Adsorption-catalytic method for reducing the content of sulphur compounds in gas condensate diesel fuel
Gas condensate diesel fuels, being an excellent resource base, often do not meet modern standards of the cetane number value and the content of sulfur compounds (SC). Currently, Euro 5 and Euro 6 (
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| Veröffentlicht in: | IOP conference series. Materials Science and Engineering 2023-08, Vol.1289 (1), p.12065 |
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| creator | Grishina, Irina Lyubimenko, Valentina Kolesnikov, Sergey Shcherban, Alena Vinokurov, Vladimir |
| description | Gas condensate diesel fuels, being an excellent resource base, often do not meet modern standards of the cetane number value and the content of sulfur compounds (SC). Currently, Euro 5 and Euro 6 ( |
| doi_str_mv | 10.1088/1757-899X/1289/1/012065 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_iop_j</sourceid><recordid>TN_cdi_proquest_journals_2857439273</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2857439273</sourcerecordid><originalsourceid>FETCH-LOGICAL-c2035-41e9e71a6383ba45b3002c0c8e29d3c32428f653c0d6c441d1a126ca740a5d1d3</originalsourceid><addsrcrecordid>eNqFkE1LAzEQhoMoWKu_wYAnD2vztZvssZT6ARUPKngLaZJtt2yTNcke-u_dZaUiCJ5mmHneGXgAuMboDiMhZpjnPBNl-THDRJQzPEOYoCI_AZPj5vTYC3wOLmLcIVRwxtAEbOYm-tCm2rtMq6SaQ6o13Nu09QZWPsBgTadrt4Fpa6H2LlmXoK9g7Jp224V-tG9950yEtYMbFQfGWBdVstDUNtoGVp1tLsFZpZpor77rFLzfL98Wj9nq5eFpMV9lmiCaZwzb0nKsCiroWrF8TREiGmlhSWmopoQRURU51cgUmjFssMKk0IozpHKDDZ2Cm_FuG_xnZ2OSO98F17-UROSc0ZJw2lN8pHTwMQZbyTbUexUOEiM5WJWDLzm4k4NVieVotU_SMVn79uf0_6nbP1LPr8vfnGxNRb8AdxmIMA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2857439273</pqid></control><display><type>article</type><title>Adsorption-catalytic method for reducing the content of sulphur compounds in gas condensate diesel fuel</title><source>Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals</source><source>Institute of Physics Open Access Journal Titles</source><source>IOPscience extra</source><source>Free Full-Text Journals in Chemistry</source><creator>Grishina, Irina ; Lyubimenko, Valentina ; Kolesnikov, Sergey ; Shcherban, Alena ; Vinokurov, Vladimir</creator><creatorcontrib>Grishina, Irina ; Lyubimenko, Valentina ; Kolesnikov, Sergey ; Shcherban, Alena ; Vinokurov, Vladimir</creatorcontrib><description>Gas condensate diesel fuels, being an excellent resource base, often do not meet modern standards of the cetane number value and the content of sulfur compounds (SC). Currently, Euro 5 and Euro 6 (<10 ppm sulfur content) diesel motor fuels are produced worldwide. High-quality diesel fuels are produced using hydro desulfurization process. Analysis of scientific publications has shown that the adsorption is effective method of desulphurization, which can serve as a method of removing SC from fuels or refining oil and its fractions, which allows removing residual sulfur. The advantages of the adsorption method are: low level of capital costs; simplicity of equipment; carrying out the process under much milder conditions compared to hydro desulfurization. In this paper, an original adsorption-catalytic method of reducing the concentration of SC to <10 ppm using a nanoporous adsorbent-catalyst is proposed. The structure and content of complex sulfur compounds in gas condensate fuels obtained from the raw materials of two deposits – Yamburgsky and Zapolyarny – were determined by gas chromatography–mass spectrometry. The next SC substances were found:
tert
-hexadecanethiol (C
16
H
34
S); 4,4,6-trimethyl-5-phenyl-1,3-oxazinane-2-thione (C
13
H
17
NOS); 1,2-bis(2-methylundecan-2-yl)-disulfane (C
