Synthesis and characterization of Cu/EMC-2 zeolite by two routes
The dispersion and loading of metallic species into supports are a critical issue that determines its activity and stability during the catalytic reactions. In the present work, the incorporation of Cu in EMC-2 zeolite was carried out. Two methods were evaluated: in situ and post-synthesis. The zeol...
Gespeichert in:
| Veröffentlicht in: | Chemical papers 2023-10, Vol.77 (10), p.6387-6396 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 6396 |
|---|---|
| container_issue | 10 |
| container_start_page | 6387 |
| container_title | Chemical papers |
| container_volume | 77 |
| creator | Medina-Ramirez, Adriana Morado-Alcantar, Francisco J. Galindo-Esquivel, Ignacio R. Diaz-Guillen, Juan C. Lopez Badillo, C. M. |
| description | The dispersion and loading of metallic species into supports are a critical issue that determines its activity and stability during the catalytic reactions. In the present work, the incorporation of Cu in EMC-2 zeolite was carried out. Two methods were evaluated: in situ and post-synthesis. The zeolitic materials were characterized by XRD, SEM/EDS and FT-IR. The obtained materials presented an intergrowth of EMT/FAU framework, favoring the incorporation and dispersion of copper. The higher copper content into EMC-2 zeolite was reached by post-synthesis method. The efficient copper loading, the dispersion and hydrothermal stability of the Cu/EMC-2 zeolites make these materials to be useful for catalytic applications. |
| doi_str_mv | 10.1007/s11696-023-02947-5 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2862584568</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2862584568</sourcerecordid><originalsourceid>FETCH-LOGICAL-c319t-aad875f0635d5207f64328c9d603e4b7c70d421b47393d473bae746cbbf2cd693</originalsourceid><addsrcrecordid>eNp9kEtLAzEUhYMoWKt_wFXAdWzemeyUoT5AcaGuQyaTsVPqpCYZpP31Rkdw5-Leuznn3MMHwDnBlwRjtUiESC0RpqyM5gqJAzAjjEmksRKHYIaZlEgyQY_BSUprjDnHAs_A1fNuyCuf-gTt0EK3stG67GO_t7kPAwwdrMfF8rFGFO592PTZw2YH82eAMYzZp1Nw1NlN8me_dw5eb5Yv9R16eLq9r68fkGNEZ2RtWynR4VKhFRSrTnJGK6dbiZnnjXIKt5yShiumWVt2Y73i0jVNR10rNZuDiyl3G8PH6FM26zDGobw0tJJUVFzIqqjopHIxpBR9Z7axf7dxZwg236TMRMoUUuaHlBHFxCZTKuLhzce_6H9cXwFjakQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2862584568</pqid></control><display><type>article</type><title>Synthesis and characterization of Cu/EMC-2 zeolite by two routes</title><source>Springer Nature - Complete Springer Journals</source><creator>Medina-Ramirez, Adriana ; Morado-Alcantar, Francisco J. ; Galindo-Esquivel, Ignacio R. ; Diaz-Guillen, Juan C. ; Lopez Badillo, C. M.</creator><creatorcontrib>Medina-Ramirez, Adriana ; Morado-Alcantar, Francisco J. ; Galindo-Esquivel, Ignacio R. ; Diaz-Guillen, Juan C. ; Lopez Badillo, C. M.</creatorcontrib><description>The dispersion and loading of metallic species into supports are a critical issue that determines its activity and stability during the catalytic reactions. In the present work, the incorporation of Cu in EMC-2 zeolite was carried out. Two methods were evaluated: in situ and post-synthesis. The zeolitic materials were characterized by XRD, SEM/EDS and FT-IR. The obtained materials presented an intergrowth of EMT/FAU framework, favoring the incorporation and dispersion of copper. The higher copper content into EMC-2 zeolite was reached by post-synthesis method. The efficient copper loading, the dispersion and hydrothermal stability of the Cu/EMC-2 zeolites make these materials to be useful for catalytic applications.</description><identifier>ISSN: 0366-6352</identifier><identifier>EISSN: 1336-9075</identifier><identifier>EISSN: 2585-7290</identifier><identifier>DOI: 10.1007/s11696-023-02947-5</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Biochemistry ; Biotechnology ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Copper ; Dispersion ; Industrial Chemistry/Chemical Engineering ; Materials Science ; Medicinal Chemistry ; Original Paper ; Stability ; Synthesis ; Zeolites</subject><ispartof>Chemical papers, 2023-10, Vol.77 (10), p.6387-6396</ispartof><rights>Institute of Chemistry, Slovak Academy of Sciences 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-aad875f0635d5207f64328c9d603e4b7c70d421b47393d473bae746cbbf2cd693</citedby><cites>FETCH-LOGICAL-c319t-aad875f0635d5207f64328c9d603e4b7c70d421b47393d473bae746cbbf2cd693</cites><orcidid>0000-0002-3713-3582</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11696-023-02947-5$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11696-023-02947-5$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids></links><search><creatorcontrib>Medina-Ramirez, Adriana</creatorcontrib><creatorcontrib>Morado-Alcantar, Francisco J.</creatorcontrib><creatorcontrib>Galindo-Esquivel, Ignacio R.</creatorcontrib><creatorcontrib>Diaz-Guillen, Juan C.</creatorcontrib><creatorcontrib>Lopez Badillo, C. M.</creatorcontrib><title>Synthesis and characterization of Cu/EMC-2 zeolite by two routes</title><title>Chemical papers</title><addtitle>Chem. Pap</addtitle><description>The dispersion and loading of metallic species into supports are a critical issue that determines its activity and stability during the catalytic reactions. In the present work, the incorporation of Cu in EMC-2 zeolite was carried out. Two methods were evaluated: in situ and post-synthesis. The zeolitic materials were characterized by XRD, SEM/EDS and FT-IR. The obtained materials presented an intergrowth of EMT/FAU framework, favoring the incorporation and dispersion of copper. The higher copper content into EMC-2 zeolite was reached by post-synthesis method. The efficient copper loading, the dispersion and hydrothermal stability of the Cu/EMC-2 zeolites make these materials to be useful for catalytic applications.