Recovery of Zn(II) from Simulated Liquid Waste Using Poly(Vinyl Alcohol-Acrylamide) Synthesized by Gamma Radiolysis Method
The recovery of enriched Zn-68 is extremely important in the production of short-lived isotope (Ga-67) in the Cyclotron because of its high price. A high amount of Zn-68 is produced during the production of Ga-67 from its target (Zn-target) by a solvent extraction technique. In this investigation, w...
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| Veröffentlicht in: | Journal of polymers and the environment 2023-11, Vol.31 (11), p.4960-4971 |
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| creator | Massoud, A. Mahmoud, H. H. |
| description | The recovery of enriched Zn-68 is extremely important in the production of short-lived isotope (Ga-67) in the Cyclotron because of its high price. A high amount of Zn-68 is produced during the production of Ga-67 from its target (Zn-target) by a solvent extraction technique. In this investigation, we successfully prepared poly(vinyl alcohol-t-acrylamide), P(VA-t-AM) resin using the gamma radiolysis technique. The characterization of pristine PVA and synthesized P(VA-t-AM) was performed to confirm their structures. The produced polymer was tested for the elimination of Zn
2+
ions from simulated liquid waste as produced during the production of the Ga-67. To get the highest uptake of Zn
2+
ions on the polymer, various parameters such as solution pH, polymer weight, and contact time were applied. The loading Zn
2+
ions were studied at optimum conditions of the Batch approach. Then, the retrieval of Zn
2+
ions from the packed chromatographic column was tested using different parameters such as flow rates, bed depths, and initial concentration of Zn
2+
. The results indicated that the percentages of loaded Zn
2+
ions on the packed column were 96.94% at the best operational conditions. Moreover, different eluents were applied to the retrieval of Zn
2+
ions from the P(VA-t-AM) column, and the data confirmed that the retrieval percentage of Zn
2+
ions from P(VA-t-AM) was 98.43% at the optimum. The reusability of the working polymer was examined for eight cycles. This paper recommended that the synthesized P(VA-t-AM) can be utilized for the retrieval of Zn
2+
ions from the spent Zn-68 target in the Cyclotron. |
| doi_str_mv | 10.1007/s10924-023-02910-1 |
| format | Article |
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2+
ions from simulated liquid waste as produced during the production of the Ga-67. To get the highest uptake of Zn
2+
ions on the polymer, various parameters such as solution pH, polymer weight, and contact time were applied. The loading Zn
2+
ions were studied at optimum conditions of the Batch approach. Then, the retrieval of Zn
2+
ions from the packed chromatographic column was tested using different parameters such as flow rates, bed depths, and initial concentration of Zn
2+
. The results indicated that the percentages of loaded Zn
2+
ions on the packed column were 96.94% at the best operational conditions. Moreover, different eluents were applied to the retrieval of Zn
2+
ions from the P(VA-t-AM) column, and the data confirmed that the retrieval percentage of Zn
2+
ions from P(VA-t-AM) was 98.43% at the optimum. The reusability of the working polymer was examined for eight cycles. This paper recommended that the synthesized P(VA-t-AM) can be utilized for the retrieval of Zn
2+
ions from the spent Zn-68 target in the Cyclotron.</description><identifier>ISSN: 1566-2543</identifier><identifier>EISSN: 1572-8919</identifier><identifier>DOI: 10.1007/s10924-023-02910-1</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Acrylamide ; Chemistry ; Chemistry and Materials Science ; Cyclotrons ; Environmental Chemistry ; Environmental Engineering/Biotechnology ; Industrial Chemistry/Chemical Engineering ; Ions ; Liquid wastes ; Materials Science ; Original Paper ; Packed columns ; Parameters ; Polymer Sciences ; Polymers ; Radiolysis ; Recovery ; Retrieval ; Solvent extraction ; Synthesis ; Zinc</subject><ispartof>Journal of polymers and the environment, 2023-11, Vol.31 (11), p.4960-4971</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-608a63a1ebdc133f3170c70018e6edf8548a47b3e633ac7ce3403f232887b49e3</citedby><cites>FETCH-LOGICAL-c319t-608a63a1ebdc133f3170c70018e6edf8548a47b3e633ac7ce3403f232887b49e3</cites><orcidid>0000-0002-3454-4458</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10924-023-02910-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10924-023-02910-1$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Massoud, A.