24
H
50
S
2
); 3-methyl-2,4a,9,9a-tetrahydro-1H-2λ
4
-indeno [2,1-c]thiopyran-2-carbonitrile (C
14
H
15
NS) and 2,3,4,5-pentamethylbenzene-sulfoneamide (C
11
H
17
NO
2
S). Three-dimensional images of SC molecules and their adsorption complexes with Al-Ni-Mo-O component of a complex adsorbent-catalyst were obtained by molecular modeling. The adsorption energies of SC on the Al-Ni-Mo-O catalyst are calculated. The obtained values of the adsorption energies are in the range of −99.17 ÷−231.66 kJ/mol. As a result of the conducted research, a cartridge with selected adsorbent catalysts has been developed, which must be activated by heating in an inert medium up to 350 ° C. The average life of the cartridge is 1.5 years, after which it needs restoration.</description><identifier>ISSN: 1757-8981</identifier><identifier>EISSN: 1757-899X</identifier><identifier>DOI: 10.1088/1757-899X/1289/1/012065</identifier><language>eng</language><publisher>Bristol: IOP Publishing</publisher><subject>Adsorbents ; Adsorption ; Aluminum ; Capital costs ; Cartridges ; Catalysts ; Cetane number ; Condensates ; Desulfurizing ; Diesel fuels ; Gas chromatography ; Low level ; Mass spectrometry ; Molybdenum ; Motor fuels ; Nickel ; Raw materials ; Sulfur compounds ; Sulfur content</subject><ispartof>IOP conference series. Materials Science and Engineering, 2023-08, Vol.1289 (1), p.12065</ispartof><rights>Published under licence by IOP Publishing Ltd</rights><rights>Published under licence by IOP Publishing Ltd. This work is published under http://creativecommons.org/licenses/by/3.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c2035-41e9e71a6383ba45b3002c0c8e29d3c32428f653c0d6c441d1a126ca740a5d1d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://iopscience.iop.org/article/10.1088/1757-899X/1289/1/012065/pdf$$EPDF$$P50$$Giop$$Hfree_for_read</linktopdf><link.rule.ids>315,781,785,27929,27930,38873,38895,53845,53872</link.rule.ids></links><search><creatorcontrib>Grishina, Irina</creatorcontrib><creatorcontrib>Lyubimenko, Valentina</creatorcontrib><creatorcontrib>Kolesnikov, Sergey</creatorcontrib><creatorcontrib>Shcherban, Alena</creatorcontrib><creatorcontrib>Vinokurov, Vladimir</creatorcontrib><title>Adsorption-catalytic method for reducing the content of sulphur compounds in gas condensate diesel fuel</title><title>IOP conference series. Materials Science and Engineering</title><addtitle>IOP Conf. Ser.: Mater. Sci. Eng</addtitle><description>Gas condensate diesel fuels, being an excellent resource base, often do not meet modern standards of the cetane number value and the content of sulfur compounds (SC). Currently, Euro 5 and Euro 6 (<10 ppm sulfur content) diesel motor fuels are produced worldwide. High-quality diesel fuels are produced using hydro desulfurization process. Analysis of scientific publications has shown that the adsorption is effective method of desulphurization, which can serve as a method of removing SC from fuels or refining oil and its fractions, which allows removing residual sulfur. The advantages of the adsorption method are: low level of capital costs; simplicity of equipment; carrying out the process under much milder conditions compared to hydro desulfurization. In this paper, an original adsorption-catalytic method of reducing the concentration of SC to <10 ppm using a nanoporous adsorbent-catalyst is proposed. The structure and content of complex sulfur compounds in gas condensate fuels obtained from the raw materials of two deposits – Yamburgsky and Zapolyarny – were determined by gas chromatography–mass spectrometry. The next SC substances were found:
tert
-hexadecanethiol (C
