A new highly sensitive cryogenic luminescent MOF thermometer built with pyromellitic acid
A ratiometric thermometer based on a mixed Eu-Tb metal-organic framework is reported with a maximum relative thermal sensitivity of 16.1% K −1 at 11 K making this material one of the best-performing thermometers currently reported in the literature. The sensing mechanism of {[Tb 2− x Eu x (H 2 Btec)...
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| Veröffentlicht in: | Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2023-08, Vol.11 (32), p.1951-1956 |
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| container_end_page | 1956 |
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| container_issue | 32 |
| container_start_page | 1951 |
| container_title | Journal of materials chemistry. C, Materials for optical and electronic devices |
| container_volume | 11 |
| creator | Amiaud, Thibault Jubera, Véronique Serier-Brault, Hélène |
| description | A ratiometric thermometer based on a mixed Eu-Tb metal-organic framework is reported with a maximum relative thermal sensitivity of 16.1% K
−1
at 11 K making this material one of the best-performing thermometers currently reported in the literature. The sensing mechanism of {[Tb
2−
x
Eu
x
(H
2
Btec)(Btec)(H
2
O)
2
]·4H
2
O}
n
(Btec = 1,2,4,5 Benzenetetracarboxylic acid) has been attributed to a phonon-assisted energy migration between neighboring Tb
3+
ions in the structure.
Design of a new highly sensitive cryogenic luminescent thermometer based on a mixed Eu/Tb MOF. |
| doi_str_mv | 10.1039/d3tc02125d |
| format | Article |
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−1
at 11 K making this material one of the best-performing thermometers currently reported in the literature. The sensing mechanism of {[Tb
2−
x
Eu
x
(H
2
Btec)(Btec)(H
2
O)
2
]·4H
2
O}
n
(Btec = 1,2,4,5 Benzenetetracarboxylic acid) has been attributed to a phonon-assisted energy migration between neighboring Tb
3+
ions in the structure.
Design of a new highly sensitive cryogenic luminescent thermometer based on a mixed Eu/Tb MOF.</description><identifier>ISSN: 2050-7526</identifier><identifier>EISSN: 2050-7534</identifier><identifier>DOI: 10.1039/d3tc02125d</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Chemical Sciences ; Instrumentation and Detectors ; Material chemistry ; Metal-organic frameworks ; Physics ; Thermometers ; Thermometry</subject><ispartof>Journal of materials chemistry. C, Materials for optical and electronic devices, 2023-08, Vol.11 (32), p.1951-1956</ispartof><rights>Copyright Royal Society of Chemistry 2023</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c351t-b17b4eafc636e33e8f301e21e4747b24b65e8fd0d6449a3e154a41826b03a7ee3</citedby><cites>FETCH-LOGICAL-c351t-b17b4eafc636e33e8f301e21e4747b24b65e8fd0d6449a3e154a41826b03a7ee3</cites><orcidid>0000-0002-3300-1347 ; 0000-0002-2832-3958</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,776,780,881,27901,27902</link.rule.ids><backlink>$$Uhttps://hal.science/hal-04182580$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Amiaud, Thibault</creatorcontrib><creatorcontrib>Jubera, Véronique</creatorcontrib><creatorcontrib>Serier-Brault, Hélène</creatorcontrib><title>A new highly sensitive cryogenic luminescent MOF thermometer built with pyromellitic acid</title><title>Journal of materials chemistry. C, Materials for optical and electronic devices</title><description>A ratiometric thermometer based on a mixed Eu-Tb metal-organic framework is reported with a maximum relative thermal sensitivity of 16.1% K
−1
at 11 K making this material one of the best-performing thermometers currently reported in the literature. The sensing mechanism of {[Tb
2−
x
Eu
x
(H
2
Btec)(Btec)(H
2
O)
2
]·4H
2
O}
n
(Btec = 1,2,4,5 Benzenetetracarboxylic acid) has been attributed to a phonon-assisted energy migration between neighboring Tb
3+
ions in the structure.