</creatorcontrib><creatorcontrib>Mahmoud, H. H.</creatorcontrib><title>Recovery of Zn(II) from Simulated Liquid Waste Using Poly(Vinyl Alcohol-Acrylamide) Synthesized by Gamma Radiolysis Method</title><title>Journal of polymers and the environment</title><addtitle>J Polym Environ</addtitle><description>The recovery of enriched Zn-68 is extremely important in the production of short-lived isotope (Ga-67) in the Cyclotron because of its high price. A high amount of Zn-68 is produced during the production of Ga-67 from its target (Zn-target) by a solvent extraction technique. In this investigation, we successfully prepared poly(vinyl alcohol-t-acrylamide), P(VA-t-AM) resin using the gamma radiolysis technique. The characterization of pristine PVA and synthesized P(VA-t-AM) was performed to confirm their structures. The produced polymer was tested for the elimination of Zn
2+
ions from simulated liquid waste as produced during the production of the Ga-67. To get the highest uptake of Zn
2+
ions on the polymer, various parameters such as solution pH, polymer weight, and contact time were applied. The loading Zn
2+
ions were studied at optimum conditions of the Batch approach. Then, the retrieval of Zn
2+
ions from the packed chromatographic column was tested using different parameters such as flow rates, bed depths, and initial concentration of Zn
2+
. The results indicated that the percentages of loaded Zn
2+
ions on the packed column were 96.94% at the best operational conditions. Moreover, different eluents were applied to the retrieval of Zn
2+
ions from the P(VA-t-AM) column, and the data confirmed that the retrieval percentage of Zn
2+
ions from P(VA-t-AM) was 98.43% at the optimum. The reusability of the working polymer was examined for eight cycles. This paper recommended that the synthesized P(VA-t-AM) can be utilized for the retrieval of Zn
2+
ions from the spent Zn-68 target in the Cyclotron.</description><subject>Acrylamide</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Cyclotrons</subject><subject>Environmental Chemistry</subject><subject>Environmental Engineering/Biotechnology</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Ions</subject><subject>Liquid wastes</subject><subject>Materials Science</subject><subject>Original Paper</subject><subject>Packed columns</subject><subject>Parameters</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Radiolysis</subject><subject>Recovery</subject><subject>Retrieval</subject><subject>Solvent extraction</subject><subject>Synthesis</subject><subject>Zinc</subject><issn>1566-2543</issn><issn>1572-8919</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp9kMFKw0AQhoMoWKsv4GnBSz1EZ7NpsjmWorVQUVqr4GXZbibtliTb7qZC-vRureDNwzBz-L5_4A-Cawp3FCC9dxSyKA4hYn4yCiE9CTq0n0Yhz2h2eriTJIz6MTsPLpxbA4CnoBPsp6jMF9qWmIJ81r3x-JYU1lRkpqtdKRvMyURvdzonH9I1SOZO10vyasq2967rtiSDUpmVKcOBsm0pK53jLZm1dbNCp_feXrRkJKtKkqnMtdecduQZm5XJL4OzQpYOr353N5g_PrwNn8LJy2g8HExCxWjWhAlwmTBJcZEryljBaAoqBaAcE8wL3o-5jNMFw4QxqVKFLAZWRCziPF3EGbJucHPM3Viz3aFrxNrsbO1fiognWZpx2gdPRUdKWeOcxUJsrK6kbQUFcehYHDsWvmPx07GgXmJHyXm4XqL9i_7H-gZ_0H7J</recordid><startdate>20231101</startdate><enddate>20231101</enddate><creator>Massoud, A.</creator><creator>Mahmoud, H. H.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7SR</scope><scope>7XB</scope><scope>88I</scope><scope>8AO</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>M2P</scope><scope>PATMY</scope><scope>PCBAR</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PYCSY</scope><scope>Q9U</scope><orcidid>https://orcid.org/0000-0002-3454-4458</orcidid></search><sort><creationdate>20231101</creationdate><title>Recovery of Zn(II) from Simulated Liquid Waste Using Poly(Vinyl Alcohol-Acrylamide) Synthesized by Gamma Radiolysis Method</title><author>Massoud, A. ; Mahmoud, H. H.