16
H
34
S); 4,4,6-trimethyl-5-phenyl-1,3-oxazinane-2-thione (C
13
H
17
NOS); 1,2-bis(2-methylundecan-2-yl)-disulfane (C
24
H
50
S
2
); 3-methyl-2,4a,9,9a-tetrahydro-1H-2λ
4
-indeno [2,1-c]thiopyran-2-carbonitrile (C
14
H
15
NS) and 2,3,4,5-pentamethylbenzene-sulfoneamide (C
11
H
17
NO
2
S). Three-dimensional images of SC molecules and their adsorption complexes with Al-Ni-Mo-O component of a complex adsorbent-catalyst were obtained by molecular modeling. The adsorption energies of SC on the Al-Ni-Mo-O catalyst are calculated. The obtained values of the adsorption energies are in the range of −99.17 ÷−231.66 kJ/mol. As a result of the conducted research, a cartridge with selected adsorbent catalysts has been developed, which must be activated by heating in an inert medium up to 350 ° C. The average life of the cartridge is 1.5 years, after which it needs restoration.</description><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Aluminum</subject><subject>Capital costs</subject><subject>Cartridges</subject><subject>Catalysts</subject><subject>Cetane number</subject><subject>Condensates</subject><subject>Desulfurizing</subject><subject>Diesel fuels</subject><subject>Gas chromatography</subject><subject>Low level</subject><subject>Mass spectrometry</subject><subject>Molybdenum</subject><subject>Motor fuels</subject><subject>Nickel</subject><subject>Raw materials</subject><subject>Sulfur compounds</subject><subject>Sulfur content</subject><issn>1757-8981</issn><issn>1757-899X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>O3W</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNqFkE1LAzEQhoMoWKu_wYAnD2vztZvssZT6ARUPKngLaZJtt2yTNcke-u_dZaUiCJ5mmHneGXgAuMboDiMhZpjnPBNl-THDRJQzPEOYoCI_AZPj5vTYC3wOLmLcIVRwxtAEbOYm-tCm2rtMq6SaQ6o13Nu09QZWPsBgTadrt4Fpa6H2LlmXoK9g7Jp224V-tG9950yEtYMbFQfGWBdVstDUNtoGVp1tLsFZpZpor77rFLzfL98Wj9nq5eFpMV9lmiCaZwzb0nKsCiroWrF8TREiGmlhSWmopoQRURU51cgUmjFssMKk0IozpHKDDZ2Cm_FuG_xnZ2OSO98F17-UROSc0ZJw2lN8pHTwMQZbyTbUexUOEiM5WJWDLzm4k4NVieVotU_SMVn79uf0_6nbP1LPr8vfnGxNRb8AdxmIMA</recordid><startdate>20230801</startdate><enddate>20230801</enddate><creator>Grishina, Irina</creator><creator>Lyubimenko, Valentina</creator><creator>Kolesnikov, Sergey</creator><creator>Shcherban, Alena</creator><creator>Vinokurov, Vladimir</creator><general>IOP Publishing</general><scope>O3W</scope><scope>TSCCA</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PTHSS</scope></search><sort><creationdate>20230801</creationdate><title>Adsorption-catalytic method for reducing the content of sulphur compounds in gas condensate diesel fuel</title><author>Grishina, Irina ; Lyubimenko, Valentina ; Kolesnikov, Sergey ; Shcherban, Alena ; Vinokurov, Vladimir</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2035-41e9e71a6383ba45b3002c0c8e29d3c32428f653c0d6c441d1a126ca740a5d1d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Adsorbents</topic><topic>Adsorption</topic><topic>Aluminum</topic><topic>Capital costs</topic><topic>Cartridges</topic><topic>Catalysts</topic><topic>Cetane number</topic><topic>Condensates</topic><topic>Desulfurizing</topic><topic>Diesel fuels</topic><topic>Gas chromatography</topic><topic>Low level</topic><topic>Mass spectrometry</topic><topic>Molybdenum</topic><topic>Motor fuels</topic><topic>Nickel</topic><topic>Raw materials</topic><topic>Sulfur compounds</topic><topic>Sulfur content</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Grishina, Irina</creatorcontrib><creatorcontrib>Lyubimenko, Valentina</creatorcontrib><creatorcontrib>Kolesnikov, Sergey</creatorcontrib><creatorcontrib>Shcherban, Alena</creatorcontrib><creatorcontrib>Vinokurov, Vladimir</creatorcontrib><collection>Institute