NiO nanoparticles decorated pine needle-liked CuO as efficient electrocatalysts to boost methanol oxidation reaction

Design and synthesis of high-performance and low-cost electrocatalysts for methanol oxidation reaction (MOR) are of great significance in energy conversion applications. In this work, g-NiO/CuO composites with high catalytic performance for MOR are successfully synthesized by a template method using...

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Veröffentlicht in:Ionics 2023-09, Vol.29 (9), p.3693-3701
Hauptverfasser: Tang, Xiao, Wang, Zhenwei, Cai, Dandan, Shao, Qinsi, Qin, Ziwei, Liu, Yang, Li, Wenxian, Li, Ying, Zhang, Jiujun
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container_end_page 3701
container_issue 9
container_start_page 3693
container_title Ionics
container_volume 29
creator Tang, Xiao
Wang, Zhenwei
Cai, Dandan
Shao, Qinsi
Qin, Ziwei
Liu, Yang
Li, Wenxian
Li, Ying
Zhang, Jiujun
description Design and synthesis of high-performance and low-cost electrocatalysts for methanol oxidation reaction (MOR) are of great significance in energy conversion applications. In this work, g-NiO/CuO composites with high catalytic performance for MOR are successfully synthesized by a template method using g-C 3 N 4 flakes as the sacrificial template. NiO nanoparticles are dispersed uniformly on the surface of the pine needle-liked CuO substrate, resulting in a synergistic effect which can enhance the electrocatalytic MOR activity and stability of g-NiO/CuO catalysts. The catalyst shows a maximum peak current density of 159 mA cm −2 and also long-term stability. The bimetal-oxide-synergistic strategy in this work highlights a promising way for the design of catalysts with high electrochemical performance for direct methanol fuel cells (DMFCs).
doi_str_mv 10.1007/s11581-023-05097-6
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subjects Bimetals
Carbon nitride
Catalysts
Catalytic converters
Chemical synthesis
Chemistry
Chemistry and Materials Science
Condensed Matter Physics
Copper oxides
Electrocatalysts
Electrochemical analysis
Electrochemistry
Energy conversion
Energy Storage
Fuel cells
Methanol
Nanoparticles
Nickel oxides
Optical and Electronic Materials
Oxidation
Renewable and Green Energy
Stability
Substrates
Synergistic effect
title NiO nanoparticles decorated pine needle-liked CuO as efficient electrocatalysts to boost methanol oxidation reaction
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