One-pot Synthesis of Copper-doped ZnO Nanorods photocatalysts: Degradation of Diuron Herbicide Under Simulated Solar Light
In the current study, Copper doped ZnO nanorods (Zn 1 − y Cu y O) have been synthesized using a one-pot polyolmethod with low Cu molar content (0
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| Veröffentlicht in: | Journal of inorganic and organometallic polymers and materials 2023-08, Vol.33 (8), p.2523-2530 |
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| container_issue | 8 |
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| container_title | Journal of inorganic and organometallic polymers and materials |
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| creator | Fkiri, Anis Saidani, Mohamed Ali Chmangui, Anis Smiri, Leila Samia |
| description | In the current study, Copper doped ZnO nanorods (Zn
1 − y
Cu
y
O) have been synthesized using a one-pot polyolmethod with low Cu molar content (0 |
| doi_str_mv | 10.1007/s10904-023-02654-4 |
| format | Article |
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1 − y
Cu
y
O) have been synthesized using a one-pot polyolmethod with low Cu molar content (0 < y < 0.373%) and have been evaluated in the photodegradation of Diuron, one of the most highly toxic and persistent herbicides in water ecosystems.The triethylene-glycol (TREG) polyol solvent played an important role as a reducing and stabilizing agent in controlling the morphology, size and photocatalytic activity ofZn
1 − y
Cu
y
O photocatalysts. X-ray diffraction, transmission electron microscopy, N
2
adsorption study, inductively coupled plasma optical emission spectroscopy and UV–Vis diffuse reflectance spectroscopy measurements were carried out to examine the physical and optical properties of the synthesized samples. Such Zn
1 − y
Cu
y
O nanorods photocatalysts with optimized y = 0.047% Cu content exhibit 9 times higher photocatalytic activity than undoped ZnO nanorods under solar light illumination, attributed to higher charge separation rates for the photo-generated carriers in the Zn
1 − y
Cu
y
O nanorods structure.</description><identifier>ISSN: 1574-1443</identifier><identifier>EISSN: 1574-1451</identifier><identifier>DOI: 10.1007/s10904-023-02654-4</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Catalytic activity ; Chemistry ; Chemistry and Materials Science ; Copper ; Diffuse reflectance spectroscopy ; Diuron ; Emission analysis ; Herbicides ; Inductively coupled plasma ; Inorganic Chemistry ; Light ; Nanorods ; Optical emission spectroscopy ; Optical properties ; Organic Chemistry ; Photocatalysis ; Photocatalysts ; Photodegradation ; Polymer Sciences ; Stabilizers (agents) ; Synthesis ; Zinc oxide</subject><ispartof>Journal of inorganic and organometallic polymers and materials, 2023-08, Vol.33 (8), p.2523-2530</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c270t-a8a88b8b301ee8edf08e30a3376d3ebc399e7253b0e1e6cd1e9b90834155966f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10904-023-02654-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10904-023-02654-4$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,781,785,27929,27930,41493,42562,51324</link.rule.ids></links><search><creatorcontrib>Fkiri, Anis</creatorcontrib><creatorcontrib>Saidani, Mohamed Ali</creatorcontrib><creatorcontrib>Chmangui, Anis</creatorcontrib><creatorcontrib>Smiri, Leila Samia</creatorcontrib><title>One-pot Synthesis of Copper-doped ZnO Nanorods photocatalysts: Degradation of Diuron Herbicide Under Simulated Solar Light</title><title>Journal of inorganic and organometallic polymers and materials</title><addtitle>J Inorg Organomet Polym</addtitle><description>In the current study, Copper doped ZnO nanorods (Zn
1 − y
Cu
y
O) have been synthesized using a one-pot polyolmethod with low Cu molar content (0 < y < 0.373%) and have been evaluated in the photodegradation of Diuron, one of the most highly toxic and persistent herbicides in water ecosystems.The triethylene-glycol (TREG) polyol solvent played an important role as a reducing and stabilizing agent in controlling the morphology, size and photocatalytic activity ofZn
1 − y
Cu
y
O photocatalysts. X-ray diffraction, transmission electron microscopy, N
2
adsorption study, inductively coupled plasma optical emission spectroscopy and UV–Vis diffuse reflectance spectroscopy measurements were carried out to examine the physical and optical properties of the synthesized samples. Such Zn
1 − y
Cu
y
O nanorods photocatalysts with optimized y = 0.047% Cu content exhibit 9 times higher photocatalytic activity than undoped ZnO nanorods under solar light illumination, attributed to higher charge separation rates for the photo-generated carriers in the Zn
1 − y
Cu
y
