Electrodeposition of Silver(I) Selenide from Aqueous Solutions of Thiocyanates
Silver(I) selenide that exhibits pronounced thermoelectric properties is electrodeposited from aqueous solutions containing thiocyanate complexes of silver(I) and Se(IV) compounds at рН 4.7. Ag 2 Se is formed at the cathodic potential more negative than –0.9 V (SHE). The coatings are characterized b...
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| Veröffentlicht in: | Russian journal of electrochemistry 2023-09, Vol.59 (9), p.683-689 |
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| container_end_page | 689 |
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| container_issue | 9 |
| container_start_page | 683 |
| container_title | Russian journal of electrochemistry |
| container_volume | 59 |
| creator | Kuznetsov, V. V. Tyagnerev, E. A. Kapustin, A. V. Zhukov, V. Yu Filatova, E. A. |
| description | Silver(I) selenide that exhibits pronounced thermoelectric properties is electrodeposited from aqueous solutions containing thiocyanate complexes of silver(I) and Se(IV) compounds at рН 4.7. Ag
2
Se is formed at the cathodic potential more negative than –0.9 V (SHE). The coatings are characterized by the methods of scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and atomic-force microscopy (AFM). The stoichiometry of the cathodic deposit is close to Ag
2
Se. XRD studies demonstrated the formation of the orthorhombic modification of silver(I) selenide under electrodeposition conditions. The cathodic deposits have the columnar nanostructure. |
| doi_str_mv | 10.1134/S1023193523090094 |
| format | Article |
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2
Se is formed at the cathodic potential more negative than –0.9 V (SHE). The coatings are characterized by the methods of scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and atomic-force microscopy (AFM). The stoichiometry of the cathodic deposit is close to Ag
2
Se. XRD studies demonstrated the formation of the orthorhombic modification of silver(I) selenide under electrodeposition conditions. The cathodic deposits have the columnar nanostructure.</description><identifier>ISSN: 1023-1935</identifier><identifier>EISSN: 1608-3342</identifier><identifier>DOI: 10.1134/S1023193523090094</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Aqueous solutions ; Cathodic coating (process) ; Chemistry ; Chemistry and Materials Science ; Electrochemistry ; Electrodeposition ; Microscopy ; Photoelectrons ; Physical Chemistry ; Selenium ; Stoichiometry ; Thiocyanates ; X ray photoelectron spectroscopy ; X-ray diffraction</subject><ispartof>Russian journal of electrochemistry, 2023-09, Vol.59 (9), p.683-689</ispartof><rights>Pleiades Publishing, Ltd. 2023. ISSN 1023-1935, Russian Journal of Electrochemistry, 2023, Vol. 59, No. 9, pp. 683–689. © Pleiades Publishing, Ltd., 2023. Russian Text © The Author(s), 2023, published in Elektrokhimiya, 2023, Vol. 59, No. 9, pp. 536–542.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-bfab72e576bd9c39116721197bd0584aa997fc536505f1b450bf6761c82617c33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1023193523090094$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1023193523090094$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Kuznetsov, V. V.</creatorcontrib><creatorcontrib>Tyagnerev, E. A.</creatorcontrib><creatorcontrib>Kapustin, A. V.</creatorcontrib><creatorcontrib>Zhukov, V. Yu</creatorcontrib><creatorcontrib>Filatova, E. A.</creatorcontrib><title>Electrodeposition of Silver(I) Selenide from Aqueous Solutions of Thiocyanates</title><title>Russian journal of electrochemistry</title><addtitle>Russ J Electrochem</addtitle><description>Silver(I) selenide that exhibits pronounced thermoelectric properties is electrodeposited from aqueous solutions containing thiocyanate complexes of silver(I) and Se(IV) compounds at рН 4.7. Ag
2
Se is formed at the cathodic potential more negative than –0.9 V (SHE). The coatings are characterized by the methods of scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and atomic-force microscopy (AFM). The stoichiometry of the cathodic deposit is close to Ag
2
