Enhanced breakdown strength and energy storage density of PMMA/PVDF blends by coating superficial layers and doping organic fillers
Polymer-based flexible dielectrics have been widely used in capacitor energy storage due to their advantages of ultrahigh power density, flexibility, and scalability. To develop the polymer dielectric films with high-energy storage density has been a hot topic in the domain of dielectric energy stor...
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| Veröffentlicht in: | Journal of materials science. Materials in electronics 2023-08, Vol.34 (23), p.1657, Article 1657 |
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| creator | Zhang, Changhai Wang, Hairui Liu, Zeyang Zhang, Tiandong Tang, Chao Liu, Xianli Chi, Qingguo |
| description | Polymer-based flexible dielectrics have been widely used in capacitor energy storage due to their advantages of ultrahigh power density, flexibility, and scalability. To develop the polymer dielectric films with high-energy storage density has been a hot topic in the domain of dielectric energy storage. In this study, both of electric breakdown strength and energy storage density of poly(methyl methacrylate)/poly(vinylidene fluoride) (PMMA/PVDF) blending films are significantly improved by coating superficial layers and doping organic fillers, which involves using organic molecular semiconductor [6,6]phenyl C61 butyrate methyl ester (PCBM) as fillers doped into PMMA/PVDF (PMMA/PVDF@PCBM), and growing boron nitride (BN) barrier layer on the surface of the PMMA/PVDF@PCBM film (BN-PMMA/PVDF@PCBM-BN). The increased potential barrier height at the BN inorganic layer/metal electrode interface can remarkably suppress charge injection from electrodes. Additionally, the formation of charge traps at the interfaces of PCBM fillers and PVDF/PMMA matrix can significantly limit charge migration. An ultrahigh breakdown field strength of 889.6 kV/mm is achieved in the BN-PMMA/PVDF@0.7wt%PCBM-BN film, which also delivers a maximum discharged energy density of 25.62 J/cm
3
. This work provides an efficient method to enhance energy storage performance of polymer dielectric films by coating superficial layers and doping organic fillers. |
| doi_str_mv | 10.1007/s10854-023-11070-w |
| format | Article |
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3
. This work provides an efficient method to enhance energy storage performance of polymer dielectric films by coating superficial layers and doping organic fillers.</description><identifier>ISSN: 0957-4522</identifier><identifier>EISSN: 1573-482X</identifier><identifier>DOI: 10.1007/s10854-023-11070-w</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Barrier layers ; Boron nitride ; Breakdown ; Characterization and Evaluation of Materials ; Charge injection ; Chemistry and Materials Science ; Coating ; Dielectric strength ; Doping ; Electrodes ; Energy storage ; Field strength ; Fillers ; Materials Science ; Optical and Electronic Materials ; Organic chemistry ; Polymer blends ; Polymer films ; Polymers ; Polymethyl methacrylate ; Polyvinylidene fluorides ; Vinylidene fluoride</subject><ispartof>Journal of materials science. Materials in electronics, 2023-08, Vol.34 (23), p.1657, Article 1657</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-9afdd31fcf32c39dc947dfef6595b60e2d387e60e8f73ce3d3cefa0072879bd53</citedby><cites>FETCH-LOGICAL-c319t-9afdd31fcf32c39dc947dfef6595b60e2d387e60e8f73ce3d3cefa0072879bd53</cites><orcidid>0000-0002-7124-9570</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10854-023-11070-w$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10854-023-11070-w$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,778,782,27907,27908,41471,42540,51302</link.rule.ids></links><search><creatorcontrib>Zhang, Changhai</creatorcontrib><creatorcontrib>Wang, Hairui</creatorcontrib><creatorcontrib>Liu, Zeyang</creatorcontrib><creatorcontrib>Zhang, Tiandong</creatorcontrib><creatorcontrib>Tang, Chao</creatorcontrib><creatorcontrib>Liu, Xianli</creatorcontrib><creatorcontrib>Chi, Qingguo</creatorcontrib><title>Enhanced