Phase V−T diagrams of solid hydrocarbons. part III: Cyclic compounds
P−T and V−T phase diagrams of cyclic hydrocarbons, namely benzene (C6H6), cyclopentane (C5H10), thiophene (C4H4S), and tetrahydrofuran (C4H8O), were constructed using both literature and our experimental data obtained during the study of isochoric thermal conductivity in high-temperature phase. The...
Gespeichert in:
| Veröffentlicht in: | Low temperature physics (Woodbury, N.Y.) N.Y.), 2023-08, Vol.49 (8), p.971-978 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 978 |
|---|---|
| container_issue | 8 |
| container_start_page | 971 |
| container_title | Low temperature physics (Woodbury, N.Y.) |
| container_volume | 49 |
| creator | Konstantinov, V. A. Karachevtseva, A. V. Sagan, V. V. |
| description | P−T and V−T phase diagrams of cyclic hydrocarbons, namely benzene (C6H6), cyclopentane (C5H10), thiophene (C4H4S), and tetrahydrofuran (C4H8O), were constructed using both literature and our experimental data obtained during the study of isochoric thermal conductivity in high-temperature phase. The V−T phase diagrams of cyclohexane (C6H12) and furan (C4H4O), presented earlier, were refined and supplemented with P−T diagrams. The possibility of constructing a phase diagram for cyclohexene (C6H10) is also discussed. The changes in molar volume during melting and the boundaries of the existence of high-temperature phases have been determined. The magnitudes of thermal pressure of cyclic hydrocarbons studied were obtained. Experimental values of dPm/dT on melting line were compared with those calculated by the Clapeyron-Clausius equation. |
| doi_str_mv | 10.1063/10.0020165 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2844904548</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2844904548</sourcerecordid><originalsourceid>FETCH-LOGICAL-c360t-5dec0a056f54b6617f5faa49df19da16a05d7c652820fe762fa46d44e2ae9df03</originalsourceid><addsrcrecordid>eNp9kM1Kw0AUhQdRsFY3PsGAOyX1TjI_jTspVgOCLqq4C7fzY1PaTJxJF30D1z6iT-KUdu3qu3A-zoVDyCWDEQNZ3CYC5MCkOCIDBiVkUjB1vLtlkSmlPk7JWYxLAJbSckCmrwuMlr7_fv_MqGnwM-A6Uu9o9KvG0MXWBK8xzH0bR7TD0NOqqu7oZKtXjabarzu_aU08JycOV9FeHDgkb9OH2eQpe355rCb3z5kuJPSZMFYDgpBO8LmUTDnhEHlpHCsNMpkio7QU-TgHZ5XMHXJpOLc52iRBMSRX-94u-K-NjX299JvQppd1Pua8BC74OFnXe0sHH2Owru5Cs8awrRnUuyV2POyU5Ju9HHXTY9_49j_7D-R0Z1I</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2844904548</pqid></control><display><type>article</type><title>Phase V−T diagrams of solid hydrocarbons. part III: Cyclic compounds</title><source>AIP Journals Complete</source><creator>Konstantinov, V. A. ; Karachevtseva, A. V. ; Sagan, V. V.</creator><creatorcontrib>Konstantinov, V. A. ; Karachevtseva, A. V. ; Sagan, V. V.</creatorcontrib><description>P−T and V−T phase diagrams of cyclic hydrocarbons, namely benzene (C6H6), cyclopentane (C5H10), thiophene (C4H4S), and tetrahydrofuran (C4H8O), were constructed using both literature and our experimental data obtained during the study of isochoric thermal conductivity in high-temperature phase. The V−T phase diagrams of cyclohexane (C6H12) and furan (C4H4O), presented earlier, were refined and supplemented with P−T diagrams. The possibility of constructing a phase diagram for cyclohexene (C6H10) is also discussed. The changes in molar volume during melting and the boundaries of the existence of high-temperature phases have been determined. The magnitudes of thermal pressure of cyclic hydrocarbons studied were obtained. Experimental values of dPm/dT on melting line were compared with those calculated by the Clapeyron-Clausius equation.</description><identifier>ISSN: 1063-777X</identifier><identifier>EISSN: 1090-6517</identifier><identifier>DOI: 10.1063/10.0020165</identifier><identifier>CODEN: LTPHEG</identifier><language>eng</language><publisher>Melville: American Institute of Physics</publisher><subject>Benzene ; Cyclic compounds ; Cyclic hydrocarbons ; Cyclohexane ; High temperature ; Molar volume ; Phase diagrams ; Tetrahydrofuran ; Thermal conductivity</subject><ispartof>Low temperature physics (Woodbury, N.Y.), 2023-08, Vol.49 (8), p.971-978</ispartof><rights>Author(s)</rights><rights>2023 Author(s). Published under an exclusive license by AIP Publishing.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c360t-5dec0a056f54b6617f5faa49df19da16a05d7c652820fe762fa46d44e2ae9df03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://pubs.aip.org/ltp/article-lookup/doi/10.1063/10.0020165$$EHTML$$P50$$Gscitation$$H</linktohtml><link.rule.ids>315,781,785,795,4513,27929,27930,76389</link.rule.ids></links><search><creatorcontrib>Konstantinov, V. A.</creatorcontrib><creatorcontrib>Karachevtseva, A. V.</creatorcontrib><creatorcontrib>Sagan, V. V.</creatorcontrib><title>Phase V−T diagrams of solid hydrocarbons. part III: Cyclic compounds</title><title>Low temperature physics (Woodbury, N.Y.)