Multifaceted analysis of PbO–Bi2O3–ZnO–B2O3 glasses: unveiling structural, Optical, and gamma-ray shielding behaviour
The fabrication process of PbO–Bi 2 O 3 –ZnO–B 2 O 3 (PBZB) glasses involved the application of a melt quenching technique. The glass samples were revealed through X-ray diffraction (XRD) analysis to be amorphous in nature. Fourier-transform infrared (FTIR) spectra, ranging from 4000 to 400 cm −1 ,...
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| Veröffentlicht in: | Journal of materials science. Materials in electronics 2023-08, Vol.34 (24), p.1721, Article 1721 |
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| creator | Al-Otaibi, Jamelah S. Almuqrin, Aljawhara H. Sayyed, M. I. Kumar, Ashok |
| description | The fabrication process of PbO–Bi
2
O
3
–ZnO–B
2
O
3
(PBZB) glasses involved the application of a melt quenching technique. The glass samples were revealed through X-ray diffraction (XRD) analysis to be amorphous in nature. Fourier-transform infrared (FTIR) spectra, ranging from 4000 to 400 cm
−1
, exhibited peaks and bands indicating bending and stretching vibrations associated with the constituent groups in the glasses. The Raman spectra indicated that non-bridging oxygens (NBOs) formed with PbO’s incorporation into the network. To investigate the UV–Vis spectra of the glass, the Derivation of Absorption Spectrum Fitting (DASF) method was employed. This analysis predicted a decrease in energy band gap values, which was attributed to the increased presence of NBOs within the glass network. The prepared glasses’ radiation-shielding properties were reported using Phy-X software in the range of 0.284–1.333 MeV, where it was found that the mass attenuation coefficient (MAC) follows the order of PBZB1 |
| doi_str_mv | 10.1007/s10854-023-11166-3 |
| format | Article |
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2
O
3
–ZnO–B
2
O
3
(PBZB) glasses involved the application of a melt quenching technique. The glass samples were revealed through X-ray diffraction (XRD) analysis to be amorphous in nature. Fourier-transform infrared (FTIR) spectra, ranging from 4000 to 400 cm
−1
, exhibited peaks and bands indicating bending and stretching vibrations associated with the constituent groups in the glasses. The Raman spectra indicated that non-bridging oxygens (NBOs) formed with PbO’s incorporation into the network. To investigate the UV–Vis spectra of the glass, the Derivation of Absorption Spectrum Fitting (DASF) method was employed. This analysis predicted a decrease in energy band gap values, which was attributed to the increased presence of NBOs within the glass network. The prepared glasses’ radiation-shielding properties were reported using Phy-X software in the range of 0.284–1.333 MeV, where it was found that the mass attenuation coefficient (MAC) follows the order of PBZB1 < PBZB2 < PBZB3 < PBZB4, which means a positive correlation of the samples’ MAC with the glasses’ PbO content, or an inverse correlation with the glasses’ B
2
O
3
content. Thus, the sample characterized by the highest content of PbO, or the least B
2
O
3
content, has the greatest radiation shielding ability. The ratio between the tenth value layer for the PBZB1 and PBZB4 samples was estimated, with the results demonstrating the ratio to be higher than one, thus indicating that PBZB1’s TVL is always greater than PBZB4’s TVL. From the ratio between the TVL, we found that the addition of PbO causes a reduction in the thickness of the glass that is needed to attenuate the incoming photons. The PBZB4 sample (which contains 70 mol% of PbO) has the greatest advantage over the other materials in the glass system at lower and higher energies, while having a slightly reduced advantage at medium energies. PBZB4 possesses the lowest HVL value, thus qualify as the best shielding material.</description><identifier>ISSN: 0957-4522</identifier><identifier>EISSN: 1573-482X</identifier><identifier>DOI: 10.1007/s10854-023-11166-3</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Absorption spectra ; Attenuation coefficients ; Bismuth trioxide ; Boron oxides ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Energy bands ; Energy gap ; Fourier transforms ; Gamma rays ; Glass ; Infrared analysis ; Infrared spectra ; Lead oxides ; Materials Science ; Optical and Electronic Materials ; Radiation ; Radiation shielding ; Raman spectra ; Zinc oxide</subject><ispartof>Journal of materials science. Materials in electronics, 2023-08, Vol.34 (24), p.1721, Article 1721</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-daa47d0e41afc7199f3bd10c5f122424efec464b12b97fb043be410cb82153cc3</citedby><cites>FETCH-LOGICAL-c319t-daa47d0e41afc7199f3bd10c5f122424efec464b12b97fb043be410cb82153cc3</cites><orcidid>0000-0001-8905-5304</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10854-023-11166-3$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10854-023-11166-3$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Al-Otaibi, Jamelah S.