An amorphous Lewis-acidic zirconium chlorofluoride as HF shuttle: C-F bond activation and formation

An exceptional HF transfer reaction by C-F bond activation of fluoropentane and a subsequent hydrofluorination of alkynes at room temperature is reported. An amorphous Lewis-acidic Zr chlorofluoride serves as heterogeneous catalyst, which is characterised by an eightfold coordination environment at...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2023-09, Vol.59 (75), p.11224-11227
Hauptverfasser:	Heinekamp, Christian, Buzanich, Ana Guilherme, Ahrens, Mike, Braun, Thomas, Emmerling, Franziska
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkynes Chlorine Fluorine Hydrofluorination Metallic glasses Room temperature
Online-Zugang:	Volltext
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