of Physics Open Access Journal Titles</collection><collection>IOPscience (Open Access)</collection><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>Access via ProQuest (Open Access)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Engineering Collection</collection><jtitle>IOP conference series. Materials Science and Engineering</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Grishina, Irina</au><au>Lyubimenko, Valentina</au><au>Kolesnikov, Sergey</au><au>Shcherban, Alena</au><au>Vinokurov, Vladimir</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Adsorption-catalytic method for reducing the content of sulphur compounds in gas condensate diesel fuel</atitle><jtitle>IOP conference series. Materials Science and Engineering</jtitle><addtitle>IOP Conf. Ser.: Mater. Sci. Eng</addtitle><date>2023-08-01</date><risdate>2023</risdate><volume>1289</volume><issue>1</issue><spage>12065</spage><pages>12065-</pages><issn>1757-8981</issn><eissn>1757-899X</eissn><abstract>Gas condensate diesel fuels, being an excellent resource base, often do not meet modern standards of the cetane number value and the content of sulfur compounds (SC). Currently, Euro 5 and Euro 6 (<10 ppm sulfur content) diesel motor fuels are produced worldwide. High-quality diesel fuels are produced using hydro desulfurization process. Analysis of scientific publications has shown that the adsorption is effective method of desulphurization, which can serve as a method of removing SC from fuels or refining oil and its fractions, which allows removing residual sulfur. The advantages of the adsorption method are: low level of capital costs; simplicity of equipment; carrying out the process under much milder conditions compared to hydro desulfurization. In this paper, an original adsorption-catalytic method of reducing the concentration of SC to <10 ppm using a nanoporous adsorbent-catalyst is proposed. The structure and content of complex sulfur compounds in gas condensate fuels obtained from the raw materials of two deposits – Yamburgsky and Zapolyarny – were determined by gas chromatography–mass spectrometry. The next SC substances were found:
tert
-hexadecanethiol (C
16
H
34
S); 4,4,6-trimethyl-5-phenyl-1,3-oxazinane-2-thione (C
13
H
17
NOS); 1,2-bis(2-methylundecan-2-yl)-disulfane (C
24
H
50
S
2
); 3-methyl-2,4a,9,9a-tetrahydro-1H-2λ
4
-indeno [2,1-c]thiopyran-2-carbonitrile (C
14
H
15
NS) and 2,3,4,5-pentamethylbenzene-sulfoneamide (C
11
H
17
NO
2
S). Three-dimensional images of SC molecules and their adsorption complexes with Al-Ni-Mo-O component of a complex adsorbent-catalyst were obtained by molecular modeling. The adsorption energies of SC on the Al-Ni-Mo-O catalyst are calculated. The obtained values of the adsorption energies are in the range of −99.17 ÷−231.66 kJ/mol. As a result of the conducted research, a cartridge with selected adsorbent catalysts has been developed, which must be activated by heating in an inert medium up to 350 ° C. The average life of the cartridge is 1.5 years, after which it needs restoration.</abstract><cop>Bristol</cop><pub>IOP Publishing</pub><doi>10.1088/1757-899X/1289/1/012065</doi><tpages>13</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | Adsorbents Adsorption Aluminum Capital costs Cartridges Catalysts Cetane number Condensates Desulfurizing Diesel fuels Gas chromatography Low level Mass spectrometry Molybdenum Motor fuels Nickel Raw materials Sulfur compounds Sulfur content |
| title | Adsorption-catalytic method for reducing the content of sulphur compounds in gas condensate diesel fuel |
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