breakdown strength and energy storage density of PMMA/PVDF blends by coating superficial layers and doping organic fillers</title><title>Journal of materials science. Materials in electronics</title><addtitle>J Mater Sci: Mater Electron</addtitle><description>Polymer-based flexible dielectrics have been widely used in capacitor energy storage due to their advantages of ultrahigh power density, flexibility, and scalability. To develop the polymer dielectric films with high-energy storage density has been a hot topic in the domain of dielectric energy storage. In this study, both of electric breakdown strength and energy storage density of poly(methyl methacrylate)/poly(vinylidene fluoride) (PMMA/PVDF) blending films are significantly improved by coating superficial layers and doping organic fillers, which involves using organic molecular semiconductor [6,6]phenyl C61 butyrate methyl ester (PCBM) as fillers doped into PMMA/PVDF (PMMA/PVDF@PCBM), and growing boron nitride (BN) barrier layer on the surface of the PMMA/PVDF@PCBM film (BN-PMMA/PVDF@PCBM-BN). The increased potential barrier height at the BN inorganic layer/metal electrode interface can remarkably suppress charge injection from electrodes. Additionally, the formation of charge traps at the interfaces of PCBM fillers and PVDF/PMMA matrix can significantly limit charge migration. An ultrahigh breakdown field strength of 889.6 kV/mm is achieved in the BN-PMMA/PVDF@0.7wt%PCBM-BN film, which also delivers a maximum discharged energy density of 25.62 J/cm
3
. This work provides an efficient method to enhance energy storage performance of polymer dielectric films by coating superficial layers and doping organic fillers.</description><subject>Barrier layers</subject><subject>Boron nitride</subject><subject>Breakdown</subject><subject>Characterization and Evaluation of Materials</subject><subject>Charge injection</subject><subject>Chemistry and Materials Science</subject><subject>Coating</subject><subject>Dielectric strength</subject><subject>Doping</subject><subject>Electrodes</subject><subject>Energy storage</subject><subject>Field strength</subject><subject>Fillers</subject><subject>Materials Science</subject><subject>Optical and Electronic Materials</subject><subject>Organic chemistry</subject><subject>Polymer blends</subject><subject>Polymer films</subject><subject>Polymers</subject><subject>Polymethyl methacrylate</subject><subject>Polyvinylidene fluorides</subject><subject>Vinylidene fluoride</subject><issn>0957-4522</issn><issn>1573-482X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kD9PwzAQxS0EEqXwBZgsMQf8J2nisSotIIHoAIjNcuxzCAS72KmqzHxx3BaJjeXudPfeO-mH0Dkll5SQ8ipSUhV5RhjPKCUlyTYHaESLkmd5xV4P0YiIoszygrFjdBLjOyFkkvNqhL7n7k05DQbXAdSH8RuHYx_ANf0bVs5gcBCaIe18UA1gAy62_YC9xcuHh-nV8uV6gesOnIm4HrD2qm9dg-N6BcG2ulUd7tQAIe7CjF9trz40yrUa27br0ukUHVnVRTj77WP0vJg_zW6z-8ebu9n0PtOcij4TyhrDqdWWM82F0SIvjQU7KURRTwgww6sS0lDZkmvgJhWrEh1WlaI2BR-ji33uKvivNcRevvt1cOmlZFUuuMiLfKtie5UOPsYAVq5C-6nCICmRW9hyD1sm2HIHW26Sie9NMYldA-Ev-h_XD9t9hW0</recordid><startdate>20230801</startdate><enddate>20230801</enddate><creator>Zhang, Changhai</creator><creator>Wang, Hairui</creator><creator>Liu, Zeyang</creator><creator>Zhang, Tiandong</creator><creator>Tang, Chao</creator><creator>Liu, Xianli</creator><creator>Chi, Qingguo</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>F28</scope><scope>FR3</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>L7M</scope><scope>P5Z</scope><scope>P62</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>S0W</scope><orcidid>https://orcid.org/0000-0002-7124-9570</orcidid></search><sort><creationdate>20230801</creationdate><title>Enhanced breakdown strength and energy storage density of PMMA/PVDF blends by coating superficial layers and doping organic fillers</title><author>Zhang, Changhai ; Wang, Hairui ; Liu, Zeyang ; Zhang, Tiandong ; Tang, Chao ; Liu, Xianli ; Chi, Qingguo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-9afdd31fcf32c39dc947dfef6595b60e2d387e60e8f73ce3d3cefa0072879bd53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Barrier