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-608a63a1ebdc133f3170c70018e6edf8548a47b3e633ac7ce3403f232887b49e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Acrylamide</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Cyclotrons</topic><topic>Environmental Chemistry</topic><topic>Environmental Engineering/Biotechnology</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Ions</topic><topic>Liquid wastes</topic><topic>Materials Science</topic><topic>Original Paper</topic><topic>Packed columns</topic><topic>Parameters</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Radiolysis</topic><topic>Recovery</topic><topic>Retrieval</topic><topic>Solvent extraction</topic><topic>Synthesis</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Massoud, A.</creatorcontrib><creatorcontrib>Mahmoud, H. H.</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Engineered Materials Abstracts</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest Pharma Collection</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>Agricultural & Environmental Science Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>Natural Science Collection</collection><collection>Earth, Atmospheric & Aquatic Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Science Database</collection><collection>Environmental Science Database</collection><collection>Earth, Atmospheric & Aquatic Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Environmental Science Collection</collection><collection>ProQuest Central Basic</collection><jtitle>Journal of polymers and the environment</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Massoud, A.</au><au>Mahmoud, H. H.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Recovery of Zn(II) from Simulated Liquid Waste Using Poly(Vinyl Alcohol-Acrylamide) Synthesized by Gamma Radiolysis Method</atitle><jtitle>Journal of polymers and the environment</jtitle><stitle>J Polym Environ</stitle><date>2023-11-01</date><risdate>2023</risdate><volume>31</volume><issue>11</issue><spage>4960</spage><epage>4971</epage><pages>4960-4971</pages><issn>1566-2543</issn><eissn>1572-8919</eissn><abstract>The recovery of enriched Zn-68 is extremely important in the production of short-lived isotope (Ga-67) in the Cyclotron because of its high price. A high amount of Zn-68 is produced during the production of Ga-67 from its target (Zn-target) by a solvent extraction technique. In this investigation, we successfully prepared poly(vinyl alcohol-t-acrylamide), P(VA-t-AM) resin using the gamma radiolysis technique. The characterization of pristine PVA and synthesized P(VA-t-AM) was performed to confirm their structures. The produced polymer was tested for the elimination of Zn
2+
ions from simulated liquid waste as produced during the production of the Ga-67. To get the highest uptake of Zn
2+
ions on the polymer, various parameters such as solution pH, polymer weight, and contact time were applied. The loading Zn
2+
ions were studied at optimum conditions of the Batch approach. Then, the retrieval of Zn
2+
ions from the packed chromatographic column was tested using different parameters such as flow rates, bed depths, and initial concentration of Zn
2+
. The results indicated that the percentages of loaded Zn
2+
ions on the packed column were 96.94% at the best operational conditions. Moreover, different eluents were applied to the retrieval of Zn
2+
ions from the P(VA-t-AM) column, and the data confirmed that the retrieval percentage of Zn
2+
ions from P(VA-t-AM) was 98.43% at the optimum. The reusability of the working polymer was examined for eight cycles. This paper recommended that the synthesized P(VA-t-AM) can be utilized for the retrieval of Zn
2+
ions from the spent Zn-68 target in the Cyclotron.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10924-023-02910-1</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0002-3454-4458</orcidid></addata></record> |
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| subjects | Acrylamide Chemistry Chemistry and Materials Science Cyclotrons Environmental Chemistry Environmental Engineering/Biotechnology Industrial Chemistry/Chemical Engineering Ions Liquid wastes Materials Science Original Paper Packed columns Parameters Polymer Sciences Polymers Radiolysis Recovery Retrieval Solvent extraction Synthesis Zinc |
| title | Recovery of Zn(II) from Simulated Liquid Waste Using Poly(Vinyl Alcohol-Acrylamide) Synthesized by Gamma Radiolysis Method |
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