Se. XRD studies demonstrated the formation of the orthorhombic modification of silver(I) selenide under electrodeposition conditions. The cathodic deposits have the columnar nanostructure.</description><subject>Aqueous solutions</subject><subject>Cathodic coating (process)</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Electrochemistry</subject><subject>Electrodeposition</subject><subject>Microscopy</subject><subject>Photoelectrons</subject><subject>Physical Chemistry</subject><subject>Selenium</subject><subject>Stoichiometry</subject><subject>Thiocyanates</subject><subject>X ray photoelectron spectroscopy</subject><subject>X-ray diffraction</subject><issn>1023-1935</issn><issn>1608-3342</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1kEFLxDAQhYMouK7-AG8FL3qoZpImaY7LsurCooeu55KmiXbpNjVphf33pqzgQTzNwPvem-EhdA34HoBmDwVgQkFSRiiWGMvsBM2A4zylNCOncY9yOunn6CKEHcY4FyBn6GXVGj14V5vehWZoXJc4mxRN-2X87fouKUxruqY2ifVunyw-R-PGkBSuHSc2TPD2o3H6oDo1mHCJzqxqg7n6mXP09rjaLp_TzevTernYpJrwfEgrqypBDBO8qqWmEoALAiBFVWOWZ0pJKaxmlDPMLFQZw5XlgoPOCQehKZ2jm2Nu7138KQzlzo2-iydLkgtMGQgKkYIjpb0LwRtb9r7ZK38oAZdTbeWf2qKHHD0hst278b_J_5u-ARxgbYA</recordid><startdate>20230901</startdate><enddate>20230901</enddate><creator>Kuznetsov, V. V.</creator><creator>Tyagnerev, E. A.</creator><creator>Kapustin, A. V.</creator><creator>Zhukov, V. Yu</creator><creator>Filatova, E. A.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20230901</creationdate><title>Electrodeposition of Silver(I) Selenide from Aqueous Solutions of Thiocyanates</title><author>Kuznetsov, V. V. ; Tyagnerev, E. A. ; Kapustin, A. V. ; Zhukov, V. Yu ; Filatova, E. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-bfab72e576bd9c39116721197bd0584aa997fc536505f1b450bf6761c82617c33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Aqueous solutions</topic><topic>Cathodic coating (process)</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Electrochemistry</topic><topic>Electrodeposition</topic><topic>Microscopy</topic><topic>Photoelectrons</topic><topic>Physical Chemistry</topic><topic>Selenium</topic><topic>Stoichiometry</topic><topic>Thiocyanates</topic><topic>X ray photoelectron spectroscopy</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kuznetsov, V. V.</creatorcontrib><creatorcontrib>Tyagnerev, E. A.</creatorcontrib><creatorcontrib>Kapustin, A. V.</creatorcontrib><creatorcontrib>Zhukov, V. Yu</creatorcontrib><creatorcontrib>Filatova, E. A.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kuznetsov, V. V.</au><au>Tyagnerev, E. A.</au><au>Kapustin, A. V.</au><au>Zhukov, V. Yu</au><au>Filatova, E. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrodeposition of Silver(I) Selenide from Aqueous Solutions of Thiocyanates</atitle><jtitle>Russian journal of electrochemistry</jtitle><stitle>Russ J Electrochem</stitle><date>2023-09-01</date><risdate>2023</risdate><volume>59</volume><issue>9</issue><spage>683</spage><epage>689</epage><pages>683-689</pages><issn>1023-1935</issn><eissn>1608-3342</eissn><abstract>Silver(I) selenide that exhibits pronounced thermoelectric properties is electrodeposited from aqueous solutions containing thiocyanate complexes of silver(I) and Se(IV) compounds at рН 4.7. Ag
2
Se is formed at the cathodic potential more negative than –0.9 V (SHE). The coatings are characterized by the methods of scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and atomic-force microscopy (AFM). The stoichiometry of the cathodic deposit is close to Ag
2
Se. XRD studies demonstrated the formation of the orthorhombic modification of silver(I) selenide under electrodeposition conditions. The cathodic deposits have the columnar nanostructure.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1023193523090094</doi><tpages>7</tpages></addata></record> |
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| subjects | Aqueous solutions Cathodic coating (process) Chemistry Chemistry and Materials Science Electrochemistry Electrodeposition Microscopy Photoelectrons Physical Chemistry Selenium Stoichiometry Thiocyanates X ray photoelectron spectroscopy X-ray diffraction |
| title | Electrodeposition of Silver(I) Selenide from Aqueous Solutions of Thiocyanates |
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