Computational Mechanistic Study on Intramolecular Triple Cyclization of 1-Biphenylethynyl-2-phenylethynylbenzenes Giving Spiro Fluorene-Phenylenevinylenes by Dual Catalysis

Cationic Au(I) complex-catalyzed double cyclizations of 1,2-dialkynylbenzene derivatives are valuable for the straightforward synthesis of ladder-type π-conjugated compounds. We have previously developed a method for synthesizing ladder-type π-conjugated molecules with spiro skeleton (spiro fluorene...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Bulletin of the Chemical Society of Japan 2023-07, Vol.96 (7), p.717-723
Hauptverfasser:	Nagashima, Yuki, Ouchi, Seiya, Inoue, Tomonori, Tanaka, Ken
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Cations Chemical synthesis Reaction mechanisms Regioselectivity
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!