</creatorcontrib><creatorcontrib>Almuqrin, Aljawhara H.</creatorcontrib><creatorcontrib>Sayyed, M. I.</creatorcontrib><creatorcontrib>Kumar, Ashok</creatorcontrib><title>Multifaceted analysis of PbO–Bi2O3–ZnO–B2O3 glasses: unveiling structural, Optical, and gamma-ray shielding behaviour</title><title>Journal of materials science. Materials in electronics</title><addtitle>J Mater Sci: Mater Electron</addtitle><description>The fabrication process of PbO–Bi
2
O
3
–ZnO–B
2
O
3
(PBZB) glasses involved the application of a melt quenching technique. The glass samples were revealed through X-ray diffraction (XRD) analysis to be amorphous in nature. Fourier-transform infrared (FTIR) spectra, ranging from 4000 to 400 cm
−1
, exhibited peaks and bands indicating bending and stretching vibrations associated with the constituent groups in the glasses. The Raman spectra indicated that non-bridging oxygens (NBOs) formed with PbO’s incorporation into the network. To investigate the UV–Vis spectra of the glass, the Derivation of Absorption Spectrum Fitting (DASF) method was employed. This analysis predicted a decrease in energy band gap values, which was attributed to the increased presence of NBOs within the glass network. The prepared glasses’ radiation-shielding properties were reported using Phy-X software in the range of 0.284–1.333 MeV, where it was found that the mass attenuation coefficient (MAC) follows the order of PBZB1 < PBZB2 < PBZB3 < PBZB4, which means a positive correlation of the samples’ MAC with the glasses’ PbO content, or an inverse correlation with the glasses’ B
2
O
3
content. Thus, the sample characterized by the highest content of PbO, or the least B
2
O
3
content, has the greatest radiation shielding ability. The ratio between the tenth value layer for the PBZB1 and PBZB4 samples was estimated, with the results demonstrating the ratio to be higher than one, thus indicating that PBZB1’s TVL is always greater than PBZB4’s TVL. From the ratio between the TVL, we found that the addition of PbO causes a reduction in the thickness of the glass that is needed to attenuate the incoming photons. The PBZB4 sample (which contains 70 mol% of PbO) has the greatest advantage over the other materials in the glass system at lower and higher energies, while having a slightly reduced advantage at medium energies. PBZB4 possesses the lowest HVL value, thus qualify as the best shielding material.</description><subject>Absorption spectra</subject><subject>Attenuation coefficients</subject><subject>Bismuth trioxide</subject><subject>Boron oxides</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Energy bands</subject><subject>Energy gap</subject><subject>Fourier transforms</subject><subject>Gamma rays</subject><subject>Glass</subject><subject>Infrared analysis</subject><subject>Infrared spectra</subject><subject>Lead oxides</subject><subject>Materials Science</subject><subject>Optical and Electronic Materials</subject><subject>Radiation</subject><subject>Radiation shielding</subject><subject>Raman spectra</subject><subject>Zinc oxide</subject><issn>0957-4522</issn><issn>1573-482X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9kMtKAzEUhoMoWKsv4Crg1mhuc3On4g0qdaEgbkKSSaYp05mazBSKG9_BN_RJTDuCO1fnHPj-czgfAMcEnxGMs_NAcJ5whClDhJA0RWwHjEiSMcRz-roLRrhIMsQTSvfBQQhzjHHKWT4CH4993TkrtelMCWUj63VwAbYWPqnp9-fXlaNTFutbs53iAKtahmDCBeyblXG1ayoYOt_rrveyPoXTZef0ppFNCSu5WEjk5RqGmTN1uYGVmcmVa3t_CPasrIM5-q1j8HJ783x9jybTu4frywnSjBQdKqXkWYkNJ9LqjBSFZaokWCeWUMopN9ZonnJFqCoyqzBnKrJYq5yShGnNxuBk2Lv07XtvQifm8Xp8NQiaJ1k0xDIeKTpQ2rcheGPF0ruF9GtBsNhIFoNkESWLrWTBYogNoRDhpjL-b_U_qR_AzoMO</recordid><startdate>20230801</startdate><enddate>20230801</enddate><creator>Al-Otaibi, Jamelah S.</creator><creator>Almuqrin, Aljawhara H.</creator><creator>Sayyed, M. I.