Catalytic Conversion of Oil in Model and Natural Reservoir Rocks
The catalytic activity of metal oxides in the processes of low- and high-temperature oxidation (LTO and HTO, respectively) of oil was studied on model systems consisting of oil-saturated quartz sand with additives of Al2O3, Cr2O3 and MgO using thermal analysis methods. The used additives were shown...
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| Veröffentlicht in: | Processes 2023-08, Vol.11 (8), p.2380 |
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| creator | Okhotnikova, Ekaterina S. Barskaya, Ekaterina E. Ganeeva, Yulia M. Yusupova, Tatyana N. Dengaev, Aleksey V. Vakhin, Alexey V. |
| description | The catalytic activity of metal oxides in the processes of low- and high-temperature oxidation (LTO and HTO, respectively) of oil was studied on model systems consisting of oil-saturated quartz sand with additives of Al2O3, Cr2O3 and MgO using thermal analysis methods. The used additives were shown to shift the LTO and HTO processes to the low-temperature region. The catalytic activity of a natural reservoir carbonate rock without and with water was studied. This study established that at room temperature in dry carbonate rock, the oil components undergo dealkylation and polycondensation of aromatic fragments for a week. In the presence of water, the polycondensation processes are suppressed, and the cracking of resin and asphaltene occurs. The cracking reactions lead to a decrease in the content of heteroatoms in resins and asphaltenes. |
| doi_str_mv | 10.3390/pr11082380 |
| format | Article |
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The used additives were shown to shift the LTO and HTO processes to the low-temperature region. The catalytic activity of a natural reservoir carbonate rock without and with water was studied. This study established that at room temperature in dry carbonate rock, the oil components undergo dealkylation and polycondensation of aromatic fragments for a week. In the presence of water, the polycondensation processes are suppressed, and the cracking of resin and asphaltene occurs. The cracking reactions lead to a decrease in the content of heteroatoms in resins and asphaltenes.</description><identifier>ISSN: 2227-9717</identifier><identifier>EISSN: 2227-9717</identifier><identifier>DOI: 10.3390/pr11082380</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Additives ; Aluminum oxide ; Analysis ; Asphaltenes ; Carbonate rocks ; Carbonates ; Catalytic activity ; Catalytic converters ; Chromatography ; Dealkylation ; High temperature ; Hydrocarbons ; Low temperature ; Metal oxides ; Oils & fats ; Oxidation ; Quartz ; Reservoirs ; Resins ; Room temperature ; Spectrum analysis ; Sulfur content ; Temperature ; Thermal analysis ; Viscosity</subject><ispartof>Processes, 2023-08, Vol.11 (8), p.2380</ispartof><rights>COPYRIGHT 2023 MDPI AG</rights><rights>2023 by the authors. Licensee MDPI, Basel, Switzerland. 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The used additives were shown to shift the LTO and HTO processes to the low-temperature region. The catalytic activity of a natural reservoir carbonate rock without and with water was studied. This study established that at room temperature in dry carbonate rock, the oil components undergo dealkylation and polycondensation of aromatic fragments for a week. In the presence of water, the polycondensation processes are suppressed, and the cracking of resin and asphaltene occurs. 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The used additives were shown to shift the LTO and HTO processes to the low-temperature region. The catalytic activity of a natural reservoir carbonate rock without and with water was studied. This study established that at room temperature in dry carbonate rock, the oil components undergo dealkylation and polycondensation of aromatic fragments for a week. In the presence of water, the polycondensation processes are suppressed, and the cracking of resin and asphaltene occurs. The cracking reactions lead to a decrease in the content of heteroatoms in resins and asphaltenes.</abstract><cop>Basel</cop><pub>MDPI AG</pub><doi>10.3390/pr11082380</doi><orcidid>https://orcid.org/0000-0002-5168-7063</orcidid><orcidid>https://orcid.org/0000-0003-3309-3453</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Additives Aluminum oxide Analysis Asphaltenes Carbonate rocks Carbonates Catalytic activity Catalytic converters Chromatography Dealkylation High temperature Hydrocarbons Low temperature Metal oxides Oils & fats Oxidation Quartz Reservoirs Resins Room temperature Spectrum analysis Sulfur content Temperature Thermal analysis Viscosity |
| title | Catalytic Conversion of Oil in Model and Natural Reservoir Rocks |
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