174</pages><issn>1388-6150</issn><eissn>1588-2926</eissn><abstract>Aliphatic polycarbonates (APCs) have become an essential packaging material because of their renewability, biodegradability, and biocompatibility. In this study, a series of high molecular weights APCs have been successfully synthesized using dimethyl carbonate (DMC) and different lengths of aliphatic diols with even carbon (n
-CH2
= 4–12) via melt polymerization. Thermal properties, isothermal crystallization behavior, crystal structure, and scale of microstructure of APCs indicated that the flexibility and crystallization of molecular chains gradually increased with the increasing number of methylene groups of repeating units. However, due to the rigidity of ester group was higher than methylene group, and crystallization could increase the rigidity of chain segments, yielding strength and Young’s modulus of APCs decreased first and then gradually increased with the increasing number of methylene groups in the repeating units. Furthermore, the scale of microstructure indicated that Brill transition increased the distance between intermolecular chains. Therefore, although the
trans-gauche
coexistence chain conformation simultaneously decreased the rigidity and crystallization of chain segments, barrier property of poly(octamethylene carbonate) with Brill transition was similar to long-chain APCs because of the lengthened diffusion path. The analytical mechanism of structure-performance relationship from the viewpoint of molecular interactions and chain structure will provide an entirely new thought for developing new barrier materials.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s10973-023-12352-5</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0002-5477-9502</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1388-6150 |
| ispartof | Journal of thermal analysis and calorimetry, 2023-10, Vol.148 (19), p.10163-10174 |
| issn | 1388-6150 1588-2926 |
| language | eng |
| recordid | cdi_proquest_journals_2870724708 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Aliphatic compounds Analysis Analytical Chemistry Biocompatibility Chemical synthesis Chemistry Chemistry and Materials Science Crystal structure Crystallization Crystals Diols Inorganic Chemistry Measurement Science and Instrumentation Methylene Microstructure Modulus of elasticity Molecular chains Molecular conformation Molecular interactions Molecular structure Physical Chemistry Polycarbonate resins Polycarbonates Polymer Sciences Polymerization Rigidity Segments Structure Thermal properties Thermodynamic properties |
| title | Synthesis, thermal and barrier properties of biodegradable aliphatic polycarbonates with different chain lengths |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-04T16%3A31%3A21IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale_proqu&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis,%20thermal%20and%20barrier%20properties%20of%20biodegradable%20aliphatic%20polycarbonates%20with%20different%20chain%20lengths&rft.jtitle=Journal%20of%20thermal%20analysis%20and%20calorimetry&rft.au=Liu,%20Lipeng&rft.date=2023-10-01&rft.volume=148&rft.issue=19&rft.spage=10163&rft.epage=10174&rft.pages=10163-10174&rft.issn=1388-6150&rft.eissn=1588-2926&rft_id=info:doi/10.1007/s10973-023-12352-5&rft_dat=%3Cgale_proqu%3EA767318936%3C/gale_proqu%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2870724708&rft_id=info:pmid/&rft_galeid=A767318936&rfr_iscdi=true |