</title><description>P−T and V−T phase diagrams of cyclic hydrocarbons, namely benzene (C6H6), cyclopentane (C5H10), thiophene (C4H4S), and tetrahydrofuran (C4H8O), were constructed using both literature and our experimental data obtained during the study of isochoric thermal conductivity in high-temperature phase. The V−T phase diagrams of cyclohexane (C6H12) and furan (C4H4O), presented earlier, were refined and supplemented with P−T diagrams. The possibility of constructing a phase diagram for cyclohexene (C6H10) is also discussed. The changes in molar volume during melting and the boundaries of the existence of high-temperature phases have been determined. The magnitudes of thermal pressure of cyclic hydrocarbons studied were obtained. Experimental values of dPm/dT on melting line were compared with those calculated by the Clapeyron-Clausius equation.</description><subject>Benzene</subject><subject>Cyclic compounds</subject><subject>Cyclic hydrocarbons</subject><subject>Cyclohexane</subject><subject>High temperature</subject><subject>Molar volume</subject><subject>Phase diagrams</subject><subject>Tetrahydrofuran</subject><subject>Thermal conductivity</subject><issn>1063-777X</issn><issn>1090-6517</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9kM1Kw0AUhQdRsFY3PsGAOyX1TjI_jTspVgOCLqq4C7fzY1PaTJxJF30D1z6iT-KUdu3qu3A-zoVDyCWDEQNZ3CYC5MCkOCIDBiVkUjB1vLtlkSmlPk7JWYxLAJbSckCmrwuMlr7_fv_MqGnwM-A6Uu9o9KvG0MXWBK8xzH0bR7TD0NOqqu7oZKtXjabarzu_aU08JycOV9FeHDgkb9OH2eQpe355rCb3z5kuJPSZMFYDgpBO8LmUTDnhEHlpHCsNMpkio7QU-TgHZ5XMHXJpOLc52iRBMSRX-94u-K-NjX299JvQppd1Pua8BC74OFnXe0sHH2Owru5Cs8awrRnUuyV2POyU5Ju9HHXTY9_49j_7D-R0Z1I</recordid><startdate>20230801</startdate><enddate>20230801</enddate><creator>Konstantinov, V. A.</creator><creator>Karachevtseva, A. V.</creator><creator>Sagan, V. V.</creator><general>American Institute of Physics</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope></search><sort><creationdate>20230801</creationdate><title>Phase V−T diagrams of solid hydrocarbons. part III: Cyclic compounds</title><author>Konstantinov, V. A. ; Karachevtseva, A. V. ; Sagan, V. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c360t-5dec0a056f54b6617f5faa49df19da16a05d7c652820fe762fa46d44e2ae9df03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Benzene</topic><topic>Cyclic compounds</topic><topic>Cyclic hydrocarbons</topic><topic>Cyclohexane</topic><topic>High temperature</topic><topic>Molar volume</topic><topic>Phase diagrams</topic><topic>Tetrahydrofuran</topic><topic>Thermal conductivity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Konstantinov, V. A.</creatorcontrib><creatorcontrib>Karachevtseva, A. V.</creatorcontrib><creatorcontrib>Sagan, V. V.</creatorcontrib><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Low temperature physics (Woodbury, N.Y.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Konstantinov, V. A.</au><au>Karachevtseva, A. V.</au><au>Sagan, V. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Phase V−T diagrams of solid hydrocarbons. part III: Cyclic compounds</atitle><jtitle>Low temperature physics (Woodbury, N.Y.)</jtitle><date>2023-08-01</date><risdate>2023</risdate><volume>49</volume><issue>8</issue><spage>971</spage><epage>978</epage><pages>971-978</pages><issn>1063-777X</issn><eissn>1090-6517</eissn><coden>LTPHEG</coden><abstract>P−T and V−T phase diagrams of cyclic hydrocarbons, namely benzene (C6H6), cyclopentane (C5H10), thiophene (C4H4S), and tetrahydrofuran (C4H8O), were constructed using both literature and our experimental data obtained during the study of isochoric thermal conductivity in high-temperature phase. The V−T phase diagrams of cyclohexane (C6H12) and furan (C4H4O), presented earlier, were refined and supplemented with P−T diagrams. The possibility of constructing a phase diagram for cyclohexene (C6H10) is also discussed. The changes in molar volume during melting and the boundaries of the existence of high-temperature phases have been determined. The magnitudes of thermal pressure of cyclic hydrocarbons studied were obtained. Experimental values of dPm/dT on melting line were compared with those calculated by the Clapeyron-Clausius equation.</abstract><cop>Melville</cop><pub>American Institute of Physics</pub><doi>10.1063/10.0020165</doi><tpages>8</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1063-777X |
| ispartof | Low temperature physics (Woodbury, N.Y.), 2023-08, Vol.49 (8), p.971-978 |
| issn | 1063-777X 1090-6517 |
| language | eng |
| recordid | cdi_proquest_journals_2844904548 |
| source | AIP Journals Complete |
| subjects | Benzene Cyclic compounds Cyclic hydrocarbons Cyclohexane High temperature Molar volume Phase diagrams Tetrahydrofuran Thermal conductivity |
| title | Phase V−T diagrams of solid hydrocarbons. part III: Cyclic compounds |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-14T22%3A37%3A28IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Phase%20V%E2%88%92T%20diagrams%20of%20solid%20hydrocarbons.%20part%20III:%20Cyclic%20compounds&rft.jtitle=Low%20temperature%20physics%20(Woodbury,%20N.Y.)&rft.au=Konstantinov,%20V.%20A.&rft.date=2023-08-01&rft.volume=49&rft.issue=8&rft.spage=971&rft.epage=978&rft.pages=971-978&rft.issn=1063-777X&rft.eissn=1090-6517&rft.coden=LTPHEG&rft_id=info:doi/10.1063/10.0020165&rft_dat=%3Cproquest_cross%3E2844904548%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2844904548&rft_id=info:pmid/&rfr_iscdi=true |