Formal [2+1] Cycloadditions of a Metallacyclopentadiene Unit with Alkynes: Constructing Tetracyclic Conjugated Frameworks with Bridgehead Metals

Comprehensive Summary Metallacyclopentadienes play a vital role in transition‐metal mediated and catalyzed cycloaddition reactions of alkynes. Though versatile reactions of metallacyclopentadienes with alkynes have been disclosed, [2+1] cycloadditions of metallacyclopentadienes and alkynes have neve...

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Veröffentlicht in:	Chinese journal of chemistry 2023-08, Vol.41 (16), p.1987-1993
Hauptverfasser:	Chu, Zhenwei, Li, Jinhua, Chen, Dafa, Lu, Zhengyu, Meng, Weiran, Luo, Ming, Xia, Haiping
Format:	Artikel
Sprache:	eng
Schlagworte:	Absorption spectra Alkynes Chemical reactions Conjugation Cycloaddition Density functional theory Deuteration Electrophilic substitution Functionals Metallacycle Metals Photovoltaics Substitution reactions Vinylidene
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