O nanorods structure.</description><subject>Catalytic activity</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Copper</subject><subject>Diffuse reflectance spectroscopy</subject><subject>Diuron</subject><subject>Emission analysis</subject><subject>Herbicides</subject><subject>Inductively coupled plasma</subject><subject>Inorganic Chemistry</subject><subject>Light</subject><subject>Nanorods</subject><subject>Optical emission spectroscopy</subject><subject>Optical properties</subject><subject>Organic Chemistry</subject><subject>Photocatalysis</subject><subject>Photocatalysts</subject><subject>Photodegradation</subject><subject>Polymer Sciences</subject><subject>Stabilizers (agents)</subject><subject>Synthesis</subject><subject>Zinc oxide</subject><issn>1574-1443</issn><issn>1574-1451</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9kLFOwzAQhi0EEqXwAkyWmAN2bCcOG2qBIlV0KF1YLCe-tKlSO9juUJ6elCDYGE53w__9J30IXVNySwnJ7wIlBeEJSVk_meAJP0EjKnKeUC7o6e_N2Tm6CGFLCJNE0BH6XFhIOhfx8mDjBkITsKvxxHUd-MS4Dgx-twv8qq3zzgTcbVx0lY66PYQY7vEU1l4bHRtnj-C02fv-moEvm6oxgFfWgMfLZrdvdezLlq7VHs-b9SZeorNatwGufvYYrZ4e3yazZL54fpk8zJMqzUlMtNRSlrJkhAJIMDWRwIhmLM8Mg7JiRQF5KlhJgEJWGQpFWRDJOBWiyLKajdHN0Nt597GHENXW7b3tX6pUcp6LjPc6xigdUpV3IXioVeebnfYHRYk6OlaDY9U7Vt-OFe8hNkChD9s1-L_qf6gv_1qACw</recordid><startdate>20230801</startdate><enddate>20230801</enddate><creator>Fkiri, Anis</creator><creator>Saidani, Mohamed Ali</creator><creator>Chmangui, Anis</creator><creator>Smiri, Leila Samia</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20230801</creationdate><title>One-pot Synthesis of Copper-doped ZnO Nanorods photocatalysts: Degradation of Diuron Herbicide Under Simulated Solar Light</title><author>Fkiri, Anis ; Saidani, Mohamed Ali ; Chmangui, Anis ; Smiri, Leila Samia</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c270t-a8a88b8b301ee8edf08e30a3376d3ebc399e7253b0e1e6cd1e9b90834155966f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Catalytic activity</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Copper</topic><topic>Diffuse reflectance spectroscopy</topic><topic>Diuron</topic><topic>Emission analysis</topic><topic>Herbicides</topic><topic>Inductively coupled plasma</topic><topic>Inorganic Chemistry</topic><topic>Light</topic><topic>Nanorods</topic><topic>Optical emission spectroscopy</topic><topic>Optical properties</topic><topic>Organic Chemistry</topic><topic>Photocatalysis</topic><topic>Photocatalysts</topic><topic>Photodegradation</topic><topic>Polymer Sciences</topic><topic>Stabilizers (agents)</topic><topic>Synthesis</topic><topic>Zinc oxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fkiri, Anis</creatorcontrib><creatorcontrib>Saidani, Mohamed Ali</creatorcontrib><creatorcontrib>Chmangui, Anis</creatorcontrib><creatorcontrib>Smiri, Leila Samia</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fkiri, Anis</au><au>Saidani, Mohamed Ali</au><au>Chmangui, Anis</au><au>Smiri, Leila Samia</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>One-pot Synthesis of Copper-doped ZnO Nanorods photocatalysts: Degradation of Diuron Herbicide Under Simulated Solar Light</atitle><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle><stitle>J Inorg Organomet Polym</stitle><date>2023-08-01</date><risdate>2023</risdate><volume>33</volume><issue>8</issue><spage>2523</spage><epage>2530</epage><pages>2523-2530</pages><issn>1574-1443</issn><eissn>1574-1451</eissn><abstract>In the current study, Copper doped ZnO nanorods (Zn
1 − y
Cu
y
O) have been synthesized using a one-pot polyolmethod with low Cu molar content (0 < y < 0.373%) and have been evaluated in the photodegradation of Diuron, one of the most highly toxic and persistent herbicides in water ecosystems.The triethylene-glycol (TREG) polyol solvent played an important role as a reducing and stabilizing agent in controlling the morphology, size and photocatalytic activity ofZn
1 − y
Cu
y
O photocatalysts. X-ray diffraction, transmission electron microscopy, N
2
adsorption study, inductively coupled plasma optical emission spectroscopy and UV–Vis diffuse reflectance spectroscopy measurements were carried out to examine the physical and optical properties of the synthesized samples. Such Zn
1 − y
Cu
y
O nanorods photocatalysts with optimized y = 0.047% Cu content exhibit 9 times higher photocatalytic activity than undoped ZnO nanorods under solar light illumination, attributed to higher charge separation rates for the photo-generated carriers in the Zn
1 − y
Cu
y
O nanorods structure.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10904-023-02654-4</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1574-1443 |
| ispartof | Journal of inorganic and organometallic polymers and materials, 2023-08, Vol.33 (8), p.2523-2530 |
| issn | 1574-1443 1574-1451 |
| language | eng |
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| source | SpringerNature Journals |
| subjects | Catalytic activity Chemistry Chemistry and Materials Science Copper Diffuse reflectance spectroscopy Diuron Emission analysis Herbicides Inductively coupled plasma Inorganic Chemistry Light Nanorods Optical emission spectroscopy Optical properties Organic Chemistry Photocatalysis Photocatalysts Photodegradation Polymer Sciences Stabilizers (agents) Synthesis Zinc oxide |
| title | One-pot Synthesis of Copper-doped ZnO Nanorods photocatalysts: Degradation of Diuron Herbicide Under Simulated Solar Light |
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