layers</topic><topic>Boron nitride</topic><topic>Breakdown</topic><topic>Characterization and Evaluation of Materials</topic><topic>Charge injection</topic><topic>Chemistry and Materials Science</topic><topic>Coating</topic><topic>Dielectric strength</topic><topic>Doping</topic><topic>Electrodes</topic><topic>Energy storage</topic><topic>Field strength</topic><topic>Fillers</topic><topic>Materials Science</topic><topic>Optical and Electronic Materials</topic><topic>Organic chemistry</topic><topic>Polymer blends</topic><topic>Polymer films</topic><topic>Polymers</topic><topic>Polymethyl methacrylate</topic><topic>Polyvinylidene fluorides</topic><topic>Vinylidene fluoride</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Changhai</creatorcontrib><creatorcontrib>Wang, Hairui</creatorcontrib><creatorcontrib>Liu, Zeyang</creatorcontrib><creatorcontrib>Zhang, Tiandong</creatorcontrib><creatorcontrib>Tang, Chao</creatorcontrib><creatorcontrib>Liu, Xianli</creatorcontrib><creatorcontrib>Chi, Qingguo</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>DELNET Engineering & Technology Collection</collection><jtitle>Journal of materials science. Materials in electronics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Changhai</au><au>Wang, Hairui</au><au>Liu, Zeyang</au><au>Zhang, Tiandong</au><au>Tang, Chao</au><au>Liu, Xianli</au><au>Chi, Qingguo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Enhanced breakdown strength and energy storage density of PMMA/PVDF blends by coating superficial layers and doping organic fillers</atitle><jtitle>Journal of materials science. Materials in electronics</jtitle><stitle>J Mater Sci: Mater Electron</stitle><date>2023-08-01</date><risdate>2023</risdate><volume>34</volume><issue>23</issue><spage>1657</spage><pages>1657-</pages><artnum>1657</artnum><issn>0957-4522</issn><eissn>1573-482X</eissn><abstract>Polymer-based flexible dielectrics have been widely used in capacitor energy storage due to their advantages of ultrahigh power density, flexibility, and scalability. To develop the polymer dielectric films with high-energy storage density has been a hot topic in the domain of dielectric energy storage. In this study, both of electric breakdown strength and energy storage density of poly(methyl methacrylate)/poly(vinylidene fluoride) (PMMA/PVDF) blending films are significantly improved by coating superficial layers and doping organic fillers, which involves using organic molecular semiconductor [6,6]phenyl C61 butyrate methyl ester (PCBM) as fillers doped into PMMA/PVDF (PMMA/PVDF@PCBM), and growing boron nitride (BN) barrier layer on the surface of the PMMA/PVDF@PCBM film (BN-PMMA/PVDF@PCBM-BN). The increased potential barrier height at the BN inorganic layer/metal electrode interface can remarkably suppress charge injection from electrodes. Additionally, the formation of charge traps at the interfaces of PCBM fillers and PVDF/PMMA matrix can significantly limit charge migration. An ultrahigh breakdown field strength of 889.6 kV/mm is achieved in the BN-PMMA/PVDF@0.7wt%PCBM-BN film, which also delivers a maximum discharged energy density of 25.62 J/cm
3
. This work provides an efficient method to enhance energy storage performance of polymer dielectric films by coating superficial layers and doping organic fillers.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10854-023-11070-w</doi><orcidid>https://orcid.org/0000-0002-7124-9570</orcidid></addata></record> |
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| subjects | Barrier layers Boron nitride Breakdown Characterization and Evaluation of Materials Charge injection Chemistry and Materials Science Coating Dielectric strength Doping Electrodes Energy storage Field strength Fillers Materials Science Optical and Electronic Materials Organic chemistry Polymer blends Polymer films Polymers Polymethyl methacrylate Polyvinylidene fluorides Vinylidene fluoride |
| title | Enhanced breakdown strength and energy storage density of PMMA/PVDF blends by coating superficial layers and doping organic fillers |
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