</creator><creator>Kumar, Ashok</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>F28</scope><scope>FR3</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>L7M</scope><scope>P5Z</scope><scope>P62</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>S0W</scope><orcidid>https://orcid.org/0000-0001-8905-5304</orcidid></search><sort><creationdate>20230801</creationdate><title>Multifaceted analysis of PbO–Bi2O3–ZnO–B2O3 glasses: unveiling structural, Optical, and gamma-ray shielding behaviour</title><author>Al-Otaibi, Jamelah S. ; Almuqrin, Aljawhara H. ; Sayyed, M. I. ; Kumar, Ashok</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-daa47d0e41afc7199f3bd10c5f122424efec464b12b97fb043be410cb82153cc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Absorption spectra</topic><topic>Attenuation coefficients</topic><topic>Bismuth trioxide</topic><topic>Boron oxides</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Energy bands</topic><topic>Energy gap</topic><topic>Fourier transforms</topic><topic>Gamma rays</topic><topic>Glass</topic><topic>Infrared analysis</topic><topic>Infrared spectra</topic><topic>Lead oxides</topic><topic>Materials Science</topic><topic>Optical and Electronic Materials</topic><topic>Radiation</topic><topic>Radiation shielding</topic><topic>Raman spectra</topic><topic>Zinc oxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Al-Otaibi, Jamelah S.</creatorcontrib><creatorcontrib>Almuqrin, Aljawhara H.</creatorcontrib><creatorcontrib>Sayyed, M. I.</creatorcontrib><creatorcontrib>Kumar, Ashok</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>DELNET Engineering & Technology Collection</collection><jtitle>Journal of materials science. Materials in electronics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Al-Otaibi, Jamelah S.</au><au>Almuqrin, Aljawhara H.</au><au>Sayyed, M. I.</au><au>Kumar, Ashok</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Multifaceted analysis of PbO–Bi2O3–ZnO–B2O3 glasses: unveiling structural, Optical, and gamma-ray shielding behaviour</atitle><jtitle>Journal of materials science. Materials in electronics</jtitle><stitle>J Mater Sci: Mater Electron</stitle><date>2023-08-01</date><risdate>2023</risdate><volume>34</volume><issue>24</issue><spage>1721</spage><pages>1721-</pages><artnum>1721</artnum><issn>0957-4522</issn><eissn>1573-482X</eissn><abstract>The fabrication process of PbO–Bi
2
O
3
–ZnO–B
2
O
3
(PBZB) glasses involved the application of a melt quenching technique. The glass samples were revealed through X-ray diffraction (XRD) analysis to be amorphous in nature. Fourier-transform infrared (FTIR) spectra, ranging from 4000 to 400 cm
−1
, exhibited peaks and bands indicating bending and stretching vibrations associated with the constituent groups in the glasses. The Raman spectra indicated that non-bridging oxygens (NBOs) formed with PbO’s incorporation into the network. To investigate the UV–Vis spectra of the glass, the Derivation of Absorption Spectrum Fitting (DASF) method was employed. This analysis predicted a decrease in energy band gap values, which was attributed to the increased presence of NBOs within the glass network. The prepared glasses’ radiation-shielding properties were reported using Phy-X software in the range of 0.284–1.333 MeV, where it was found that the mass attenuation coefficient (MAC) follows the order of PBZB1 < PBZB2 < PBZB3 < PBZB4, which means a positive correlation of the samples’ MAC with the glasses’ PbO content, or an inverse correlation with the glasses’ B
2
O
3
content. Thus, the sample characterized by the highest content of PbO, or the least B
2
O
3
content, has the greatest radiation shielding ability. The ratio between the tenth value layer for the PBZB1 and PBZB4 samples was estimated, with the results demonstrating the ratio to be higher than one, thus indicating that PBZB1’s TVL is always greater than PBZB4’s TVL. From the ratio between the TVL, we found that the addition of PbO causes a reduction in the thickness of the glass that is needed to attenuate the incoming photons. The PBZB4 sample (which contains 70 mol% of PbO) has the greatest advantage over the other materials in the glass system at lower and higher energies, while having a slightly reduced advantage at medium energies. PBZB4 possesses the lowest HVL value, thus qualify as the best shielding material.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10854-023-11166-3</doi><orcidid>https://orcid.org/0000-0001-8905-5304</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0957-4522 |
| ispartof | Journal of materials science. Materials in electronics, 2023-08, Vol.34 (24), p.1721, Article 1721 |
| issn | 0957-4522 1573-482X |
| language | eng |
| recordid | cdi_proquest_journals_2857482374 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Absorption spectra Attenuation coefficients Bismuth trioxide Boron oxides Characterization and Evaluation of Materials Chemistry and Materials Science Energy bands Energy gap Fourier transforms Gamma rays Glass Infrared analysis Infrared spectra Lead oxides Materials Science Optical and Electronic Materials Radiation Radiation shielding Raman spectra Zinc oxide |
| title | Multifaceted analysis of PbO–Bi2O3–ZnO–B2O3 glasses: unveiling structural, Optical, and gamma-ray shielding behaviour |
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