</description><subject>Biochemistry</subject><subject>Biotechnology</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Copper</subject><subject>Dispersion</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Materials Science</subject><subject>Medicinal Chemistry</subject><subject>Original Paper</subject><subject>Stability</subject><subject>Synthesis</subject><subject>Zeolites</subject><issn>0366-6352</issn><issn>1336-9075</issn><issn>2585-7290</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9kEtLAzEUhYMoWKt_wFXAdWzemeyUoT5AcaGuQyaTsVPqpCYZpP31Rkdw5-Leuznn3MMHwDnBlwRjtUiESC0RpqyM5gqJAzAjjEmksRKHYIaZlEgyQY_BSUprjDnHAs_A1fNuyCuf-gTt0EK3stG67GO_t7kPAwwdrMfF8rFGFO592PTZw2YH82eAMYzZp1Nw1NlN8me_dw5eb5Yv9R16eLq9r68fkGNEZ2RtWynR4VKhFRSrTnJGK6dbiZnnjXIKt5yShiumWVt2Y73i0jVNR10rNZuDiyl3G8PH6FM26zDGobw0tJJUVFzIqqjopHIxpBR9Z7axf7dxZwg236TMRMoUUuaHlBHFxCZTKuLhzce_6H9cXwFjakQ</recordid><startdate>20231001</startdate><enddate>20231001</enddate><creator>Medina-Ramirez, Adriana</creator><creator>Morado-Alcantar, Francisco J.</creator><creator>Galindo-Esquivel, Ignacio R.</creator><creator>Diaz-Guillen, Juan C.</creator><creator>Lopez Badillo, C. M.</creator><general>Springer International Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-3713-3582</orcidid></search><sort><creationdate>20231001</creationdate><title>Synthesis and characterization of Cu/EMC-2 zeolite by two routes</title><author>Medina-Ramirez, Adriana ; Morado-Alcantar, Francisco J. ; Galindo-Esquivel, Ignacio R. ; Diaz-Guillen, Juan C. ; Lopez Badillo, C. M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-aad875f0635d5207f64328c9d603e4b7c70d421b47393d473bae746cbbf2cd693</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Biochemistry</topic><topic>Biotechnology</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Copper</topic><topic>Dispersion</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Materials Science</topic><topic>Medicinal Chemistry</topic><topic>Original Paper</topic><topic>Stability</topic><topic>Synthesis</topic><topic>Zeolites</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Medina-Ramirez, Adriana</creatorcontrib><creatorcontrib>Morado-Alcantar, Francisco J.</creatorcontrib><creatorcontrib>Galindo-Esquivel, Ignacio R.</creatorcontrib><creatorcontrib>Diaz-Guillen, Juan C.</creatorcontrib><creatorcontrib>Lopez Badillo, C. M.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemical papers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Medina-Ramirez, Adriana</au><au>Morado-Alcantar, Francisco J.</au><au>Galindo-Esquivel, Ignacio R.</au><au>Diaz-Guillen, Juan C.</au><au>Lopez Badillo, C. M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and characterization of Cu/EMC-2 zeolite by two routes</atitle><jtitle>Chemical papers</jtitle><stitle>Chem. Pap</stitle><date>2023-10-01</date><risdate>2023</risdate><volume>77</volume><issue>10</issue><spage>6387</spage><epage>6396</epage><pages>6387-6396</pages><issn>0366-6352</issn><eissn>1336-9075</eissn><eissn>2585-7290</eissn><abstract>The dispersion and loading of metallic species into supports are a critical issue that determines its activity and stability during the catalytic reactions. In the present work, the incorporation of Cu in EMC-2 zeolite was carried out. Two methods were evaluated: in situ and post-synthesis. The zeolitic materials were characterized by XRD, SEM/EDS and FT-IR. The obtained materials presented an intergrowth of EMT/FAU framework, favoring the incorporation and dispersion of copper. The higher copper content into EMC-2 zeolite was reached by post-synthesis method. The efficient copper loading, the dispersion and hydrothermal stability of the Cu/EMC-2 zeolites make these materials to be useful for catalytic applications.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s11696-023-02947-5</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0002-3713-3582</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0366-6352 |
| ispartof | Chemical papers, 2023-10, Vol.77 (10), p.6387-6396 |
| issn | 0366-6352 1336-9075 2585-7290 |
| language | eng |
| recordid | cdi_proquest_journals_2862584568 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Biochemistry Biotechnology Chemistry Chemistry and Materials Science Chemistry/Food Science Copper Dispersion Industrial Chemistry/Chemical Engineering Materials Science Medicinal Chemistry Original Paper Stability Synthesis Zeolites |
| title | Synthesis and characterization of Cu/EMC-2 zeolite by two routes |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-20T20%3A50%3A08IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20and%20characterization%20of%20Cu/EMC-2%20zeolite%20by%20two%20routes&rft.jtitle=Chemical%20papers&rft.au=Medina-Ramirez,%20Adriana&rft.date=2023-10-01&rft.volume=77&rft.issue=10&rft.spage=6387&rft.epage=6396&rft.pages=6387-6396&rft.issn=0366-6352&rft.eissn=1336-9075&rft_id=info:doi/10.1007/s11696-023-02947-5&rft_dat=%3Cproquest_cross%3E2862584568%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2862584568&rft_id=info:pmid/&rfr_iscdi=true |