In situ growth of the δ-manganese dioxide on carbon cloth by different concentrations of reactants for eco-friendly battery applications
Aqueous zinc ion batteries (AZIBs) have drawn more notice because of their affordability, high security, and favorable ecological impact. So far, manganese oxide (MnO 2 ) is thought to be an attractive material for storing energy among cathodes of aqueous zinc ion batteries. In particular, the layer...
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| Veröffentlicht in: | Journal of solid state electrochemistry 2023-10, Vol.27 (10), p.2691-2700 |
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| creator | Feng, Yaping Zhang, Youfeng Zhang, Yichen Zhang, Liang Wang, Yinling |
| description | Aqueous zinc ion batteries (AZIBs) have drawn more notice because of their affordability, high security, and favorable ecological impact. So far, manganese oxide (MnO
2
) is thought to be an attractive material for storing energy among cathodes of aqueous zinc ion batteries. In particular, the layered manganese dioxide (δ-MnO
2
) is more favorable to the diffusion of ions and can provide higher specific capacity. However, The effect of the concentration of reactants on microstructure and electrochemical performance of δ-MnO
2
, which has been less studied. Herein, the δ-MnO
2
deposited on carbon fabric as the cathodes of AZIBs by four different reactant concentrations (0.05 M, 0.07 M, 0.10 M, and 0.12 M) of potassium permanganate solution were successfully prepared. The electrochemical properties of AZIBs fabricated by reactant concentrations of 0.10 M KMnO
4
were excellent. The δ-MnO
2
/CC-0.10 M cathode provided higher rechargeable capacity of 268 mA h•g
−1
at 0.1 A•g
−1
, outstanding rate capability, and long cycle life of 97.3% preservation after 500 cycles at 2A•g
−1
. This study systematically demonstrates the influence of reagent concentration on the efficiency and stability of aqueous zinc–manganese ion batteries. |
| doi_str_mv | 10.1007/s10008-023-05569-9 |
| format | Article |
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2
) is thought to be an attractive material for storing energy among cathodes of aqueous zinc ion batteries. In particular, the layered manganese dioxide (δ-MnO
2
) is more favorable to the diffusion of ions and can provide higher specific capacity. However, The effect of the concentration of reactants on microstructure and electrochemical performance of δ-MnO
2
, which has been less studied. Herein, the δ-MnO
2
deposited on carbon fabric as the cathodes of AZIBs by four different reactant concentrations (0.05 M, 0.07 M, 0.10 M, and 0.12 M) of potassium permanganate solution were successfully prepared. The electrochemical properties of AZIBs fabricated by reactant concentrations of 0.10 M KMnO
4
were excellent. The δ-MnO
2
/CC-0.10 M cathode provided higher rechargeable capacity of 268 mA h•g
−1
at 0.1 A•g
−1
, outstanding rate capability, and long cycle life of 97.3% preservation after 500 cycles at 2A•g
−1
. This study systematically demonstrates the influence of reagent concentration on the efficiency and stability of aqueous zinc–manganese ion batteries.</description><identifier>ISSN: 1432-8488</identifier><identifier>EISSN: 1433-0768</identifier><identifier>DOI: 10.1007/s10008-023-05569-9</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Analytical Chemistry ; Carbon ; Cathodes ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Condensed Matter Physics ; Diffusion layers ; Electrochemical analysis ; Electrochemistry ; Energy Storage ; Ion diffusion ; Manganese dioxide ; Manganese ions ; Original Paper ; Physical Chemistry ; Potassium permanganate ; Reagents ; Rechargeable batteries</subject><ispartof>Journal of solid state electrochemistry, 2023-10, Vol.27 (10), p.2691-2700</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-2ea23aac561e8bd0c3ef7c80ee4385366ab97cc220bbc7210fe3914305d3cb1d3</citedby><cites>FETCH-LOGICAL-c319t-2ea23aac561e8bd0c3ef7c80ee4385366ab97cc220bbc7210fe3914305d3cb1d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10008-023-05569-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10008-023-05569-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Feng, Yaping</creatorcontrib><creatorcontrib>Zhang, Youfeng</creatorcontrib><creatorcontrib>Zhang, Yichen</creatorcontrib><creatorcontrib>Zhang, Liang</creatorcontrib><creatorcontrib>Wang, Yinling</creatorcontrib><title>In situ growth of the δ-manganese dioxide on carbon cloth by different concentrations of reactants for eco-friendly battery applications</title><title>Journal of solid state electrochemistry</title><addtitle>J Solid State Electrochem</addtitle><description>Aqueous zinc ion batteries (AZIBs) have drawn more notice because of their affordability, high security, and favorable ecological impact. So far, manganese oxide (MnO
2
) is thought to be an attractive material for storing energy among cathodes of aqueous zinc ion batteries. In particular, the layered manganese dioxide (δ-MnO
2
) is more favorable to the diffusion of ions and can provide higher specific capacity. However, The effect of the concentration of reactants on microstructure and electrochemical performance of δ-MnO
2
, which has been less studied. Herein, the δ-MnO
2
deposited on carbon fabric as the cathodes of AZIBs by four different reactant concentrations (0.05 M, 0.07 M, 0.10 M, and 0.12 M) of potassium permanganate solution were successfully prepared. The electrochemical properties of AZIBs fabricated by reactant concentrations of 0.10 M KMnO