Design of a new highly sensitive cryogenic luminescent thermometer based on a mixed Eu/Tb MOF.</description><subject>Chemical Sciences</subject><subject>Instrumentation and Detectors</subject><subject>Material chemistry</subject><subject>Metal-organic frameworks</subject><subject>Physics</subject><subject>Thermometers</subject><subject>Thermometry</subject><issn>2050-7526</issn><issn>2050-7534</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpFkctLw0AQxoMoWLQX78KCJ4XoPvM4ltZaodJLPXhaNptJsyWPurttyX9vaqTOZYaP33wM3wTBHcHPBLP0JWdeY0qoyC-CEcUCh7Fg_PI80-g6GDu3xX0lJEqidBR8TVADR1SaTVl1yEHjjDcHQNp27QYao1G1r00DTkPj0cdqjnwJtm5r8GBRtjeVR0fjS7TrbC9WVb-ukdImvw2uClU5GP_1m-Bz_rqeLsLl6u19OlmGmgniw4zEGQdV6IhFwBgkBcMEKAEe8zijPItEr-U4jzhPFQMiuOIkoVGGmYoB2E3wOPiWqpI7a2plO9kqIxeTpTxp-ISLBB9Izz4M7M6233twXm7bvW368yRNBImTmKW0p54GStvWOQvF2ZZgeUpazth6-pv0rIfvB9g6feb-P8F-AG8Kecc</recordid><startdate>20230817</startdate><enddate>20230817</enddate><creator>Amiaud, Thibault</creator><creator>Jubera, Véronique</creator><creator>Serier-Brault, Hélène</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0002-3300-1347</orcidid><orcidid>https://orcid.org/0000-0002-2832-3958</orcidid></search><sort><creationdate>20230817</creationdate><title>A new highly sensitive cryogenic luminescent MOF thermometer built with pyromellitic acid</title><author>Amiaud, Thibault ; Jubera, Véronique ; Serier-Brault, Hélène</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c351t-b17b4eafc636e33e8f301e21e4747b24b65e8fd0d6449a3e154a41826b03a7ee3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Chemical Sciences</topic><topic>Instrumentation and Detectors</topic><topic>Material chemistry</topic><topic>Metal-organic frameworks</topic><topic>Physics</topic><topic>Thermometers</topic><topic>Thermometry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Amiaud, Thibault</creatorcontrib><creatorcontrib>Jubera, Véronique</creatorcontrib><creatorcontrib>Serier-Brault, Hélène</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Journal of materials chemistry. C, Materials for optical and electronic devices</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Amiaud, Thibault</au><au>Jubera, Véronique</au><au>Serier-Brault, Hélène</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A new highly sensitive cryogenic luminescent MOF thermometer built with pyromellitic acid</atitle><jtitle>Journal of materials chemistry. C, Materials for optical and electronic devices</jtitle><date>2023-08-17</date><risdate>2023</risdate><volume>11</volume><issue>32</issue><spage>1951</spage><epage>1956</epage><pages>1951-1956</pages><issn>2050-7526</issn><eissn>2050-7534</eissn><abstract>A ratiometric thermometer based on a mixed Eu-Tb metal-organic framework is reported with a maximum relative thermal sensitivity of 16.1% K
−1
at 11 K making this material one of the best-performing thermometers currently reported in the literature. The sensing mechanism of {[Tb
2−
x
Eu
x
(H
2
Btec)(Btec)(H
2
O)
2
]·4H
2
O}
n
(Btec = 1,2,4,5 Benzenetetracarboxylic acid) has been attributed to a phonon-assisted energy migration between neighboring Tb
3+
ions in the structure.
Design of a new highly sensitive cryogenic luminescent thermometer based on a mixed Eu/Tb MOF.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d3tc02125d</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0002-3300-1347</orcidid><orcidid>https://orcid.org/0000-0002-2832-3958</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2050-7526 |
| ispartof | Journal of materials chemistry. C, Materials for optical and electronic devices, 2023-08, Vol.11 (32), p.1951-1956 |
| issn | 2050-7526 2050-7534 |
| language | eng |
| recordid | cdi_proquest_journals_2851787392 |
| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Chemical Sciences Instrumentation and Detectors Material chemistry Metal-organic frameworks Physics Thermometers Thermometry |
| title | A new highly sensitive cryogenic luminescent MOF thermometer built with pyromellitic acid |
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