4
were excellent. The δ-MnO
2
/CC-0.10 M cathode provided higher rechargeable capacity of 268 mA h•g
−1
at 0.1 A•g
−1
, outstanding rate capability, and long cycle life of 97.3% preservation after 500 cycles at 2A•g
−1
. This study systematically demonstrates the influence of reagent concentration on the efficiency and stability of aqueous zinc–manganese ion batteries.</description><subject>Analytical Chemistry</subject><subject>Carbon</subject><subject>Cathodes</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Diffusion layers</subject><subject>Electrochemical analysis</subject><subject>Electrochemistry</subject><subject>Energy Storage</subject><subject>Ion diffusion</subject><subject>Manganese dioxide</subject><subject>Manganese ions</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Potassium permanganate</subject><subject>Reagents</subject><subject>Rechargeable batteries</subject><issn>1432-8488</issn><issn>1433-0768</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9UMtOwzAQjBBIlMIPcLLE2eBHEztHVPGoVIkLnC3HWbepUrvYriCfwP_wHXwTLkHixmVnVzszq52iuKTkmhIibmKuRGLCOCZlWdW4PiomdMbzKCp5_NMzLGdSnhZnMW4IoaKiZFJ8LByKXdqjVfBvaY28RWkN6OsTb7VbaQcRUNv5964F5B0yOjQH6H3mNkNeWQsBXELGO5Mx6NR5Fw8-AbRJ2qWIrA8IjMc2dODafkCNTgnCgPRu13dmlJwXJ1b3ES5-cVq83N89zx_x8ulhMb9dYsNpnTADzbjWpqwoyKYlhoMVRhKAGZclryrd1MIYxkjTGMEoscDr_D0pW24a2vJpcTX67oJ_3UNMauP3weWTismKCVGXNcksNrJM8DEGsGoXuq0Og6JEHSJXY-QqR65-Ild1FvFRFDPZrSD8Wf-j-gZkTIft</recordid><startdate>20231001</startdate><enddate>20231001</enddate><creator>Feng, Yaping</creator><creator>Zhang, Youfeng</creator><creator>Zhang, Yichen</creator><creator>Zhang, Liang</creator><creator>Wang, Yinling</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20231001</creationdate><title>In situ growth of the δ-manganese dioxide on carbon cloth by different concentrations of reactants for eco-friendly battery applications</title><author>Feng, Yaping ; Zhang, Youfeng ; Zhang, Yichen ; Zhang, Liang ; Wang, Yinling</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-2ea23aac561e8bd0c3ef7c80ee4385366ab97cc220bbc7210fe3914305d3cb1d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Analytical Chemistry</topic><topic>Carbon</topic><topic>Cathodes</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Diffusion layers</topic><topic>Electrochemical analysis</topic><topic>Electrochemistry</topic><topic>Energy Storage</topic><topic>Ion diffusion</topic><topic>Manganese dioxide</topic><topic>Manganese ions</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Potassium permanganate</topic><topic>Reagents</topic><topic>Rechargeable batteries</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Feng, Yaping</creatorcontrib><creatorcontrib>Zhang, Youfeng</creatorcontrib><creatorcontrib>Zhang, Yichen</creatorcontrib><creatorcontrib>Zhang, Liang</creatorcontrib><creatorcontrib>Wang, Yinling</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of solid state electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Feng, Yaping</au><au>Zhang, Youfeng</au><au>Zhang, Yichen</au><au>Zhang, Liang</au><au>Wang, Yinling</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>In situ growth of the δ-manganese dioxide on carbon cloth by different concentrations of reactants for eco-friendly battery applications</atitle><jtitle>Journal of solid state electrochemistry</jtitle><stitle>J Solid State Electrochem</stitle><date>2023-10-01</date><risdate>2023</risdate><volume>27</volume><issue>10</issue><spage>2691</spage><epage>2700</epage><pages>2691-2700</pages><issn>1432-8488</issn><eissn>1433-0768</eissn><abstract>Aqueous zinc ion batteries (AZIBs) have drawn more notice because of their affordability, high security, and favorable ecological impact. So far, manganese oxide (MnO
2
) is thought to be an attractive material for storing energy among cathodes of aqueous zinc ion batteries. In particular, the layered manganese dioxide (δ-MnO
2
) is more favorable to the diffusion of ions and can provide higher specific capacity. However, The effect of the concentration of reactants on microstructure and electrochemical performance of δ-MnO
2
, which has been less studied. Herein, the δ-MnO
2
deposited on carbon fabric as the cathodes of AZIBs by four different reactant concentrations (0.05 M, 0.07 M, 0.10 M, and 0.12 M) of potassium permanganate solution were successfully prepared. The electrochemical properties of AZIBs fabricated by reactant concentrations of 0.10 M KMnO
4
were excellent. The δ-MnO
2
/CC-0.10 M cathode provided higher rechargeable capacity of 268 mA h•g
−1
at 0.1 A•g
−1
, outstanding rate capability, and long cycle life of 97.3% preservation after 500 cycles at 2A•g
−1
. This study systematically demonstrates the influence of reagent concentration on the efficiency and stability of aqueous zinc–manganese ion batteries.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s10008-023-05569-9</doi><tpages>10</tpages></addata></record> |
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| subjects | Analytical Chemistry Carbon Cathodes Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Condensed Matter Physics Diffusion layers Electrochemical analysis Electrochemistry Energy Storage Ion diffusion Manganese dioxide Manganese ions Original Paper Physical Chemistry Potassium permanganate Reagents Rechargeable batteries |
| title | In situ growth of the δ-manganese dioxide on carbon cloth by different concentrations of reactants for eco-friendly battery applications |
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